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13840-33-0

Basic Information
CAS No.: 13840-33-0
Name: LITHIUM HYPOCHLORITE
Molecular Structure:
Molecular Structure of 13840-33-0 (LITHIUM HYPOCHLORITE)
Formula: ClH O . Li
Molecular Weight: 58.3934
Synonyms: Hypochlorousacid, lithium salt (8CI,9CI);Lithium hypochlorite (7CI);Lithium chlorideoxide (LiClO);Lithium hypochlorite (LiClO);Lithium oxychloride;
EINECS: 237-558-1
Density: g/cm3
Melting Point: 100 ºC (Decomposes )
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: Very soluble in water (approximately 40% at 25 deg C)
Appearance: White powder with a faint chlorine odour
Hazard Symbols: Strong oxidant, may ignite organic materials.
Risk Codes: 8-22-31-34
Safety: A powerful oxidizer. An eye, skin, and mucous membrane irritant. When heated to decomposition it emits very toxic fumes of Li2O and Cl. Used for swimming pool chlorination, and as a laundry bleach. See also LITHIUM COMPOUNDS and HYPOCHLORITES.
PSA: 23.06000
LogP: 0.57070
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Chemistry

IUPAC:  Lithium hypochlorite
 Lithium hypochlorite with CAS NO.of 13840-33-0 is also called for CCRIS 4023 ; Caswell No. 528A ; EINECS 237-558-1 ; EPA Pesticide Chemical Code 014702 ; Lithium chloride oxide ; Lithium oxychloride ; Hypochlorous acid, lithium salt and so on.
Molecular Formula: ClLiO
Molecular Weight: 58.39
EINECS: 237-558-1
H bond acceptors: 1 
H bond donors: 1 
Freely Rotating Bonds: 0 
Heavy Atom Count: 3
Formal Charge: 0
Complexity: 4.8
Isotope Atom Count: 0
Defined Atom StereoCenter Count: 0
Undefined Atom StereoCenter Count: 0
Defined Bond StereoCenter Count: 0
Undefined Bond StereoCenter Count: 0
Covalently-Bonded Unit Count: 2
The molecular structure of  Lithium hypochlorite with CAS NO.of  13840-33-0:

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A powerful oxidizer. An eye, skin, and mucous membrane irritant. When heated to decomposition it emits very toxic fumes of Li2O and Cl. Used for swimming pool chlorination, and as a laundry bleach. See also LITHIUM COMPOUNDS and HYPOCHLORITES.
Hazard Codes:  OOxidizing,C Corrosive
Risk Statements:  8-22-31-34 
R8 :Contact with combustible material may cause fire. 
R22:Harmful if swallowed. 
R31 :Contact with acids liberates toxic gas. 
R34:Causes burns.
Safety Statements:  17-26-36/37/39-45 
S17:Keep away from combustible material. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR:  1471
RTECS:  NH3486000
HazardClass:  5.1
PackingGroup:  II

Standards and Recommendations

DOT Classification:  5.1; Label: Oxidizer

Specification

1.Reactivity Profile
 Lithium hypochlorite with CAS NO.of 13840-33-0 is a powerful oxidizing agent, particularly in the presence of water or at higher temperature as Lithium hypochlorite decomposes to release oxygen and chlorine gases.