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| CAS No.: | 14324-55-1 |
|---|---|
| Name: | Ethyl ziram |
| Article Data: | 7 |
| Molecular Structure: | |
|
|
|
| Formula: | C10H20N2S4Zn |
| Molecular Weight: | 361.936 |
| Synonyms: | Perkacit ZDEC-PDR;SoxinolEZ;Vulkacit LDA;Vulkazit LDA;ZDC;Zinc bis(N,N-diethyldithiocarbamate);Zinc diethylcarbamodithioate;Zinc, bis(diethylcarbamodithioato-kS,kS')-, (T-4)- (9CI);Accel PZ;Accelerator ZDC;Bis(N,N-diethyldithiocarbamato)zinc;EZ;Ethazate;Ethylzimate;Karbamat ETS; |
| EINECS: | 238-270-9 |
| Density: | 1.48 g/cm3 |
| Melting Point: | 178-181 °C(lit.) |
| Boiling Point: | 176.4 °C at 760 mmHg |
| Flash Point: | 60.5 °C |
| Solubility: | Insoluble in water. Soluble in benzene carbon disulfide and organic liquids. |
| Appearance: | white to off white powder |
| Hazard Symbols: |
 Xn, N
|
| Risk Codes: | 22-36/37/38-43-50/53 |
| Safety: | 24-37-60-61 |
| Transport Information: | UN 3077 9/PG 3 |
| PSA: | 70.66000 |
| LogP: | 2.31750 |
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Specification
The Zinc diethyl dithiocarbamate , with cas registry number of 14324-55-1, has many other registry numbers including 115028-55-2, 120092-57-1, 136-94-7, 14460-21-0, 15465-13-1, 18445-58-4, 32733-02-1, 39456-86-5, 880359-15-9, 92481-10-2. Its IUPAC name is also called zinc N,N-diethylcarbamodithioate . Its systematic name is zinc bis(diethylcarbamodithioate) . It belongs to categories of (1)Organometallics; (2)Classes of Metal Compounds; (3)Transition Metal Compounds; (4)Zn (Zinc) Compounds. It is soluble in ether , carbon disulfide , benzene and chloroform , slightly soluble in alcohol , not dissolve in water .
Physical properties of Zinc diethyl dithiocarbamate : (1) ACD/LogP: 1.81 ; (2) # of Rule of 5 Violations: 0 ; (3) ACD/LogD (pH 5.5): 0.86 ; (4) ACD/LogD (pH 7.4): -0.95 ; (5) ACD/BCF (pH 5.5): 1.56 ; (6) ACD/BCF (pH 7.4): 1 ; (7) ACD/KOC (pH 5.5): 25.7 ; (8) ACD/KOC (pH 7.4): 1 ; (9) #H bond acceptors: 1 ; (10) #H bond donors: 0 ; (11) #Freely Rotating Bonds: 2 ; (12) Enthalpy of Vaporization: 41.27 kJ/mol ; (13) Vapour Pressure: 1.1 mmHg at 25°C.
Uses of Zinc diethyl dithiocarbamate : (1) It is mainly used as an ultra accelerator for natural rubber and synthetic rubber, especially for butyl rubber, EPDM rubber and latex. (2) It is also an analytical reagent.
Preparation of Zinc diethyl dithiocarbamate : First, Sodium dibutyldithiocarbamate is prepared by reaction of condensation by carbon disulfide with diethylamine . Then, Zinc diethyl dithiocarbamate is obtained by replacement reaction of zinc sulfate (or zinc chloride) with Sodium dibutyldithiocarbamate .
When you are using this chemical, please be cautious about it as the following:
The Zinc diethyl dithiocarbamate irritate to eyes, respiratory system and skin. It is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. And it is harmful if swallowed. When use it, wear suitable gloves and avoid contact with skin. This material and its container must be disposed of as hazardous waste. Avoid release to the environment.
You can still convert the following datas into molecular structure:
(1) SMILES:[Zn+2].S=C([S-])N(CC)CC.[S-]C(=S)N(CC)CC;
(2) InChI:InChI=1/2C5H11NS2.Zn/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2;
(3) InChIKey:RKQOSDAEEGPRER-NUQVWONBAG
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 142mg/kg (142mg/kg) | Kobunshi Kako. Polymer Applications. Vol. 26, Pg. 358, 1977. | |
| mouse | LD50 | oral | 1400mg/kg (1400mg/kg) | Farmakologiya i Toksikologiya Vol. 32, Pg. 356, 1969. | |
| rabbit | LD50 | oral | 400mg/kg (400mg/kg) | International Polymer Science and Technology. Vol. 3, Pg. 93, 1976. | |
| rat | LD50 | oral | 700mg/kg (700mg/kg) | Farmakologiya i Toksikologiya Vol. 32, Pg. 356, 1969. |