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13762-51-1

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Basic Information
CAS No.: 13762-51-1
Name: Potassium borohydride
Molecular Structure:
Molecular Structure of 13762-51-1 (Potassium borohydride)
Formula: BH4.K
Molecular Weight: 53.93
Synonyms: Borate(1-),tetrahydro-, potassium (1:1);Borate(1-),tetrahydro-, potassium (8CI,9CI);Potassium tetrahydroborate;Potassium tetrahydroborate (KBH4);
EINECS: 237-360-5
Density: 1.18 g/mL at 25 °C(lit.)
Melting Point: 500 °C (dec.)(lit.)
Solubility: water: 190 g/L (25 °C)
Appearance: white crystalline powder
Hazard Symbols: FlammableF,ToxicT,CorrosiveC
Risk Codes: 14/15-24/25-34-11
Safety: 26-36/37/39-43-45-7/8-28A-16
Transport Information: UN 1870 4.3/PG 1
PSA: 0.00000
LogP: -1.45160
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Chemistry

Empirical Formula: H4BK
Molecular Weight: 53.9411 g/mol
Density: 1.18 cm3
Melting point: 500 °C
Storage tempreture: Water-free area
Water solubility: 190 g/L (25 °C)
Sensitive: Moisture Sensitive
Appearance: White crystalline or powdered solid
Structure of Potassium borohydride (CAS NO.13762-51-1):
                     
Product Category of Potassium borohydride (CAS NO.13762-51-1): Inorganic Chemicals;Reduction;Synthetic Organic Chemistry;Potassium Salts;Synthetic Reagents;Borohydrides

Uses

 Potassium borohydride (CAS NO.13762-51-1) is used as organic reagent, and pharmaceutical intermediate.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 55mg/kg (55mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.
rabbit LD50 oral 60mg/kg (60mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.
rabbit LD50 skin 230mg/kg (230mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.
rat LC50 inhalation 46mg/m3 (46mg/m3) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.
rat LD50 oral 167mg/kg (167mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.
rat LD50 subcutaneous 184mg/kg (184mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 129, 1999.

 Potassium borohydride (CAS NO.13762-51-1) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.

Safety Profile

Hazard Codes: FlammableF,ToxicT,CorrosiveC
Risk Statements: 14/15-24/25-34-11
 R11:Highly flammable. 
R14 :Reacts violently with water. 
R15:Contact with water liberates extremely flammable gases. 
R24:Toxic in contact with skin. 
R25 :Toxic if swallowed. 
R34:Causes burns.
Safety Statements: 26-36/37/39-43-45-7/8-28A-16 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

Specification

 Potassium borohydride , its cas register number is 13762-51-1. It also can be called Potassium tetrahydroborate . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Do not induce vomiting. Wash mouth out with water, and get medical aid immediately.
In addition, Potassium borohydride (CAS NO.13762-51-1) could be stable under normal temperatures and pressures. It is not compatible with water, strong oxidizing agents, acids, strong bases, alcohols, and you must not take it with high temperatures, incompatible materials, exposure to moist air or water. And also prevent it to broken down into hazardous decomposition products: oxides of boron, borane, hydrogen gas, oxides of potassium.