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CAS No.: | 14325-24-7 |
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Name: | MANGANESE PHTHALOCYANINE |
Article Data: | 19 |
Molecular Structure: | |
Formula: | C32H16MnN8 |
Molecular Weight: | 567.471 |
Synonyms: | Manganese,[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Manganese, [phthalocyaninato(2-)]-(6CI,7CI,8CI);29H,31H-Phthalocyanine, manganese complex;(Phthalocyaninato)manganese;KJB 006;Manganese phthalocyanine;Manganese(II)phthalocyanine;[Phthalocyaninato(2-)]manganese; |
Melting Point: | >300 °C |
Solubility: | Soluble in pyridine, chloronaphthalene, and conc. sulfuric acid. Insoluble in water. |
Safety: | 22-24/25 |
PSA: | 84.02000 |
LogP: | 1.46440 |
manganese (II) acetate tetrahydrate
phthalonitrile
manganese(II) phthalocyanin
Conditions | Yield |
---|---|
In ethanol at 190℃; for 3h; Autoclave; High pressure; Green chemistry; | 45% |
In ethanol at 190℃; for 1h; Temperature; Solvent; Autoclave; | 40% |
Conditions | Yield |
---|---|
With (NH4)2Mo2O7 In neat (no solvent) other Radiation; mixt. of O-phthalic anhydride, urea, metal salt and (NH4)2Mo2O7 irradiated in microwave oven at 460W for 8 min. the at 800W for 8 min, cooling to room temp.; washed (H2O, acetone, MeOH, 6M HCl), reflux with acetone, MeOH and CHCl3resp. about 12 h; elem. anal.; | 31% |
Conditions | Yield |
---|---|
With I2 In neat (no solvent) tube was loaded with ligand, Mn, I2 and (NH4)6Mo7O24*4H2O under N2, tube was immersed in a 300°C salt bath, after a few min mixt. was solidified, mixt. was left at 300°C for 6 h, cooled; powder was sublimed in a tube furnace in vac. over 2 d at 480°C, crude ppt. was resublimed in vac. at <=460°C (caution: unsublimed material is pyrophoric); elem. anal.; | 21% |
oxovanadium phthalocyanine
manganese(II) phthalocyanin
Conditions | Yield |
---|---|
With imidazole In N,N-dimethyl acetamide soln. of complex in DMA was degassed, imidazole was added, 10 min; product was not isolated; analyzed by ESR or UV; |
Conditions | Yield |
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In not given react. of phthalonitrile with Mn(2+); washing, sublimation; |
Conditions | Yield |
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In methanol React. at 65-100°C, 9-11.5 kbar for 1.75-18 h in presence of hydroquinone.; Extg. with MeOH and acetone, sublimed in vac.; | 2-50 |
Mn(OH)-phthalocyanine
manganese(II) phthalocyanin
Conditions | Yield |
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In not given Irradiation (UV/VIS); |
(phthalocyaninato)bis(pyridine)manganese(II)
manganese(II) phthalocyanin
Conditions | Yield |
---|---|
In neat (no solvent) above 180°C; |
manganese(II) phthalocyanin
Conditions | Yield |
---|---|
In tetrahydrofuran; N,N-dimethyl-formamide Irradiation (UV/VIS); |
Conditions | Yield |
---|---|
With ammonium heptamolybdate; urea Microwave irradiation; |
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The CAS register number of Manganese(II) phthalocyanine is 14325-24-7. It also can be called as Manganese, (29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32)-, (SP-4-1)- and the systematic name about this chemical is 29H,31H-phthalocyanine, manganese(2+) salt (1:1). The molecular formula about this chemical is C32H16MnN8 and the molecular weight is 567.46. It belongs to the Organometallics. When you are using it, please avoid contact with skin and eyes and do not breathe dust. This chemical is a compound of manganese and phthalocyanine.
Physical properties about Manganese(II) phthalocyanine are: (1)#H bond acceptors: 8; (2)#H bond donors: 2; (3)Polar Surface Area: 108.92Å2; (4)H-Bond Acceptor: 8; (5)Tautomer Count: 3; (6)Exact Mass: 569.103492; (7)MonoIsotopic Mass: 569.103492; (8)Topological Polar Surface Area: 53.4; (9)Heavy Atom Count: 41; (10)Formal Charge: -4; (11)Complexity: 1310; (12)Undefined Atom StereoCenter Count: 2; (13)Undefined Bond StereoCenter Count: 4; (14)Covalently-Bonded Unit Count: 2.
You can still convert the following datas into molecular structure:
(1)SMILES: [Mn+2].n1c2nc8nc(nc6nc(nc5nc(nc1c3ccccc23)c4ccccc45)c7ccccc67)c9ccccc89
(2)InChI: InChI=1/C32H18N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H,(H2,33,34,35,36,37,38,39,40);/q;+2
(3)InChIKey: IWZYXAUFAANREW-UHFFFAOYAA
(4)Std. InChI: InChI=1S/C32H18N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H,(H2,33,34,35,36,37,38,39,40);/q;+2
(5)Std. InChIKey: IWZYXAUFAANREW-UHFFFAOYSA-N