CAS No.1586-92-1,DIETHYLALUMINUM ETHOXIDE Suppliers

Products Categories

Pharmaceutical (35)
Organic Chemicals (10)
Others (5)
Materials (2)

Basic Information

Molecular Structure:
CAS No.:	1586-92-1
Name:	DIETHYLALUMINUM ETHOXIDE
Article Data:	9

Formula:	C6H15 Al O
Molecular Weight:	130.166
Synonyms:	(Ethanolato)diethylaluminum;Dealox; Diethylaluminium ethoxide; Diethylaluminum ethoxide; Diethylaluminummonoethoxide; Diethylethoxyaluminum; Ethoxydiethylaluminum
Density:	g/cm³
Melting Point:	2.5-4.5oC
Boiling Point:	°Cat760mmHg
Flash Point:	°C
Hazard Symbols:	FC
Risk Codes:	R11;R14/15;R17;R20;R34;
Safety:	Ignites spontaneously in air in the pure form or in solutions with concentrations greater than 20%. When heated to decomposition it emits acrid smoke and fumes. See also ALUMINUM COMPOUNDS.
PSA:	9.23000
LogP:	2.43500

Synthetic route

: 97-93-8
triethylaluminum

aluminium-triethylate: aluminium-triethylate

: 1586-92-1
diethyl(ethoxy)aluminum

Conditions

Conditions	Yield
at 170℃;

: 97-93-8
triethylaluminum

: 141-52-6
sodium ethanolate

A: 1586-92-1
diethyl(ethoxy)aluminum

B: 2397-68-4
sodium tetraethylaluminate

Conditions

Conditions	Yield
In hexane; n-heptane; toluene at 70℃; for 1h;

...Expand

: 97-93-8
triethylaluminum

: 555-75-9
aluminum ethoxide

: 1586-92-1
diethyl(ethoxy)aluminum

: 97-93-8
triethylaluminum

: 1586-92-1
diethyl(ethoxy)aluminum

Conditions

Conditions	Yield
With ethanol In hexane byproducts: ethane; Ar, ethanol in hexane added dropwise to a soln. of AlEt3 at -30°C; hexane was distilled off; residue was vac. distilled;

: hexaethyldialuminum

: 1586-92-1
diethyl(ethoxy)aluminum

Conditions

Conditions	Yield
With O2 In xylene shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};
With O2 In n-heptane shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};

: nickel(II) acetylacetonate

: 106475-72-3
methyltriphenylphosphonium bromide

: 1586-92-1
diethyl(ethoxy)aluminum

: 106-99-0
buta-1,3-diene

: C(x)H(x)Br(x)Ni(x)

Conditions

Conditions	Yield
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;	99%
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;	99%
In diethyl ether an orange soln. reacts with phenyl- and halide substituted methane derivative;

...Expand

: nickel(II) acetylacetonate

: 1586-92-1
diethyl(ethoxy)aluminum

: 106-99-0
buta-1,3-diene

: 106-95-6
allyl bromide

: C(x)H(x)Br(x)Ni(x)

Conditions

Conditions	Yield
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;	95%
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;	95%
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;

...Expand

: bis(acetylacetonate)nickel(II)

: 1586-92-1
diethyl(ethoxy)aluminum

: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

Conditions

Conditions	Yield
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;	93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;	93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;	93.5%
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;	93.5%

...Expand

: 1586-92-1
diethyl(ethoxy)aluminum

: 7646-78-8
tin(IV) chloride

: 597-64-8
tetraethyltin

Conditions

Conditions	Yield
100°C;	93%

: 852919-31-4
(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate

: 1586-92-1
diethyl(ethoxy)aluminum

: 10031-93-3
ethyl 4-phenylbutyrate

Conditions

Conditions	Yield
In tetrahydrofuran for 1h; Heating;	92%

Country:
Business Type:
All

Lab/Research institutions

Trading Company

Manufacturers

Other
Certificate:
Manufacturer

Enterprise Authentication

ISO

GMP

FDA

HALAL

Display:default sort
Suppiers of more reward points first

New supplier

Total:47 Page 1 of 2 1 2 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 1586-92-1

Chemistry

Molecular Structure of Ethoxy diethyl aluminum (CAS NO.1586-92-1):

IUPAC: Ethoxy(diethyl)alumane
Molecular Formula:C₆H₁₅AlO
Molecular Weight:130.16
EINECS:216-447-1
Product Categories: Organometallics;AluminumChemical Synthesis;Micro/Nanoelectronics;Organoaluminum;Organometallic Reagents;Solution Deposition Precursors;Chemical Synthesis
Density:0.862 g/mL at 25^oC
Melting Point:2.5-4.5^oC(lit.)
Boiling Point:108-109^oC
Flash Point:−1^oF
Storage temp.:0-6^oC
Vapor pressure:5 mm Hg (94^oC)
Sensitive:Air & Moisture Sensitive
SMILES:CC[Al](CC)OCC
InChIKey:InChIKey: GCPCLEKQVMKXJM-XEYNOYNSAZ

Safety Profile

Ignites spontaneously in air in the pure form or in solutions with concentrations greater than 20%. When heated to decomposition it emits acrid smoke and fumes. See also ALUMINUM COMPOUNDS.

Safty informations about Ethoxy diethyl aluminum (CAS NO.1586-92-1):
Hazard Codes:F,T Toxic ,C Corrosive
Risk Statements:11-14-17-23/24/25-34-14/15
R11:Highly flammable.
R14 :Reacts violently with water.
R17:Spontaneously flammable in air.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R34:Causes burns.
R14/15:Reacts violently with water, liberating extremely flammable gases
Safety Statements:16-26-36/37/39-45-43-27
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S27:Take off immediately all contaminated clothing.
RIDADR:UN 3394 4.2/PG 1
HazardClass:4.3
PackingGroup:I

Specification

Ethoxy diethyl aluminum with CAS registry number of 1586-92-1 is also known as Aluminum,ethoxydiethyl- ; Dlethylaluminumethoxide ; Ethoxydiethyl-aluminu ; Ethoxydiethyl-aluminum ; Diethylaluminium ethoxide ; Diethylaluminum ethoxide ; Ethoxydiethylaluminium ; Diethylaluminum ethoxide,25 WT.% (1.6M )solution in toluene . It is an organometallic reagent with the appearance of colorless clear liquid. Ethoxy diethyl aluminum is used primarily as a catalyst component in
Ziegler-Natta type systems for olefin polymerizations. The pyrophoric nature of Ethoxy diethyl aluminum presents potential hazards not common to most liquid chemicals used by industry in tank truck quantities. Ethoxy diethyl aluminum, being pyrophoric, breaks into flame spontaneously and gives off dense smoke when exposed to air. It reacts violently with water. So this compoud must be kept away from water, acids, sparks, flames, and sources of ignition.