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CAS No.: | 15454-33-8 |
---|---|
Name: | Methanol, chloro- |
Article Data: | 9 |
Molecular Structure: | |
Formula: | CH3ClO |
Molecular Weight: | 66.4872 |
Synonyms: | Methanol,chloro;Chlormethylalkohol;methylene chloride-alcohol;Chlor-methanol;Formaldehyd-hydrochlorid;chloro-methanol; |
PSA: | 20.23000 |
LogP: | 0.17500 |
methanol
chloromethyl dichloroacetate
A
chloromethanol
B
dichloroacetic acid methyl ester
Conditions | Yield |
---|---|
With perchloric acid; sodium perchlorate; water at 25℃; Rate constant; Mechanism; |
chloromethyl formate
A
formaldehyd
B
chloromethanol
C
carbon monoxide
Conditions | Yield |
---|---|
In gaseous matrix Irradiation; UV decomposition; various wavelengths, also vinyl formate, other products; |
chloromethyl formate
chloromethanol
Conditions | Yield |
---|---|
In gaseous matrix Irradiation; |
Conditions | Yield |
---|---|
perchloric acid In water at 25℃; Mechanism; Kinetics; Thermodynamic data; added acetone, sodium or lithium perchlorate; further perchlorate; concentration; temperature; ΔH(excit.), ΔS(excit.); constant ionic strength; |
hydroxymethyl radical
chloromethanol
Conditions | Yield |
---|---|
With chlorine In gas at 21.9℃; Rate constant; |
Conditions | Yield |
---|---|
hydrogenchloride In water at 25℃; Mechanism; Rate constant; concentration; constant ionic strength; |
methylperoxy radical
Chloromethylperoxy radical
A
methanol
B
formaldehyd
C
methoxyl radical
D
chloromethanol
E
formyl chloride
F
chloromethoxy radical
Conditions | Yield |
---|---|
With oxygen at 298℃; Rate constant; Irradiation; |
methanol
chloromethanol
Conditions | Yield |
---|---|
With chlorine at 21.85℃; under 700 Torr; Kinetics; Further Variations:; effect of air; Chlorination; Photolysis; |
N-chloro-succinimide
hydroxymethyl radical
A
Succinimidyl-Radikal
B
chloromethanol
Conditions | Yield |
---|---|
With methanol; hexachloroiridium(III)(3-); dinitrogen monoxide In water at 22 - 23℃; Rate constant; Irradiation; |
hydroxymethyl radical
1-chloropiperidine-2,6-dione
A
chloromethanol
B
glutarimidyl radical
Conditions | Yield |
---|---|
With methanol; hexachloroiridium(III)(3-); dinitrogen monoxide In water at 22 - 23℃; Rate constant; Irradiation; |