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13718-26-8

Basic Information
CAS No.: 13718-26-8
Name: Sodium metavanadate
Article Data: 87
Molecular Structure:
Molecular Structure of 13718-26-8 (Sodium metavanadate)
Formula: NaVO3
Molecular Weight: 121.929
Synonyms: Sodiumvanadate(V) (NaVO3) (6CI,7CI);Vanadate (VO31-), sodium (9CI);Vanadic acid(HVO3), sodium salt (8CI);Monosodium trioxovanadate(1-);NaVO3;Sodiummetavanadate;Sodium metavanadate (NaVO3);Sodium trioxovanadate(1-);Sodiumvanadate;Sodium vanadate (NaVO3);Sodium vanadium oxide (NaVO3);Sodiumvanadium trioxide;
EINECS: 237-272-7
Density: 3.241 g/cm3
Melting Point: 600 ºC
Solubility: Soluble in water.
Appearance: white to off-white powder
Hazard Symbols: ToxicT
Risk Codes: 25-36/37/38
Safety: 26-36/37/39-45
Transport Information: UN 3285 6.1/PG 3
PSA: 57.20000
LogP: -0.35640
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Specification

The Sodium vanadate, with the CAS registry number 13718-26-8, is also known as Sodium metavanadate. It belongs to the product categories of Straight Chain Compounds; Inorganics; Inorganic Compound. Its EINECS registry number is 237-272-7. This chemical's molecular formula is NaO3V and molecular weight is 121.93. What's more, both its IUPAC name and systematic name are the same which is called Sodium oxido(dioxo)vanadium. This chemical is a yellow solid which is soluble in water. Its use is limited to its hygroscopic property. Its natural forms include mineral metamunirite (anhydrous) and a dihydrate, munirite. This chemical is used as analysis reagent and mordant and it is used for fertilizer, gas desulfurization, photography.

Physical properties about Sodium vanadate are: (1)#H bond acceptors: 3; (2)#H bond donors: 1; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 54.37 Å2.

Preparation of Sodium vanadate: this chemical can be prepared by vanadium pentoxide with sodium hydroxide. This reaction needs concentration and crystallization.

V2O5+2NaOH→2NaVO3+H2O

When you are dealing with this chemical, you should be very careful. It is toxic if swallowed and it is irritating to eyes, respiratory system and skin. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1) SMILES: [Na+].[O-][V](=O)=O
(2) InChI: InChI=1S/Na.3O.V/q+1;;;-1;
(3) InChIKey: CMZUMMUJMWNLFH-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LD50 intravenous 7180ug/kg (7.18mg/kg) VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION

VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
Agressologie. Revue Internationale de Physio-Biologie et de Pharmacologie Appliquees aux Effets de l'Agression. Vol. 8, Pg. 51, 1967.
dog LDLo intravenous 11mg/kg (11mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LDLo subcutaneous 17mg/kg (17mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse LD50 intraperitoneal 36mg/kg (36mg/kg) BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Toxicology Letters. Vol. 23, Pg. 227, 1984.
mouse LD50 oral 74600ug/kg (74.6mg/kg) BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Toxicology Letters. Vol. 23, Pg. 227, 1984.
rabbit LDLo intravenous 17mg/kg (17mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo oral 200mg/kg (200mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 intraperitoneal 12mg/kg (12mg/kg)   Bromatologia i Chemia Toksykologiczna. Vol. 18, Pg. 109, 1985.
rat LD50 oral 98mg/kg (98mg/kg) BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Toxicology Letters. Vol. 23, Pg. 227, 1984.