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15214-89-8

Basic Information
CAS No.: 15214-89-8
Name: 2-Acrylamide-2-methylpropanesulfonic acid
Molecular Structure:
Molecular Structure of 15214-89-8 (2-Acrylamide-2-methylpropanesulfonic acid)
Formula: C7H13NO4S
Molecular Weight: 207.27
Synonyms: 1-Propanesulfonicacid, 2-acrylamido-2-methyl- (8CI);1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propenyl)amino]-(9CI);2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid;AMPS(sulfonic acid);Acrylamidomethylpropanesulfonic acid;TBAS-Q;tert-Butylacrylamidosulfonic acid;
EINECS: 239-268-0
Density: 1.266 g/cm3
Melting Point: 195-200 °C (dec.)(lit.)
Boiling Point: 412oC
Flash Point: 160 °C
Solubility: water: 1500 g/L (20°C)
Appearance: white powder
Hazard Symbols: CorrosiveC
Risk Codes: 34-21/22
Safety: 26-36/37/39-45
Transport Information: UN 2585 8/PG 3
PSA: 91.85000
LogP: 1.42670
Synthetic route
107-13-1

acrylonitrile

115-11-7

isobutene

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With sulfur trioxide at 8 - 35℃; Temperature;92.2%
Stage #1: acrylonitrile With sulfuric acid In water at -10 - -7℃; for 2h;
Stage #2: isobutene With acetic acid at 10 - 70℃; for 1.5h; Temperature;
92.09%
With methanesulfonic acid; sulfuric acid at 0 - 45℃; under 760.051 Torr; for 1h; Reagent/catalyst; Temperature;82.3%
107-13-1

acrylonitrile

115-11-7

isobutene

A

107-58-4

N-tert-Butylacrylamide

B

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

C

79-06-1

2-propenamide

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 2h;A n/a
B 87%
C n/a
1072-63-5

1-vinylimidazole

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

942205-52-9

C7H13NO4S*C5H6N2

Conditions
ConditionsYield
In methanol at 20℃; for 4h;100%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

2052-49-5

tetra(n-butyl)ammonium hydroxide

181208-67-3

2-acrylamido-2-methylpropane sulfonic acid tetrabutylammonium salt

Conditions
ConditionsYield
In methanol at 200℃;100%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 61 kDa, sulfur content 6.97%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 61 kDa, sulfur content 6.97%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;99.8%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 36 kDa, sulfur content 6.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.5 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 36 kDa, sulfur content 6.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.5 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;99.8%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 19 kDa, sulfur content 6.18%, 2-acrylamido-2-methylpropanesulfonic acid units content 19.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 19 kDa, sulfur content 6.18%, 2-acrylamido-2-methylpropanesulfonic acid units content 19.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In isopropyl alcohol at 50℃; for 24h;99.8%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, sulfur content 9.42%, 2-acrylamido-2-methylpropanesulfonic acid units content 37.6 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, sulfur content 9.42%, 2-acrylamido-2-methylpropanesulfonic acid units content 37.6 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;99.7%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 16 kDa, sulfur content 5.86%, 2-acrylamido-2-methylpropanesulfonic acid units content 17.3 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 16 kDa, sulfur content 5.86%, 2-acrylamido-2-methylpropanesulfonic acid units content 17.3 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;99.6%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 28 kDa, sulfur content 7.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.8 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 28 kDa, sulfur content 7.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.8 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;99.2%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

70384-51-9

Tris(3,6-dioxaheptyl)amine

tris-[2-(2-methoxy-ethoxy)-ethyl]-amine; compound with 2-acryloylamino-2-methyl-propane-1-sulfonic acid

Conditions
ConditionsYield
at 25℃; for 8h;99%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 23 kDa, sulfur content 6.07%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.2 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 23 kDa, sulfur content 6.07%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.2 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In isopropyl alcohol at 50℃; for 24h;98.8%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

75-50-3

trimethylamine

2-Methyl-2-(3-trimethylammoniopropionamido)propanesulfonate

Conditions
ConditionsYield
With hydroquinone In water at 25℃; for 24h;95%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, sulfur content 9.13%, 2-acrylamido-2-methylpropanesulfonic acid units content 33.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, sulfur content 9.13%, 2-acrylamido-2-methylpropanesulfonic acid units content 33.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;95%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

79-06-1

2-propenamide

polymer, Mw 14 kDa, sulfur content 7.21%, 2-acrylamido-2-methylpropanesulfonic acid units content 23.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 14 kDa, sulfur content 7.21%, 2-acrylamido-2-methylpropanesulfonic acid units content 23.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;94.8%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

poly(2-acrylamido-2-methylpropanesulfonic acid) sodium salt; monomer(s): 2-acrylamido-2-methylpropanesulfonic acid

poly(2-acrylamido-2-methylpropanesulfonic acid) sodium salt; monomer(s): 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 50℃; for 5h; Kinetics; Activation energy; Further Variations:; Temperatures; Reagents;85%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazole

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazolium 2-acrylamido-2-methylpropanesulfonate

Conditions
ConditionsYield
In methanol at 20℃; for 0.25h;84%
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

2-[3-(1-Azonia-4-azabicyclo[2.2.2]oct-1-yl)propionamido]-2-methylpropanesulfonate

Conditions
ConditionsYield
With hydroquinone In water at 20℃; for 24h;82%
In water at 20℃; for 24h; Addition;81.7%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

16433-88-8

2,7-dibromo-9H-fluorene

9,9-bis(3-propylamide-2-methylpropyl sulfonic acid)fluorene

Conditions
ConditionsYield
Stage #1: 2,7-dibromo-9H-fluorene With tetrabutylammomium bromide; potassium hydroxide In water; dimethyl sulfoxide at 4℃; for 1h;
Stage #2: 2-acrylamido-2-methylpropanesulfonic acid In water; dimethyl sulfoxide for 10h; Michael Addition;
79%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

2848-01-3

3-(diphenylphosphino)propionic acid

2-[3-(2-carboxyethyl)diphenylphosphonio]propanamido-2-methylpropane-1-sulfonate

Conditions
ConditionsYield
In acetonitrile at 20℃; for 48h;79%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

23616-79-7

benzyltri(n-butyl)ammonium chloride

1161027-41-3

benzyltributylammonium 2-acrylamido-2-methyl-1-propanesulfonate

Conditions
ConditionsYield
In water at 20℃; for 0.0833333h;73%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

5205-93-6

2-methyl-acrylic acid 3-dimethylamino-propyl amide

N,N-dimethyl-N-(3-methacrylamidopropyl)-N-[N'-(1,1-dimethyl-2-sulfonatoethyl)propionamido]betaine

Conditions
ConditionsYield
With hydroquinone In water at 20℃; for 72h; Addition;71%
With hydroquinone In water at 70℃; Kinetics; Concentration;
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

77-98-5

tetraethylammonium hydroxide

829-85-6

diphenylphosphane

2-(3-Diphenylphosphanyl-propionylamino)-2-methyl-propane-1-sulfonatetetraethyl-ammonium;

Conditions
ConditionsYield
With ditertbutylphenol In water; acetonitrile for 4h; Ambient temperature;70%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

59178-93-7

(11-Methacryloyl-amino)undecansaeure

11-methacrylamidoundecanoic acid/2-acrylamido-2-methylpropanesulfonic acid copolymer

11-methacrylamidoundecanoic acid/2-acrylamido-2-methylpropanesulfonic acid copolymer

Conditions
ConditionsYield
With sodium hydroxide In methanol at 60℃; for 21h; Product distribution / selectivity;69.2%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

62839-65-0

12-(methacrylolamino)dodecanoic acid

12-methacrylamidododecanoic acid/2-acrylamido-2-methylpropanesulfonic acid copolymer

12-methacrylamidododecanoic acid/2-acrylamido-2-methylpropanesulfonic acid copolymer

Conditions
ConditionsYield
With sodium hydroxide; 2,2'-azobis(isobutyronitrile) In methanol at 60℃; for 21h; Product distribution / selectivity;67.5%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 40 kDa, sulfur content 15.8%; monomer(s): 2-acrylamido-2-methylpropanesulfonic acid

polymer, Mw 40 kDa, sulfur content 15.8%; monomer(s): 2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h;59.7%
295-37-4

1,4,8,11-Tetraazacyclotetradecane

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

2-<3-(1,4,8,11-Tetraazacyclotetradecan-1-yl)propionylamino>-2-methylpropane-1-sulfonic acid

Conditions
ConditionsYield
With 2,4-di-tert-Butylphenol In chloroform for 336h; Ambient temperature;59%

sodium 11-methacrylamidoundecanoate

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

sodium 11-methacrylamidoundecanoic acid/2-acrylamido-2-methylpropanesulfonic acid

sodium 11-methacrylamidoundecanoic acid/2-acrylamido-2-methylpropanesulfonic acid

Conditions
ConditionsYield
With sodium hydroxide; 2,2'-azobis(isobutyronitrile) In methanol; water at 60℃; for 12.5h;53.71%

2-(acrylamidomethyl)-18-crown-6

15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

poly{(2-acrylamido-2-methyl-1-propanesulfonic acid)-co-[2-(acrylamidomethyl)-18-crown-6]}, Mn 47000 g/mol, PDI 1.68; monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid, 80 mol percent; 2-(acrylamidomethyl)-18-crown-6, 20 mol percent

poly{(2-acrylamido-2-methyl-1-propanesulfonic acid)-co-[2-(acrylamidomethyl)-18-crown-6]}, Mn 47000 g/mol, PDI 1.68; monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid, 80 mol percent; 2-(acrylamidomethyl)-18-crown-6, 20 mol percent

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In tert-butyl alcohol for 19h;47%
15214-89-8

2-acrylamido-2-methylpropanesulfonic acid

poly(2-acrylamido-2-methylpropanesulfonic acid), radical polymerization

poly(2-acrylamido-2-methylpropanesulfonic acid), radical polymerization

Conditions
ConditionsYield
With sodium disulfite; potassium peroxomonosulphate; sorbitan monostearate In hexane; water at 60℃; for 1h; pH=9; Kinetics; Product distribution; Polymerization;41%
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  • 2-Acrylamide-2-methylpropanesulfonic acid

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    15214-89-8

    2-Acrylamide-2-methylpropanesulfonic acid

    Min.Order: 1 Gram

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    15214-89-8

    lower price 2-Acrylamide-2-methylpropanesulfonic acid AMPS white powder or granule

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    Product Name: 2-Acrylamido-2-methylpropanesulfonic acid Molecular formula: C7H13NO4S CAS: 15214-89-8 Molecular weight: 207.24 Function: 1. Water treatment: The AMPS monomer homopolymer with the acrylamide acrylic

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  • 2-Acrylamide-2-methylpropanesulfonic acid

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    15214-89-8

    MSDS/COA Download

    2-Acrylamide-2-methylpropanesulfonic acid

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    Offical website: http://www.finerchem.com/pro01en/id/273.html Name: 2-Acrylamide-2-methylpropanesulfonic acid (AMPS) Cas: 15214-89-8 Synonyms: 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Molecular Formula: C7

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    China factory produced AMPS

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  • 2-Acrylamide-2-methylpropanesulfonic acid AMPS CAS 15214-89-8

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    15214-89-8

    2-Acrylamide-2-methylpropanesulfonic acid AMPS CAS 15214-89-8

    Min.Order: 1 Metric Ton

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    2-Acrylamido-2-methylpropane sulfonic acid AMPS CAS 15214-89-8 is a reactive, hydrophilic, sulfonic acid acrylic monomer used to alter the chemical properties of wide variety of anionic polymers. AMPS is a kind of vinyl monomer with sulfonic ac

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  • 2-AcrylaMido-2-Methylpropanesulfonic Acid

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    2-AcrylaMido-2-Methylpropanesulfonic Acid

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    Amadis Chemical offer CAS#15214-89-8;CAT#A809266

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  • Factory Supply  Acrylamido tert-Butyl sulfonic acid

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    Factory Supply Acrylamido tert-Butyl sulfonic acid

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    2-Acrylamide-2-methylpropanesulfonic acid Basic information Product Name: 2-Acrylamide-2-methylpropanesulfonic acid Synonyms: ampsna;2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonicaci;TBAS;ACR

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  • 15214-89-8 2-Acrylamide-2-methylpropanesulfonic acid

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    15214-89-8

    15214-89-8 2-Acrylamide-2-methylpropanesulfonic acid

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  • 2-Acrylamide-2-methylpropanesulfonic acid

  • Casno:

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    MSDS/COA Download

    2-Acrylamide-2-methylpropanesulfonic acid

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Chemistry

Molecular Structure of 2-Acrylamide-2-methylpropanesulfonic acid (CAS NO.15214-89-8):

IUPAC Name: 2-methyl-2-(prop-2-enoylamino)propane-1-sulfonic acid
Molecular Formula: C7H13NO4S
Formula Weight: 207.25
H bond acceptors: 5
H bond donors: 2
Freely Rotating Bonds: 4
Polar Surface Area: 72.06 Å2
Index of Refraction: 1.502
Molar Refractivity: 48.34 cm3
Molar Volume: 163.6 cm3
Surface Tension: 46.5 dyne/cm
Density: 1.266 g/cm3
Melting point: 195-200 °C (dec.)(lit.)
Flash Point: 160 °C
Storage temp: 2-8°C
Water Solubility : 1500 g/L (20°C)
Sensitive : Hygroscopic
InChI
InChI=1/C7H13NO4S/c1-4-6(9)8-7(2,3)5-13(10,11)12/h4H,1,5H2,2-3H3,(H,8,9)(H,10,11,12)
Smiles
O=C(NC(CS(=O)(=O)O)(C)C)C=C
Solublility: Soluble Diformamide, partly soluble in methanol, ethanol, acetone insoluble.
EINECS: 239-268-0
Product Categories: Industrial/Fine Chemicals; monomer; Organic Chemicals; Acrylamide and Methacrylamide; Acrylic Monomers; Monomers

Production

1. Use raw material of acrylonitrile, isobutene reacts with fuming sulfuric acid.
2. In the presence of solvent, firstly sulfonating isobutene to obtain sulfonated intermediates; Then in the presence of sulfuric acid reacts with acrylonitrile.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 5400mg/kg (5400mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA
Toksikologicheskii Vestnik. Vol. (3), Pg. 34, 2000.

Safety Profile

Hazard Codes: CorrosiveC
Risk Statements: 34-21/22 (Causes burns; Harmful in contact with skin and if swallowed)
Safety Statements: 26-36/37/39-45 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing, gloves and eye/face protection; In case of accident or if you feel unwell, seek medical advice immediately)
RIDADR: UN 2585 8/PG 3
WGK Germany: 1
RTECS: TZ6658000
HazardClass: 8
PackingGroup: III
HS Code: 29241900
Low toxicity by ingestion. When heated to decomposition it emits toxic vapors of NOx and SOx.

Specification

  2-Acrylamide-2-methylpropanesulfonic acid , with CAS number of 15214-89-8, can be called 1-propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]- ; 2-(Acryloylamino)-2-methyl-1-propanesulfonic acid . It is a white powder, 2-Acrylamide-2-methylpropanesulfonic acid (CAS NO.15214-89-8) is an important monomer. Its copolymers or homopolymers with different molecular weight can be widely used in textile, oil drilling, water treatment, papermaking, dying, coating, cosmetics, electronics, etc. because of its unique formular structure—containing sulfonic acid group and unsaturated radical, thus showing excellent properties in many aspects.