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142-77-8

Basic Information
CAS No.: 142-77-8
Name: 9-Octadecenoic acid(9Z)-, butyl ester
Article Data: 47
Cas Database
Molecular Structure:
Molecular Structure of 142-77-8 (9-Octadecenoic acid(9Z)-, butyl ester)
Formula: C22H42O2
Molecular Weight: 338.574
Synonyms: Kesscoflex BO;Plasthall 914;Wilmar ButylOleate;Witcizer 100;Witcizer 101;n-Butyl oleate;9-Octadecenoicacid (Z)-, butyl ester;Oleic acid, butyl ester (6CI,7CI,8CI);Advaplast 42;Butyl (Z)-9-octadecenoate;Butyl cis-9-octadecenoate;Hallco C503;Kemester 4000;Kessco 554;SINOCHEM BOT;
EINECS: 205-559-6
Density: 0.87 g/cm3
Melting Point: -55 °C
Boiling Point: 414.9 °C at 760 mmHg
Flash Point: 89.7 °C
Solubility: N/A
Appearance: N/A
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36
Transport Information: N/A
PSA: 26.30000
LogP: 7.36720
Synthetic route
112-80-1

cis-Octadecenoic acid

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions
ConditionsYield
Stage #1: cis-Octadecenoic acid; butan-1-ol With 1-octyl-3-methyl-imidazolium hydrogen sulfate at 28℃; for 0.166667h; Green chemistry;
Stage #2: With 1-butyl-3-methylimidazolium Tetrafluoroborate at 100℃; for 8h; Reagent/catalyst; Temperature; Inert atmosphere; Green chemistry;
95.2%
With mesoporous silica modified Fe3O4 nanoparticle fabricated by 3-sulfopropyl-1-(3-propyltrimethoxysilane) imida-zolium hydrogen sulfate at 109.84℃; for 4h; Green chemistry;91.5%
at 30℃; for 72h; Corynebacterium sp. S-401, phosphate buffer;25%
112-62-9

Methyl oleate

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions
ConditionsYield
ruthenium trichloride at 116.9℃; for 11h;
With sodium butanolate at 25℃; for 1.5h;
With CpLIP2 from Candida parapsilosis In aq. phosphate buffer at 30℃; for 0.25h; pH=6.5; Concentration; Reagent/catalyst; Enzymatic reaction;
542-69-8

1-iodo-butane

112-80-1

cis-Octadecenoic acid

142-77-8

oleic acid butyl ester

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide In methanol for 0.25h; Ambient temperature;
112-80-1

cis-Octadecenoic acid

71-36-3

butan-1-ol

A

142-77-8

oleic acid butyl ester

B

7732-18-5

water

Conditions
ConditionsYield
Equilibrium constant; Enthalpie der Reaktion;
109-65-9

1-bromo-butane

silver oleate

silver oleate

142-77-8

oleic acid butyl ester

112-80-1

cis-Octadecenoic acid

7664-93-9

sulfuric acid

71-36-3

butan-1-ol

A

142-77-8

oleic acid butyl ester

B

7732-18-5

water

Conditions
ConditionsYield
Equilibrium constant; Enthalpie der Reaktion;
122-32-7

trioleoylglycerol

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions
ConditionsYield
With sulfuric acid at 30℃; Kinetics;
With C2F6NO4S2(1-)*C20H39N2(1+) at 60℃; Enzymatic reaction;
Conditions
ConditionsYield
With immobilized cp283 Candida antarctica lipase B In tert-Amyl alcohol at 55℃; Enzymatic reaction;
2566-91-8

epoxidized methyl oleate

107-66-4

dibutyl phosphate

A

112-62-9

Methyl oleate

B

142-77-8

oleic acid butyl ester

C

1842-70-2

methyl 9-oxooctadecanoate

D

10-Butoxy-9-hydroxy-octadecanoic acid methyl ester

E

C23H45O6P

Conditions
ConditionsYield
With titanium(IV) oxide at 120℃; for 72h; Reagent/catalyst;
111-62-6

oleic acid ethyl ester

142-77-8

oleic acid butyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CpLIP2 from Candida parapsilosis / aq. phosphate buffer / 0.25 h / 30 °C / pH 6.5 / Enzymatic reaction
2: CpLIP2 from Candida parapsilosis / aq. phosphate buffer / 0.25 h / 30 °C / pH 6.5 / Enzymatic reaction
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Chemistry

BUTYL OLEATE's Molecular formula: C22H42O2
BUTYL OLEATE's Molar mass: 338.57
EINECS: 205-559-6
Melting point: -55°C
Boiling point: 273°C 13mm
density: 0.88 g/mL at 25 °C
refractive index: 1.4480
Flash point: 180℃
storage temp.: 2-8°C
Synonyms: 9-Octadecenoic acid (Z)-, butyl ester; Butyl oleate; OLEIC ACID N-BUTYL ESTER; (Z)-9-Octadecenoic acid butyl ester

Uses

BUTYL OLEATE is used as plasticizers, solvents, lubricants and water-proofing agent.

Toxicity Data With Reference

1.   

skn-rbt 500 mg/24H MOD

   FCTXAV    Food and Cosmetics Toxicology. 17 (1979),241.
2.   RTECS  RG3711000

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A skin irritant. Combustible when exposed to heat or flame. To fight fire, use CO2, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS; n-BUTYL ALCOHOL; and OLEIC ACID.
Hazard Codes:  Xi: Harmful
Risk Statements: 36/37/38: Irritating to eyes, respiratory system and skin 
Safety Statements: 26-36:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing
WGK Germany: 1