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1476-11-5

Basic Information
CAS No.: 1476-11-5
Name: cis-1,4-Dichloro-2-butene
Article Data: 35
Molecular Structure:
Molecular Structure of 1476-11-5 (cis-1,4-Dichloro-2-butene)
Formula: C4H6Cl2
Molecular Weight: 124.998
Synonyms: 2-Butene,1,4-dichloro-, (Z)- (8CI);(2Z)-1,4-Dichloro-2-butene;(Z)-1,4-Dichlorobutene;1,4-Dichloro-cis-2-butene;cis-1,2-Bis(chloromethyl)ethene;2-Butene,1,4-dichloro-, (2Z)-;
EINECS: 216-021-5
Density: 1.126 g/cm3
Melting Point: -48 °C
Boiling Point: 155.5 °C at 760 mmHg
Flash Point: 54.4 °C
Solubility: Not miscible or difficult to mix in water. Soluble in alcohol, ether, acetone and benzene.
Appearance: light-yellow clear liquid
Hazard Symbols: VeryT+,DangerousN
Risk Codes: 45-24/25-26-34-50/53
Safety: 53-26-28-36/37/39-45-60-61
Transport Information: UN 3390 6.1/PG 1
PSA: 0.00000
LogP: 2.02020
Synthetic route
6117-80-2

1,4-butenediol

1476-11-5

Z-1,4-dichlorobutene

Conditions
ConditionsYield
With 1,2,3-Benzotriazole; thionyl chloride In dichloromethane at 20℃; Substitution;94%
With thionyl chloride at 20℃; for 16h; Cooling with ice;84%
With thionyl chloride at 20℃; for 16.66h; Cooling with ice; Inert atmosphere;84%
1953-56-6, 70886-56-5, 2303-47-1

(Z)-but-2-ene-1,4-diyl dimethanesulfonate

1476-11-5

Z-1,4-dichlorobutene

Conditions
ConditionsYield
With calcium chloride In dimethyl sulfoxide for 3h; Ambient temperature;60%
1708-29-8

2,5-dihydrofuran

1476-11-5

Z-1,4-dichlorobutene

Conditions
ConditionsYield
With thionyl chloride; zinc(II) chloride at 80 - 85℃;
With hydrogenchloride at 90℃; for 4h;4.2 g
106-99-0

buta-1,3-diene

A

1476-11-5

Z-1,4-dichlorobutene

B

110-57-6

trans-1,4-dichlorobut-2-ene

C

310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

Conditions
ConditionsYield
With iodine; copper dichloride In benzene at 70℃; for 2h;
With copper dichloride In acetonitrile at 60℃; for 2h;
110-57-6

trans-1,4-dichlorobut-2-ene

1476-11-5

Z-1,4-dichlorobutene

Conditions
ConditionsYield
at 99.9℃; Kinetics; Thermodynamic data; Equilibrium constant; activation parameters;
821-10-3

1,4-Dichloro-2-butyne

110-83-8

cyclohexene

1476-11-5

Z-1,4-dichlorobutene

Conditions
ConditionsYield
With borane; acetic acid Product distribution; multistep reaction, stereospecificity, various alkenes;
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

A

1476-11-5

Z-1,4-dichlorobutene

B

110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With poly(p-xylylene); palladium In toluene at 99.85℃; Product distribution;
With oxygen at 100℃;
1708-29-8

2,5-dihydrofuran

7719-09-7

thionyl chloride

5435-44-9, 22243-66-9

(E)-3-Ureido-but-2-enoic acid ethyl ester

1476-11-5

Z-1,4-dichlorobutene

7647-01-0

hydrogenchloride

6117-80-2

1,4-butenediol

A

1476-11-5

Z-1,4-dichlorobutene

B

cis-4-chloro-buten-(2)-ol-(1)

cis-4-chloro-buten-(2)-ol-(1)

Conditions
ConditionsYield
at 40℃;
1476-11-5

Z-1,4-dichlorobutene

100-97-0

hexamethylenetetramine

117175-09-4

1-<(Z)-4-Chloro-2-butenyl>-1-azonia-3,5,7-triazatricyclo<3.3.1.1.3,7>decane chloride

Conditions
ConditionsYield
In dichloromethane for 5h; Reflux; Large scale reaction;100%
In ethanol; chloroform for 4h; Heating;99%
In chloroform at 60℃; for 4h;94%
In chloroform for 4h; Heating;91%
In chloroform for 4h; Reflux;91%
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Chemistry


IUPAC Name: (Z)-1,4-Dichlorobut-2-ene
Synonyms : Cis-1,4-Dichloro-2-butene ; (2Z)-1,4-Dichloro-2-butene ; (2Z)-1,4-Dichlorobut-2-ene ; 2-Butene, 1,4-dichloro- ; 2-Butene, 1,4-dichloro-, (2Z)-
Molecular formula: C4H6Cl2
Molecular weight: 125.00
CAS NO: 1476-11-5
EINECS: 216-021-5
Index of Refraction: 1.459
Surface Tension: 28 dyne/cm 
Molar Refractivity: 30.33 cm3
Molar Volume: 110.9 cm3
Density: 1.126 g/cm3
Flash Point: 54.4 °C
Enthalpy of Vaporization: 37.61 kJ/mol
Boiling Point: 155.5 °C at 760 mmHg
Vapour Pressure: 3.89 mmHg at 25 °C
Melting point : -48 ºC
Storage temp: 2-8 °C
Apperance of cis-1,4-Dichloro-2-butene (CAS NO.1476-11-5): Light-Yellow Clear Liquid

Uses

  cis-1,4-Dichloro-2-butene (CAS NO.1476-11-5) is used for pyrophendane synthesis.

Safety Profile

Hazard Codes:VeryT+DangerousN
Risk Statements: 45-24-25-26-34-50/53
R45:May cause cancer. 
R24:Toxic in contact with skin. 
R25 :Toxic if swallowed. 
R26:Very toxic by inhalation. 
R34:Causes burns. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 53-26-28-36/37/39-45-60-61
 S53:Avoid exposure - obtain special instructions before use. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3390 6.1/PG 1
WGK Germany: 3
RTECS: EM4900000
F: 8-21
HazardClass: 8
PackingGroup of cis-1,4-Dichloro-2-butene (CAS NO.1476-11-5): I