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15529-90-5

Basic Information
CAS No.: 15529-90-5
Name: CHLORO(TRIETHYLPHOSPHINE)GOLD(I)
Article Data: 19
Molecular Structure:
Molecular Structure of 15529-90-5 (CHLORO(TRIETHYLPHOSPHINE)GOLD(I))
Formula: C6H15 Au Cl P
Molecular Weight: 350.578
Synonyms: (Triethylphosphine)goldchloride; Chloro(triethylphosphine)gold; NSC 313981; SKF 36914;Triethylphosphine gold(I) chloride; Triethylphosphine-gold chloride complex;Triethylphosphineaurous chloride
Density: g/cm3
Melting Point: 84-86 °C(lit.)
Boiling Point: 210 °C0.03 mm Hg(lit.)
Flash Point: 27.2°C
Hazard Symbols:
Risk Codes: 23/24/25-36/37/38
Safety: Poison by ingestion. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Cl and POx. See also PHOSPHINE and GOLD.
PSA: 13.59000
LogP: 3.21500
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Chemistry

IUPAC Name: Gold(1+) ; Triethylphosphane ; Chloride 
Following is the structure of Chloro(triethylphosphine)gold (CAS NO.15529-90-5):
                      
Empirical Formula: C6H15AuClP
Molecular Weight: 350.5766 g/mol
EINECS: 239-572-3
Flash Point: 27.2 °C
Melting point: 84-86 °C(lit.)
Enthalpy of Vaporization: 34.93 kJ/mol
Boiling Point: 126.5 °C at 760 mmHg
Vapour Pressure: 14.1 mmHg at 25 °C
Water Solubility of Chloro(triethylphosphine)gold (CAS NO.15529-90-5): 1410 mg/L at 25 °C
Canonical SMILES: CCP(CC)CC.[Cl-].[Au+]
InChI: InChI=1S/C6H15P.Au.ClH/c1-4-7(5-2)6-3;;/h4-6H2,1-3H3;;1H/q;+1;/p-1
InChIKey: SYBBXLKWGHAVHP-UHFFFAOYSA-M

Toxicity Data With Reference

1.    

dni-hmn:oth 37,500 nmol/L

    BCPCA6    Biochemical Pharmacology. 34 (1985),3243.
2.    

orl-rat LD50:79 mg/kg

    VTPHAK    Veterinary Pathology. 15 (Suppl 5)(1978),1.
3.    

orl-mus LD50:68 mg/kg

    VTPHAK    Veterinary Pathology. 15 (Suppl 5)(1978),1.

Safety Profile

Poison by ingestion. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition, Chloro(triethylphosphine)gold (CAS NO.15529-90-5) emits very toxic fumes of Cl and POx. See also PHOSPHINE and GOLD.
Hazard Codes: ToxicT
Risk Statements 23/24/25-36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements 26-28-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: MD5431000
HazardClass: 6.1(b)
PackingGroup: III

Specification

 Chloro(triethylphosphine)gold , its cas register number is 15529-90-5. It also can be called Triethylphosphineaurous chloride ; and Triethyl phosphine gold . Its classification code are Mutation data and Reproductive Effect.