CAS No.15243-33-1,RUTHENIUM CARBONYL Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	15243-33-1
Name:	RUTHENIUM CARBONYL
Article Data:	228

Formula:	C₁₂O₁₂Ru₃
Molecular Weight:	639.335
Synonyms:	Rutheniumcarbonyl (Ru3(CO)12) (6CI,7CI);Dodecacarbonyl-triangulo-triruthenium;Dodecacarbonyltriruthenium;Triangulo-Triruthenium dodecacarbonyl;Trirutheniumdodecacarbonyl;Triruthenium dodecacarbonyl [Ru3(CO)12];cyclo-Tris(tetracarbonylruthenium)(3Ru-Ru);
EINECS:	239-287-4
Melting Point:	150 °C
Solubility:	Insoluble in water
Appearance:	Orange crystals
Hazard Symbols:	F, Xn
Risk Codes:	11-20
Safety:	24/25
PSA:	0.00000
LogP:	-2.49600

Synthetic route

: 16406-48-7
ruthenium pentacarbonyl

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In further solvent(s) byproducts: CO; exposure to an N2-atmosphere, hydrocarbon soln.;;	100%
In pentane storing of soln. for 1 day under Ar at room temp.;
In neat (no solvent) decompn. of (Ru(CO)5) at room temp.;;

: Ru2[μ-η(2)-OC(CF3)O]2(CO)6

: 201230-82-2
carbon monoxide

: 21907-50-6
cesium trifluoroacetate

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 184584-51-8
fac-Cs[Ru(CF3COO)3(CO)3]

Conditions

Conditions	Yield
In tetrahydrofuran CO-atmosphere; stirring Ru-complex soln. (30°C, 8 h); sepn. of Ru3(CO)12, evapn.;	A 95% B 99%

...Expand

: Ru3{μ-H,μ-O=C(NMe2)}(CO)10

: 74-85-1
ethene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru2(OCC2H5)(OCN(CH3)2)(CO)6

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A n/a B 98%

Yield

With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;

A n/a
B 98%

...Expand

: K(1+)*RuCl2(CO)2(CO2H)(1-) = K[RuCl2(CO)2(CO2H)]

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In 2-methoxy-ethanol byproducts: CO2, KCl; heating the Ru complex and CO in 2-methoxyethanol to 85°C for 20 min; filtration, washing (EtOH);	97%

: diruthenium(II,III) tetraacetatechloride

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With carbon monoxide In methanol; dichloromethane; water High Pressure; dissolving Ru2(CH3COO)4Cl in CH3OH-CH2Cl2-H2O (10:10:1), charging into pressure vessel, pressurizing to 1000 psi with CO, stirring at this pressure for 4 h; venting CO atmosphere, partially removing solvent by vac. distn., pptn.filtration;	96%

: H(μ-H)Ru3(CO)11

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With carbon monoxide In methanol CO atmosphere (room temp., 10 min, stirring), pptn.; redn. of vol. (vac.), filtration off, washing (MeOH): 87.7%; evapn. of filtrate to dryness, chromy. (silica, hexane): 7.9%;	95.7%

: 52621-15-5
[Ru(CO)4(η2-ethylene)]

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In n-heptane N2-atmosphere; refluxing for 2 h; solvent removal (vac.), TLC (CH2Cl2/hexane=1:1);	95%

: tricarbonyldichlororuthenium (II) dimer

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With sodium carbonate In ethylene glycol molar ratio Ru:Na2CO3=1:1; bubbling CO for 5 h at 95°C; extn. of ppt. and sublimate with CH2Cl2 (room temp.), evapn., washing (water);	93%

: 74-85-1
ethene

: Ru3(H)(OCC6H5)(CO)10

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru2(OCC2H5)(OCC6H5)(CO)6

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A n/a B 93%

Yield

A n/a
B 93%

...Expand

: ruthenium trichloride

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With triethylamine In propan-1-ol; water at 85℃; under 2625.26 Torr; Concentration; Reagent/catalyst; Solvent; Temperature; Pressure; Autoclave;	92.5%
In methanol at 125℃; under 48754.9 Torr; for 8h; Autoclave;
With triethylamine In propan-1-ol at 85℃; under 2625.26 Torr; for 17h; Autoclave; Gas phase;

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Specification

The Ruthenium,dodecacarbonyltri-, triangulo is an organic compound with the formula C₁₂O₁₂Ru₃. The systematic name of this chemical is Carbon monooxide - ruthenium. With the CAS registry number 15243-33-1, it is also named as Triruthenium Dodecacarbonyl. The product's categories are Classes of Metal Compounds; Ru (Ruthenium) Compounds; Transition Metal Compounds. Besides, it is orange plates, which should be stored in a sealed, dry, well-ventilated, lightproof place.

Physical property about Ruthenium,dodecacarbonyltri-, triangulo is: (1)#H bond acceptors: 1.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful by inhalation. When you are using it, avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/12CO.3Ru/c12*1-2;;;
(2)InChIKey: NQZFAUXPNWSLBI-UHFFFAOYAJ
(3)Std. InChI: InChI=1S/12CO.3Ru/c12*1-2;;;
(4)Std. InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N