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| CAS No.: | 14642-79-6 |
|---|---|
| Name: | BENZYLOXYTRIMETHYLSILANE |
| Molecular Structure: | |
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| Formula: | C10H16OSi |
| Molecular Weight: | 180.322 |
| Synonyms: | Silane,(benzyloxy)trimethyl- (6CI,7CI,8CI);Silane, trimethyl(phenylmethoxy)- (9CI);(Benzyloxy)trimethylsilane;Benzyl alcohol trimethylsilyl ether;Benzyltrimethylsilyl ether;Phenyl(trimethylsiloxy)methane;Trimethyl(benzyloxy)silane;Trimethyl(phenylmethoxy)silane; |
| Density: | 0.913 g/cm3 |
| Boiling Point: | 204.6 °C at 760 mmHg |
| Flash Point: | 73.9 °C |
| Appearance: | Clear very pale yellow liquid |
| Hazard Symbols: | R36/37/38:; |
| Risk Codes: | 36/37/38 |
| Safety: | 26-36/37/39-24/25-23 |
| PSA: | 9.23000 |
| LogP: | 3.03810 |
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Specification
The Benzyloxytrimethylsilane, with CAS registry number 14642-79-6, has the systematic name of (benzyloxy)(trimethyl)silane. Besides this, it is also called Silane, trimethyl(phenylmethoxy)-. This chemical is a kind of clear very pale yellow liquid. When you store this chemical, you should ensure good ventilation/exhaustion at the workplace.
Physical properties of Benzyloxytrimethylsilane: (1)ACD/LogP: 3.40; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.4; (4)ACD/LogD (pH 7.4): 3.4; (5)ACD/BCF (pH 5.5): 224.18; (6)ACD/BCF (pH 7.4): 224.18; (7)ACD/KOC (pH 5.5): 1675.58; (8)ACD/KOC (pH 7.4): 1675.58; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 9.23 Å2; (13)Index of Refraction: 1.474; (14)Molar Refractivity: 55.53 cm3; (15)Molar Volume: 197.3 cm3; (16)Polarizability: 22.01×10-24cm3; (17)Surface Tension: 25.2 dyne/cm; (18)Enthalpy of Vaporization: 42.28 kJ/mol; (19)Vapour Pressure: 0.373 mmHg at 25°C.
Preparation: this chemical can be prepared by phenylmethanol and allyl-trimethyl-silane. This reaction will need reagent triflic acid and solvent CCl4. The yield is about 98%.
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Uses of Benzyloxytrimethylsilane: it can be used to produce benzaldehyde. This reaction will need reagent benzyltriphenylphosphonium chlorate and solvent acetonitrile. The reaction time is 0.25 hour(s). The yield is about 100%.
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When you are using this chemical, please be cautious about it as the following:
The Trimesic acid irritates to eyes, respiratory system and skin, so please avoid contact with skin and eyes and do not breathe vapour. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: O([Si](C)(C)C)Cc1ccccc1
(2)InChI: InChI=1/C10H16OSi/c1-12(2,3)11-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
(3)InChIKey: AOKMFXQCRBQJOP-UHFFFAOYAR
(4)Std. InChI: InChI=1S/C10H16OSi/c1-12(2,3)11-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
(5)Std. InChIKey: AOKMFXQCRBQJOP-UHFFFAOYSA-N