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13820-41-2

Basic Information
CAS No.: 13820-41-2
Name: Platinum(II)-ammonium chloride
Molecular Structure:
Molecular Structure of 13820-41-2 (Platinum(II)-ammonium chloride)
Formula: (NH4)2.PtCl4
Molecular Weight: 372.969
Synonyms: Ammoniumchloroplatinate(II) (6CI);Ammonium tetrachloroplatinate(II) (7CI);Platinate(2-), tetrachloro-, diammonium (8CI);Platinate(2-), tetrachloro-,diammonium, (SP-4-1)- (9CI);Ammonium chloroplatinate ((NH4)2PtCl4);Ammoniumtetrachloroplatinate(2-);Bis(ammonium) tetrachloroplatinate(2-);Diammoniumtetrachloroplatinate;Diammonium tetrachloroplatinate(2-);NSC 271963;
EINECS: 237-499-1
Density: 2.936 g/cm3
Melting Point: 140 °C
Solubility: soluble in water
Appearance: light brown orange to red crystalline powder
Hazard Symbols: ToxicT
Risk Codes: 25-38-41-42/43-28
Safety: 22-26-36/37/39-45
Transport Information: UN 3288
PSA: 0.00000
LogP: 3.50790
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    Product Name: Platinum(II)-ammonium chloride CAS: 13820-41-2 MF: Cl4Pt.2H4N MW: 372.97 EINECS: 237-499-1 Mol File: 13820-41-2.mol Platinum(II)-ammonium chloride Structure Platinum(II)-ammonium chloride Chemical Properties Melting

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 0.002 mg(Pt)/m3
ACGIH TLV: TWA 0.002 mg(Pt)/m3

Specification

The IUPAC name of Platinum(II)-ammonium chloride is diazanium tetrachloroplatinum(2-). With the CAS registry number 13820-41-2 and EINECS 237-499-1, it is also named as Ammonium platinous chloride. It is light brown orange to red crystalline powder which is highly toxic. When heated to decomposition it emits toxic fumes of NH3, Cl, and Pt. So the storage environment should be well-ventilated, low-temperature and dry.

The other characteristics of this product can be summarized as: (1)#H bond acceptors: 2; (2)#H bond donors: 6; (3)#Freely Rotating Bonds: 0; (4)Rotatable Bond Count: 0; (5)Exact Mass: 372.905983; (6)MonoIsotopic Mass: 370.908933; (7)Topological Polar Surface Area: 2; (8)Heavy Atom Count: 7; (9)Formal Charge: 0; (10)Complexity: 19.1; (11)Isotope Atom Count: 0; (12)Covalently-Bonded Unit Count: 3.

Uses of Platinum(II)-ammonium chloride: It is used in spectral analysis standard. It is also used in the preparation of platinum sponge and platinum catalytic agent.

When you are using this chemical, please be cautious about it as the following:
It is not only toxic if swallowed, but also irritating to skin. And it has risk of serious damage to the eyes. So people should not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1. SMILES:Cl[Pt-2](Cl)(Cl)Cl.[NH4+].[NH4+]
2. InChI:InChI=1/4ClH.2H3N.Pt/h4*1H;2*1H3;/q;;;;;;+2/p-2/rCl4Pt.2H3N/c1-5(2,3)4;;/h;2*1H3/q-2;;/p+2
3. InChIKey:QJIMNDWDOXTTBR-YELGGKQBAU

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 60mg/kg (60mg/kg)   Toxicology and Applied Pharmacology. Vol. 49, Pg. 41, 1979.