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| CAS No.: | 14883-62-6 |
|---|---|
| Name: | Rhodium(1+),[N,N'-bis(2-aminoethyl)-1,2-ethanediamine-N,N',N'',N''']dichloro-, chloride,[OC-6-22-(R*,R*)]- (9CI) |
| Molecular Structure: | |
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| Formula: | C6H18 Cl2 N4 Rh . Cl |
| Molecular Weight: | 355.5 |
| Synonyms: | Dichloro(triethylenetetramine)rhodiumchloride (7CI); Rhodium(1+), dichloro(triethylenetetramine)-, chloride, cis-(8CI); 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-, rhodium complex |
| Density: | g/cm3 |
| Boiling Point: | 266.5°Cat760mmHg |
| Flash Point: | 143.3°C |
| Safety: | Mutation data reported. When heated to decomposition it emits toxic vapors of NOx, Rh, and Cl−. |
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Chemistry
IUPAC Name: N,N'-bis(2-Aminoethyl)ethane-1,2-diamine ; Dichlororhodium(1-) ; Chloride
Following is the structure of cis-Dichloro(triethylenetetramine)rhodium(1+) chloride (CAS NO.14883-62-6):
Empirical Formula: C6H18Cl3N4Rh
Molecular Weight: 355.4995 g/mol
Enthalpy of Vaporization: 50.45 kJ/mol
Boiling Point: 266.5 °C at 760 mmHg
Vapour Pressure: 0.00861 mmHg at 25 °C
Flash Point of cis-Dichloro(triethylenetetramine)rhodium(1+) chloride (CAS NO.14883-62-6): 143.3 °C
Canonical SMILES: C(CNCCNCCN)N.[Cl-].Cl[Rh-]Cl
InChI: InChI=1S/C6H18N4.3ClH.Rh/c7-1-3-9-5-6-10-4-2-8;/h9-10H,1-8H2;3*1H;/q;+1/p-3
InChIKey: KPDLJWLRWSURKD-UHFFFAOYSA-K
Toxicity Data With Reference
| 1. | mic-sat 2 µmol/plate | MUREAV Mutation Research. 88 (1981),165. |
Safety Profile
Mutation data reported. When heated to decomposition, cis-Dichloro(triethylenetetramine)rhodium(1+) chloride (CAS NO.14883-62-6) emits toxic vapors of NOx, Rh, and Cl−.
Standards and Recommendations
ACGIH TLV: TWA 1 mg(Rh)/m3. Not Classifiable as a human carcinogen.
Specification
cis-Dichloro(triethylenetetramine)rhodium(1+) chloride , its cas register number is 14883-62-6. It also can be called Rhodium(1+), (N,N'-bis(2-aminoethyl)-1,2-ethanediamine-N,N',N'',N''')dichloro-, chloride ; cis-Dichloro(triethylenetetramine)rhodium chloride ; and Rhodium(1+), dichloro(triethylenetetramine)-, chloride, (Z)- . Its classification code is Mutation data.