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143-18-0

Basic Information
CAS No.: 143-18-0
Name: Potassium oleate
Article Data: 7
Molecular Structure:
Molecular Structure of 143-18-0 (Potassium oleate)
Formula: C18H33KO2
Molecular Weight: 320.557
Synonyms: 9-Octadecenoicacid (9Z)-, potassium salt (9CI);9-Octadecenoic acid (Z)-, potassium salt;Oleic acid, potassium salt (8CI);Century 1005;FR 14;FR 14(emulsifier);Nonsoul OK 1;Norfox KO;OS Soap;Potassium cis-9-octadecenoate;Potassium cis-9-octadecenoic acid;9-Octadecenoicacid (9Z)-, potassium salt (1:1);Trenamine D 200;TrenamineD 201;
EINECS: 205-590-5
Density: >1.1 g/cm3
Melting Point: 235 - 240oC
Boiling Point: 360 °C at 760 mmHg
Flash Point: 270.1 °C
Solubility: Soluble in water
Appearance: brown solid or clear to amber liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36
PSA: 40.13000
LogP: 4.77380
Synthetic route
60-29-7

diethyl ether

67-66-3

chloroform

oleic acid ; compound of potassium oleate with oleic acid

A

112-80-1

cis-Octadecenoic acid

B

143-18-0

potassium oleate

112-80-1

cis-Octadecenoic acid

143-18-0

potassium oleate

Conditions
ConditionsYield
With potassium hydroxide In methanol
With potassium hydroxide at 80℃; pH=10.4;
With potassium hydroxide In methanol at 65℃; for 0.000833333h; Industrial scale;
With potassium acetate at 80℃; for 0.5h;
143-18-0

potassium oleate

106-95-6

allyl bromide

Conditions
ConditionsYield
tetrabutylammomium bromide In dichloromethane at 20 - 22℃; for 40h;79%

2,2,2-trichloroethyl (2-(tert-butylcarbamoyl)phenyl)sulfamate

143-18-0

potassium oleate

N-(tert-butyl)-2-oleamidobenzamide

Conditions
ConditionsYield
In chlorobenzene at 120℃; for 10h;64%
590-02-3

butyl chloroacetate

143-18-0

potassium oleate

oleoyloxy-acetic acid butyl ester

Conditions
ConditionsYield
With xylene at 170℃;
5445-17-0

Methyl 2-bromopropionate

143-18-0

potassium oleate

2-oleoyloxy-propionic acid methyl ester

Conditions
ConditionsYield
With xylene at 170℃;
111-25-1

1-bromo-hexane

143-18-0

potassium oleate

20290-84-0

cis-9-octadecenoic acid hexyl ester

Conditions
ConditionsYield
With ethanol
54819-86-2

n-butyl α-chloropropionate

143-18-0

potassium oleate

2-oleoyloxy-propionic acid butyl ester

Conditions
ConditionsYield
With xylene at 170℃;
143-18-0

potassium oleate

13985-41-6

9-hydroxy-10-oxooctadecanoic acid

Conditions
ConditionsYield
With potassium permanganate
143-18-0

potassium oleate

2632-61-3, 13985-22-3, 13985-23-4

(+/-)-threo-9-chloro-10-hydroxy-octadecanoic acid

Conditions
ConditionsYield
With sodium hypochlorite; carbon dioxide; water
Raw Materials
112-80-1
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Chemistry

Molecule structure of Potassium oleate (CAS NO.143-18-0):

IUPAC Name: Potassium (Z)-octadec-9-enoate 
Molecular Weight: 320.55172 g/mol
Molecular Formula: C18H33KO2 
Flash Point: 270.1 °C
Enthalpy of Vaporization: 66.53 kJ/mol
Boiling Point: 360 °C at 760 mmHg
Vapour Pressure: 3.7E-06 mmHg at 25 °C
H-Bond Acceptor: 2
Rotatable Bond Count: 15
Exact Mass: 320.211762
MonoIsotopic Mass: 320.211762
Topological Polar Surface Area: 40.1
Heavy Atom Count: 21
Canonical SMILES: CCCCCCCCC=CCCCCCCCC(=O)[O-].[K+]
Isomeric SMILES: CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
InChI: InChI=1S/C18H34O2.K/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h9-10H,2-8,11-17H2,1H3,(H,19,20);/q;+1/p-1/b10-9-;
InChIKey: MLICVSDCCDDWMD-KVVVOXFISA-M
EINECS: 205-590-5
Product Categories: Classes of Metal Compounds; K (Potassium) Compounds (excluding simple potassium salts); Typical Metal Compounds

Uses

 Potassium oleate (CAS NO.143-18-0) is a potassium type catalyst which is widely used in poly-isocyanate bubble reaction.

Toxicity Data With Reference

1.    

eye-rbt 12 mg/48H

   

JANCA2    Journal of the Association of Official Analytical Chemists. 56 (1973),905.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 1
RTECS: RK1150000
An eye irritant. When heated to decomposition it emits toxic fumes of K2O.

Specification

 Potassium oleate (CAS NO.143-18-0) is also named as 9-Octadecenoic acid (Z)-, potassium salt ; Caswell No. 698B ; EPA Pesticide Chemical Code 079095 ; HSDB 5643 ; Oleic acid, potassium salt ; Potassium 9-octadecenoate, (Z)- ; Potassium cis-9-octadecenoate ; Potassium cis-9-octadecenoic acid ; Trenamine D-200 ; Trenamine D-201 ; UNII-74WHF607EU . Potassium oleate (CAS NO.143-18-0) is brown solid or clear to amber liquid with a soapy odor. It can sinks and mix slowly with water. Salts, basic, such as Potassium oleate , generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Inhalation of dust causes irritation of nose and throat, coughing, and sneezing. Ingestion causes mild irritation of mouth and stomach. Contact with eyes causes irritation. Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.