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1474-78-8

Basic Information
CAS No.: 1474-78-8
Name: Ethyl diethoxyphosphinylformate
Article Data: 13
Molecular Structure:
Molecular Structure of 1474-78-8 (Ethyl diethoxyphosphinylformate)
Formula: C7H15 O5 P
Molecular Weight: 210.167
Synonyms: Formicacid, phosphono-, triethyl ester (7CI,8CI); Phosphinecarboxylic acid,diethoxy-, ethyl ester, oxide (9CI); Diethyl (ethoxycarbonyl)phosphonate;Diethyl carbethoxyphosphonate; Ethyl diethylphosphonoformate; NSC 108684;Triethyl carboxyphosphonate; Triethyl phosphonoformate
EINECS: 216-016-8
Density: 1.11
Boiling Point: 135 ºC (12 mmHg)
Flash Point: >110 ºC
Appearance: Clear, colorless liquid.
Hazard Symbols: Xi
Risk Codes: 36/37/38-43
Safety: S24/25
PSA: 71.64000
LogP: 2.40900
Synthetic route
541-41-3

chloroformic acid ethyl ester

122-52-1

triethyl phosphite

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
91%
30410-95-8

dimethoxymethyl phosphonic acid dimethyl ester

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
With N-Bromosuccinimide In benzene for 1h; Heating; argon atmosphere;80%
17997-33-0

diethyl(diethoxymethyl)phosphonate

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
With N-Bromosuccinimide In benzene for 1h; Heating;80%
With di-tert-butyl peroxide In chlorobenzene at 120℃; Rate constant; Mechanism; Product distribution; various solvents, various temperature;
2303-76-6, 118080-94-7

sodium diethyl phosphite

541-41-3

chloroformic acid ethyl ester

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
With diethyl ether
With Petroleum ether
64-17-5

ethanol

20537-54-6

N,N'-Bis-(O,O-diaethyl-phosphonocarbonyl)-sulfonyldiamid

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
for 13h; Heating;
16540-25-3

oxophosphonoacetic acid triethyl ester

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
at 150℃;
998-02-7

Tris-aethoxycarbonyl-phosphorotrithioit

541-41-3

chloroformic acid ethyl ester

1474-78-8

triethyl phosphonoformate

4373-18-6

tris(ethoxythiocarbonyl) phosphorotrithioite

541-41-3

chloroformic acid ethyl ester

1474-78-8

triethyl phosphonoformate

34909-25-6

diethyl <(ethylenedioxy)methyl>phosphonate

1474-78-8

triethyl phosphonoformate

Conditions
ConditionsYield
With di-tert-butyl peroxide In chlorobenzene at 120℃; Rate constant; Mechanism; Product distribution; various solvents, various temperature;
1474-78-8

triethyl phosphonoformate

99-61-6

3-nitro-benzaldehyde

621-19-2

(E)-ethyl 3-(3-nitrophenyl)acrylate

Conditions
ConditionsYield
With lithium hydroxide In tetrahydrofuran at 20℃; Horner-Wadsworth-Emmons Olefination;97%
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  • Ethyl diethoxyphosphinylformate CAS NO.1474-78-8  CAS NO.1474-78-8

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Chemistry

Molecular Structure:

Molecular Formula: C7H15O5P
Molecular Weight: 210.1648
IUPAC Name: Ethyl diethoxyphosphorylformate
Synonyms of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): AI3-18561 ; Diethyl carbethoxyphosphonate ; Diethyl ethoxycarbonylphosphonate ; EINECS 216-016-8 ; Formic acid, phosphono-, triethyl ester ; NSC 108684 ; Phosphinecarboxylic acid, diethoxy-, ethyl ester, oxide ; Triethyl carboxyphosphonate ; Triethyl phosphonoformate ; Triethyl phosphonomethanoate ; Diethyoxyphosphinecarboxylic acid, ethyl ester, oxide ; Phosphinecarboxylic acid, 1,1-diethoxy-, ethyl ester, 1-oxide
CAS NO: 1474-78-8
Product Categories: Organic Building Blocks ; Phosphonates/Phosphinates ; Phosphorus Compounds 
Index of Refraction: 1.419
Molar Refractivity: 46.61 cm3
Molar Volume: 184.4 cm3
Surface Tension: 34.4 dyne/cm
Density: 1.139 g/cm3
Flash Point: 128 °C
Enthalpy of Vaporization: 50.28 kJ/mol
Boiling Point: 264.9 °C at 760 mmHg
Vapour Pressure of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): 0.00947 mmHg at 25°C

Safety Profile

Hazard Codes of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): IrritantXi
Risk Statements: 36/37/38 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25-36/37-26 
S24/25: Avoid contact with skin and eyes. 
S36/37: Wear suitable protective clothing and gloves. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3