CAS No.14024-63-6,Zinc(II) acetylacetonate Suppliers

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Basic Information

Molecular Structure:
CAS No.:	14024-63-6
Name:	Zinc(II) acetylacetonate
Article Data:	23

Formula:	C₁₀H₁₄O₄Zn
Molecular Weight:	263.609
Synonyms:	Zinc,bis(2,4-pentanedionato)- (6CI,8CI);Zinc, bis(2,4-pentanedionato-O,O')-,(T-4)-;Zinc, bis(2,4-pentanedionato-kO,kO')-, (T-4)- (9CI);Aldrich 48,099-1;Bis(2,4-pentanedionato)zinc;Bis(acetylacetonato)zinc;Bis(pentanedionato)zinc;NSC 18472;Nacem Zinc;Tegokat 623;Zinc acetylacetonate;Zinc acetylacetonechelate;Zinc bis(2,4-pentanedionate);Zinc bis(acetylacetonate);Zincbis(acetylacetone);Zinc diacetoacetate;
EINECS:	237-860-3
Density:	1.544[at 20℃]
Melting Point:	124-126 °C
Boiling Point:	129-131 °C (10 mmHg)
Solubility:	9.1g/L at 20℃
Appearance:	White to ivory powder
Hazard Symbols:	Xn
Risk Codes:	22-36/37/38
Safety:	26-37/39
PSA:	68.28000
LogP:	1.10650

Synthetic route

: 123-54-6
acetylacetone

: 7440-66-6
zinc

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
With tert-butylammonium hexafluorophosphate(V) In acetylacetone Electrochem. Process; tetra-n-butylammonium hexafluorophosphate added to dry acetylacetone, Cuelectrode, 300 V, 10-50 mA, ca. 10 h; solid filtered off, washed twice with hexane and with petroleum ether;	86.8%
With (C4H9)4NBF4 In acetonitrile Electrolysis; reaction of Zn anode with 30% soln. of acetylacetone in CH3CN with added 0.1 M Bu4NBF4, Pt cathode; addn. of ether-acetone mixture;; pptn.; drying in vacuo;;

: 1118-67-8
sodium (Z)-4-oxopent-2-en-2-olate

: 7646-85-7
zinc(II) chloride

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) mechanically activated solid state synthesis; eccentric-type ball mill, mixt. was treated for 30 min; mixt. was sepd. by vacuum sublimation on an oil bath at 120-160°Cand pressure of 13.3 Pa; elem. anal., XRD;	70.6%

: 743369-26-8
zinc(II) carbonate

: 123-54-6
acetylacetone

: 7440-66-6
zinc

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
With tetraethylammonium chloride In acetonitrile byproducts: hydrogen; Electrolysis; electrolyis of Hacac and ZnCO3 in temp.-controlled electrochem. cell equipped with Zn anode and cathode for 193 min; using 0.1 M soln. of Et4NClin MeCN as electrolyte; concn. to pasty state under heating on magnetic stirrer and cooling to room temp.; extn. with ether; filtration, concn. of filtrate; elem. anal.;	63.6%

...Expand

: 557-34-6
zinc diacetate

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
With acetylacetone In water heated zinctate with water and acetylacetone until salt dissolution, filtered, cooled down; precipitate filtered out, washed (water), dried, recrystn. (hexane-chloroform);	63%

: zinc hydroxide

: 123-54-6
acetylacetone

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
Neat (no solvent);

: Zn(OC(CH3)CHC(CH3)O)2(H2O)

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
In neat (no solvent) dried in vac. over P2O5 for about 1 d;

: 123-54-6
acetylacetone

: zinc(II) oxide

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
In not given react. ZnO with freshly distilled acetylacetone (as in: M. Hassanein, I.F. Hewaidy, Z. Anorg. Allg. Chem. 318 (1962) 212);

: 7733-02-0
zinc(II) sulfate

: 123-54-6
acetylacetone

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
In sodium hydroxide mixing soln. of HPD in aq. NaOH and aq. soln. of ZnSO4; dehydrating crystalline hydrate (vacuum, P2O5, 4h);

: copper acetylacetonate

: 557-20-0
diethylzinc

A: 14024-63-6
zinc(II) acetylacetonate

B: 74-85-1
ethene

C: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

Conditions

Conditions	Yield
In benzene byproducts: C2H6; room temp., large excess of butadiene to prevent copper pptn.,; not isolated;

...Expand

: 557-34-6
zinc diacetate

: 123-54-6
acetylacetone

: 14024-63-6
zinc(II) acetylacetonate

Conditions

Conditions	Yield
In ethanol acetyl acetone added to soln. of Zn acetate (stirring); kept 8 h; product filtered off; washed with ethanol; dried (vac.);
In ethanol acetylacetone added to ethanol soln. of zinc acetate under stirring for 8 h; ppt. washed (ethanol) for several times, vacuum-dried;

Raw Materials

123-54-6

557-34-6

Downstream Products

557-20-0

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Chemistry

Molecular Structure of Zinc acetoacetonate (CAS NO.14024-63-6):

IUPAC Name: Zinc pentane-2,4-dione
Canonical SMILES: CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Zn+2]
InChI: InChI=1S/2C5H7O2.Zn/c2*1-4(6)3-5(2)7; /h2*3H,1-2H3; /q2*-1; +2
InChIKey: NHXVNEDMKGDNPR-UHFFFAOYSA-N
Molecular Weight: 263.62476 [g/mol]
Molecular Formula: C₁₀H₁₄O₄Zn
H-Bond Donor: 0
H-Bond Acceptor: 6
EINECS: 237-860-3
Boiling point: 129-131 °C (10 mmHg)
Flash Point: 71.9 °C
Appearance: White to ivory powder
Melting Point: 124-126 °C
Classification Code: Mutation data
Product Categories: Organometallics; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Synthetic Organic Chemistry; Transition Metal Compounds; Zn (Zinc) Compounds

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	intraperitoneal	50mg/kg (50mg/kg)		Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. Vol. PH43-64-886,

Consensus Reports

Zinc and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of ZnO.
Safety Information of Zinc acetoacetonate (CAS NO.14024-63-6):
Hazard Codes: Harmful Xn
Risk Statements: 22-36-36/37/38
R22:Harmful if swallowed.
R36:Irritating to eyes.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 20-39-37/39-26
S20:When using, do not eat or drink.
S37/39:Wear suitable gloves and eye/face protection.
S39:Wear eye / face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RTECS: ZH0917500
TSCA: Yes

Specification

Zinc acetoacetonate (CAS NO.14024-63-6), its Synonyms are Bis(2,4-pentanedionato)zinc ; Bis(acetylacetonato)zinc ; Bis(pentanedionato)zinc ; Zinc 2,4-pentanedione ; Zinc acetylacetonate ; Zinc acetylacetone chelate ; Zinc bis(2,4-pentanedionate) ; Zinc bis(acetylacetonate) ; Zinc bis(acetylacetone) ; Zinc diacetoacetate ; Zinc(II) acetylacetonate ; Zinc, bis(2,4-pentanedionato)di- ; Zinc, bis(2,4-pentanedionato-O,O')- ; Zinc, bis(2,4-pentanedionato-O,O')-, (T-4)- .