CAS No.15629-92-2,[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	15629-92-2
Name:	[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
Article Data:	9

Formula:	C₂₇H₂₆Cl₂NiP₂
Molecular Weight:	542.04
Synonyms:	1,3-Bis(diphenylphosphino)propanenickel dichloride;[Bis(diphenylphosphino)propane]nickel dichloride;Nickel,dichloro[1,3-propanediylbis[diphenylphosphine-kP]]- (9CI);(1,3-Bis(diphenylphosphino)propane)dichloronickel;Nickel,dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-kP]]-;
EINECS:	605-052-3
Melting Point:	213 °C (dec.)(lit.)
Boiling Point:	529.7 °C at 760 mmHg
Flash Point:	291.5 °C
Solubility:	insoluble in water
Appearance:	red to red-brown powder or crystals
Hazard Symbols:	T,Xn
Risk Codes:	49-36/37/38-42/43-40
Safety:	53-26-36/37/39-45-24-22
PSA:	27.18000
LogP:	7.02130

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Chemistry

Systematic Name: Dichloronickel-propane-1,3-diylbis(diphenylphosphane) (1:1)
Molecular Formula: C₂₇H₂₆Cl₂NiP₂
Molecular Weight: 542.04 g/mol
Canonical SMILES: Cl[Ni]Cl.P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4
InChI: InChI=1/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
Product Categories: Metal Compounds;Boron, Nitrile, Thio,& TM-Cpds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Ni (Nickel) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds
Melting Point: 213 °C (dec.)(lit.)
Water Solubility: insoluble
Flash Point: 291.5 °C
Enthalpy of Vaporization: 77.45 kJ/mol
Boiling Point: 529.7 °C at 760 mmHg
Vapour Pressure of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride (CAS NO.15629-92-2): 9E-11 mmHg at 25 °C

Uses

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride (CAS NO.15629-92-2) is used as a catalyst in organic synthesis. It is used in Grignard reagent reactions involving cross-coupling of aryl halides, converting enol ethers, dithioacetals, and vinyl sulfides to olefins.

Safety Profile

Hazard Codes: Toxic T, Harmful Xn
Risk Statements: 49-36/37/38-42/43-40
R49: May cause cancer by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
R42/43: May cause sensitization by inhalation and skin contact.
R40: Limited evidence of a carcinogenic effect.
Safety Statements: 53-26-36/37/39-45-24-22
S53: Avoid exposure - obtain special instructions before use.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S24: Avoid contact with skin.
S22: Do not breathe dust.
RIDADR: 3282
WGK Germany of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride (CAS NO.15629-92-2): 3

Specification

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride (CAS NO.15629-92-2), its Synonyms are Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II) ; [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) ; 1,3-Bis(diphenylphosphine)propane nickel(II) chloride ; (1,3-Bis[diphenylphosphino]propane)dichloronickel ; Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) ; 1,3-Bis-(diphenylphosphino)-propan- . It is orange crystalline powder.