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140-56-7

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Basic Information
CAS No.: 140-56-7
Name: Fenaminosulf
Molecular Structure:
Molecular Structure of 140-56-7 (Fenaminosulf)
Formula: C8H11 N3 O3 S . Na
Molecular Weight: 251.241
Synonyms: Benzenediazosulfonicacid, p-(dimethylamino)-, sodium salt (6CI,7CI,8CI); Diazenesulfonic acid,[4-(dimethylamino)phenyl]-, sodium salt (9CI); BAY 22555; BAY 5072; Bayer22555; Bayer 5072; DAPA; DAPA (pesticide); Deksonal; Dexon; Dexon (pesticide);Dexon 70; Dexoxon; Fenaminosulf; Lesan; Sodium4-(dimethylamino)benzenediazosulfonate; Sodium[4-(dimethylamino)phenyl]diazenesulfonate; Sodiump-(dimethylamino)benzenediazosulfonate; p-(Dimethylamino)benzenediazosulfonicacid sodium salt; p-Diazodimethylaniline sodium sulfonate
EINECS: 205-419-4
Density: g/cm3
Melting Point: 200oC
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: Slightly soluble in water
Appearance: Yellow-brown crystals or brown powder.
Hazard Symbols: Toxic by ingestion.
Risk Codes: 21-25-52/53
Safety: Poison by ingestion, intravenous, and intraperitoneal routes. Experimental teratogenic effects. Human mutation data reported. Questionable carcinogen. A fungicide. When heated to decomposition it emits very toxic fumes of NOx, Na2O, and SOx.
Transport Information: UN 2811 6
PSA: 93.54000
LogP: 2.37730
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Chemistry

IUPAC Name: Sodium N-(4-dimethylaminophenyl)iminosulfamate
CAS: 140-56-7
Formula: C8H10N3NaO3S
Molecular Weight: 251.24
Molecular Structure of Sodium N-(4-dimethylaminophenyl)iminosulfamate (CAS NO.140-56-7):

Appearance: Yellow-brown crystals or brown powder.
Product Categories: fungicide

Toxicity Data With Reference

1.    

mmo-sat 25 µg/plate

    YACHDS    Yakuri to Chiryo. Pharmacology and Therapeutics. 13 (1985),4923.
2.    

mmo-esc 25 µg/plate

    YACHDS    Yakuri to Chiryo. Pharmacology and Therapeutics. 13 (1985),4923.
3.    

orl-rat LD50:60 mg/kg

    WRPCA2    World Review of Pest Control. 9 (1970),119.
4.    

ipr-rat LD50:10,300 µg/kg

    34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.1969,202.
5.    

orl-mus LDLo:140 mg/kg

    AECTCV    Archives of Environmental Contamination and Toxicology. 14 (1985),111.
6.    

ipr-mus LD50:60 mg/kg

    34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.1969,202.
7.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00143 .
8.    

ipr-dog LDLo:5 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 95 (1949),262.
9.    

orl-rbt LD50:150 mg/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/1976.
 

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 , 1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 8 , 1975,p. 147.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-101 ,1978. . EPA Genetic Toxicology Program.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Experimental teratogenic effects. Human mutation data reported. Questionable carcinogen. A fungicide. When heated to decomposition it emits very toxic fumes of NOx, Na2O, and SOx.
Safety Information about Sodium N-(4-dimethylaminophenyl)iminosulfamate (CAS NO.140-56-7):
Hazard Codes:
T:
Risk Statements about Sodium N-(4-dimethylaminophenyl)iminosulfamate (CAS NO.140-56-7):
R21: Harmful in contact with skin.
R25: Toxic if swallowed.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements about Sodium N-(4-dimethylaminophenyl)iminosulfamate (CAS NO.140-56-7):
S36/37: Wear suitable protective clothing and gloves.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S61: Avoid release to the environment. Refer to special instructions safety data sheet.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: CZ175000
HazardClass: 6.1(b)
PackingGroup: III

Specification

  The chemical synonyms of Sodium N-(4-dimethylaminophenyl)iminosulfamate (CAS NO.140-56-7) are Pehnaminosulf ; Phenaminosulf ; Sodium(4-(dimethylamino)phenyl)diazenesulfonate ; Sodium[4-(dimetylamino)phenyl]diazenesulfonate ; Sodiumfenaminosulf ; Sodiump-(dimethylamino)benzenediazosulphonate ; Sodium-p-dimethylaminobenzenediazosulphonate ; Sodium 4-dimethylaminobenzenediazosulfonate . Dust may form an explosive mixture in air. Water soluble. Closed operation, local exhaust. Recommended operating officer wearing dust mask (full cover), wearing protective clothing tape, wearing rubber gloves. Away from fire, heat source, smoking is prohibited in the workplace. Use explosion-proof ventilation systems and equipment. Avoid creating dust. Avoid contact with oxidants, acid exposure. Moving light pack light when unloaded to prevent damage to packaging and containers.