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| CAS No.: | 139-40-2 |
|---|---|
| Name: | 2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine |
| Article Data: | 16 |
| Molecular Structure: | |
|
|
|
| Formula: | C9H16 Cl N5 |
| Molecular Weight: | 229.713 |
| Synonyms: | 1,3,5-Triazine-2,4-diamine,6-chloro-N,N'-bis(1-methylethyl)- (9CI); s-Triazine, 2-chloro-4,6-bis(isopropylamino)-(6CI,8CI); 2,4-Bis(isopropylamino)-6-chloro-s-triazine;2,4-Bis[(1-methylethyl)amino]-6-chloro-s-triazine;2-Chloro-4,6-bis(isopropylamino)-1,3,5-triazine;2-Chloro-4,6-bis(isopropylamino)-s-triazine;2-Chloro-4-isopropylamino-6-isopropylamino-s-triazine; Atradex; G 30028; Geigy30,028; Gesamil; Milogard; NSC 26002; Plantulin; Primatol P; Propasin;Propazin; Propazine; Propazine (herbicide); Prozinex;s-Bis(isopropylamino)chlorotriazine |
| EINECS: | 205-359-9 |
| Density: | 1.162 |
| Melting Point: | 212-214 ºC |
| Boiling Point: | 373.1 °C at 760 mmHg |
| Flash Point: | 179.4 °C |
| Solubility: | 8.6mg/L(22 oC) |
| Appearance: | Colorless powder. |
| Hazard Symbols: |
 
|
| Risk Codes: | R40;R50/53 |
| Safety: | 36/37-60-61-45-24-16-7 |
| Transport Information: | UN 3077 |
| PSA: | 62.73000 |
| LogP: | 2.31160 |
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| Conditions | Yield |
|---|---|
| With sodium hydroxide In water; toluene at 5 - 50℃; | 98.8% |
| With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 72h; | 22.2 g |
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
- 124-40-3
dimethyl amine
- 139-40-2
propazine
- 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin
| Conditions | Yield |
|---|---|
| With water; sodium carbonate for 1.5h; Heating; | 100% |
- 616-38-6
carbonic acid dimethyl ester
- 139-40-2
propazine
- 7287-19-6
2-methylthio-4,6-bis(isopropylamino)-s-triazine
| Conditions | Yield |
|---|---|
| With potassium tert-butylate; palladium diacetate; triphenylphosphine; potassium thioacetate In dimethyl sulfoxide at 120℃; Inert atmosphere; | 91% |
| With potassium tert-butylate; palladium diacetate; triphenylphosphine; potassium thioacetate In dimethyl sulfoxide at 120℃; Schlenk technique; Inert atmosphere; | 91% |
| Conditions | Yield |
|---|---|
| With N-ethyl-N,N-diisopropylamine In tetrahydrofuran for 24h; Reflux; | 85% |
- 371-40-4
4-fluoroaniline
- 139-40-2
propazine
- 92887-87-1
4,6-Di(isopropylamino)-6-(4-fluoranilino)-1,3,5-triazin
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide for 72h; Ambient temperature; | 78% |
- 141-43-5
ethanolamine
- 139-40-2
propazine
- 125101-22-6
2-(4,6-Bis-isopropylamino-[1,3,5]triazin-2-ylamino)-ethanol
| Conditions | Yield |
|---|---|
| With sodium methylate | 76% |
| Conditions | Yield |
|---|---|
| In acetone at 45℃; for 48h; | 66% |
- 68-12-2, 33513-42-7
N,N-dimethyl-formamide
- 139-40-2
propazine
A
- 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin
B
- 53736-41-7
2-cyanamino-4,6-bisisopropylamino-sym-triazine
| Conditions | Yield |
|---|---|
| With disodium cyanamide In water at 135℃; for 0.5h; | A 65% B 11% |
- 20611-81-8
disodium cyanamide
- 139-40-2
propazine
A
- 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin
B
- 53736-41-7
2-cyanamino-4,6-bisisopropylamino-sym-triazine
| Conditions | Yield |
|---|---|
| In water; N,N-dimethyl-formamide at 135℃; for 0.5h; | A 65% B 11% |
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Chemistry
MF: C9H16ClN5
MW: 229.71
Density: 1.162
EINECS: 205-359-9
Melting Point: 212-214°C
Flash Point: 179.4 °C
Storage temp: APPROX 4°C
Index of Refraction: 1.59
Appearance: Colorless powder.
Solubility in water: 5 mg/L
Enthalpy of Vaporization: 62.03 kJ/mol
Boiling Point: 373.1 °C at 760 mmHg
Vapour Pressure: 9.19E-06 mmHg at 25°C
IUPAC Name: 6-chloro-2-N,4-N-di(propan-2-yl)-1,3,5-triazine-2,4-
diamine
Synonyms: G-30028 ; Gesamil(R) ; Chembrdg-BB 5348952 ; 6-Chloro-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine ; 2-Chloro-4，6-bis(isopropylamino)-1，3，5-triazine ; 2-Chloro-4,6-bis(Iisopropylamino)-S-triazine ; 2-Chloro-4,6-bis(ispropylamino)-S-triazine ; 2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine
Following is the molecular structure of Propazine (139-40-2):
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Uses
Propazine (139-40-2)is used as Herbicide.
Toxicity Data With Reference
| 1. | eye-rbt 400 mg open | CIGET* Ciba-Geigy Toxicology Data/Indexes, 1977 .(Ciba-Geigy Corp.,Ardsley, NY.: )1977. | ||
| 2. | orl-gpg LD50:1200 mg/kg | 85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,35. | ||
| 3. | orl-mus LD50:3180 mg/kg | 85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,35. |
Safety Profile
Moderately toxic by ingestion. Moderate eye irritation. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx and Cl−.
Safety Information of Propazine (139-40-2):
Hazard Codes: Xn;N,N,Xn,T,F
Xn: Harmful .gif){kind=small}
N: Dangerous for the environment .gif){kind=small}
T: Toxic .gif){kind=small}
F: Highly Flammable .gif){kind=small}
Risk Statements: 40-50/53-39/23/24/25-23/24/25-11
40: Limited evidence of a carcinogenic effect
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
11: Highly Flammable
Safety Statements: 36/37-60-61-45-24-16-7
36/37: Wear suitable protective clothing and gloves
60: This material and/or its container must be disposed of as hazardous waste
61: Avoid release to the environment. Refer to special instructions safety data sheet
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
24: Avoid contact with skin
16: Keep away from sources of ignition - No smoking
7: Keep container tightly closed
RIDADR: UN 3077
RTECS: XY5300000