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15454-33-8

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Basic Information
CAS No.: 15454-33-8
Name: Methanol, chloro-
Article Data: 9
Molecular Structure:
Molecular Structure of 15454-33-8 (Methanol, chloro-)
Formula: CH3ClO
Molecular Weight: 66.4872
Synonyms: Methanol,chloro;Chlormethylalkohol;methylene chloride-alcohol;Chlor-methanol;Formaldehyd-hydrochlorid;chloro-methanol;
PSA: 20.23000
LogP: 0.17500
Synthetic route
67-56-1

methanol

3338-76-9

chloromethyl dichloroacetate

A

15454-33-8

chloromethanol

B

116-54-1

dichloroacetic acid methyl ester

Conditions
ConditionsYield
With perchloric acid; sodium perchlorate; water at 25℃; Rate constant; Mechanism;
30566-31-5

chloromethyl formate

A

50-00-0

formaldehyd

B

15454-33-8

chloromethanol

C

201230-82-2

carbon monoxide

Conditions
ConditionsYield
In gaseous matrix Irradiation; UV decomposition; various wavelengths, also vinyl formate, other products;
30566-31-5

chloromethyl formate

15454-33-8

chloromethanol

Conditions
ConditionsYield
In gaseous matrix Irradiation;
6135-23-5

chloromethyl chloroacetate

A

15454-33-8

chloromethanol

B

79-11-8

chloroacetic acid

Conditions
ConditionsYield
perchloric acid In water at 25℃; Mechanism; Kinetics; Thermodynamic data; added acetone, sodium or lithium perchlorate; further perchlorate; concentration; temperature; ΔH(excit.), ΔS(excit.); constant ionic strength;
2597-43-5

hydroxymethyl radical

15454-33-8

chloromethanol

Conditions
ConditionsYield
With chlorine In gas at 21.9℃; Rate constant;
3338-76-9

chloromethyl dichloroacetate

A

79-43-6

dichloro-acetic acid

B

15454-33-8

chloromethanol

Conditions
ConditionsYield
hydrogenchloride In water at 25℃; Mechanism; Rate constant; concentration; constant ionic strength;
2143-58-0

methylperoxy radical

73761-32-7

Chloromethylperoxy radical

A

67-56-1

methanol

B

50-00-0

formaldehyd

C

2143-68-2

methoxyl radical

D

15454-33-8

chloromethanol

E

2565-30-2

formyl chloride

F

114282-89-2

chloromethoxy radical

Conditions
ConditionsYield
With oxygen at 298℃; Rate constant; Irradiation;
67-56-1

methanol

15454-33-8

chloromethanol

Conditions
ConditionsYield
With chlorine at 21.85℃; under 700 Torr; Kinetics; Further Variations:; effect of air; Chlorination; Photolysis;
128-09-6

N-chloro-succinimide

2597-43-5

hydroxymethyl radical

A

24344-83-0

Succinimidyl-Radikal

B

15454-33-8

chloromethanol

C

Ir(IV)Cl6(2-)

Ir(IV)Cl6(2-)

Conditions
ConditionsYield
With methanol; hexachloroiridium(III)(3-); dinitrogen monoxide In water at 22 - 23℃; Rate constant; Irradiation;
2597-43-5

hydroxymethyl radical

82621-82-7

1-chloropiperidine-2,6-dione

A

15454-33-8

chloromethanol

B

94694-72-1

glutarimidyl radical

C

Ir(VI)Cl6(2-)

Ir(VI)Cl6(2-)

Conditions
ConditionsYield
With methanol; hexachloroiridium(III)(3-); dinitrogen monoxide In water at 22 - 23℃; Rate constant; Irradiation;
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