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Basic Information
CAS No.: 13759-83-6
Name: SAMARIUM NITRATE HEXAHYDRATE
Molecular Structure:
Molecular Structure of 13759-83-6 (SAMARIUM NITRATE HEXAHYDRATE)
Formula: H2O . 1/2 H N O3 . 1/6 Sm
Molecular Weight: 444.50
Synonyms: Samarium nitrate(Sm(NO3)3) hexahydrate; Samarium nitrate hexahydrate (Sm[NO3]3.bul.6H2O); Samariumtrinitrate hexahydrate
EINECS: 233-798-6
Density: 2.375
Melting Point: 78°C
Boiling Point: 83 °C at 760 mmHg
Solubility: H2O: 0.1 g/mL, clear
Appearance: yellow crystals or crystalline powder
Hazard Symbols: OxidizingO
Risk Codes: 8-36/37/38
Safety: Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. When heated to decomposition it emits toxic fumes of NOx. See also SAMARIUM and NITRATES.
Transport Information: UN 1477 5
PSA: 262.02000
LogP: 0.46650
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Chemistry

IUPAC Name: Samarium(3+) trinitrate hexahydrate
Synonyms: Nitric acid, samarium(3+) salt, hexahydrate ; Samarium nitrat [German] ; Samarium trinitrate hexahydrate ; Samarium(III) nitrate hexahydrate
Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts;Samarium Salts;SamariumMetal and Ceramic Science
CAS NO: 13759-83-6
Molecular Formula of Samarium(III) nitrate, hexahydrate (1:3:6) (CAS NO.13759-83-6) : H12N3O15Sm
Molecular Weight of Samarium(III) nitrate, hexahydrate (1:3:6) (CAS NO.13759-83-6) : 444.47
Molecular Structure of Samarium(III) nitrate, hexahydrate (1:3:6) (CAS NO.13759-83-6) :
EINECS: 233-798-6
Enthalpy of Vaporization: 37.72 kJ/mol
Boiling Point: 83°C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C
Melting Point: 78°C
Density: 2.375
Storage temp: 0-6°C
Solubility : H2O: 0.1 g/mL, clear
Sensitive : Hygroscopic
Appearance:yellow crystals or crystalline powder

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LDLo subcutaneous 1600mg/kg (1600mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

CARDIAC: OTHER CHANGES

SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"
Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 145, Pg. 19, 1929.
guinea pig LDLo subcutaneous 500mg/kg (500mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 145, Pg. 19, 1929.
mouse LD50 intraperitoneal 315mg/kg (315mg/kg)   Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963.
rat LD50 intraperitoneal 285mg/kg (285mg/kg)   Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963.
rat LD50 intravenous 9mg/kg (9mg/kg)   Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963.
rat LD50 oral 2900mg/kg (2900mg/kg)   Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963.

 

Safety Profile

Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. When heated to decomposition it emits toxic fumes of NOx. See also SAMARIUM and NITRATES.
Hazard Codes OxidizingO,IrritantXi
Risk Statements 8-36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R8 :Contact with combustible material may cause fire.
Safety Statements 17-26-36/37/39-24/25-22
S17:Keep away from combustible material. 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR UN 1477 5.1/PG 3
WGK Germany 2
RTECS VP3150000
HazardClass 5.1
PackingGroup III