CAS No.15879-93-3,alpha-Chloralose Suppliers

Products Categories

Pharmaceutical (34)
Organic Chemicals (12)
Reagent (3)
Materials (2)
Catalyst and Auxiliary (2)
Plant Extract (1)
Others (1)
Basic Inorganic Chemicals (1)

Basic Information

Molecular Structure:
CAS No.:	15879-93-3
Name:	alpha-Chloralose
Article Data:	11

Formula:	C₈H₁₁Cl₃O₆
Molecular Weight:	309.531
Synonyms:	Chloralose(6CI);Chloralose, a- (8CI);a-D-Glucofuranose,1,2-O-(2,2,2-trichloroethylidene)-, (R)-;AGC;AGC(carbohydrate);Alfa 4;Alpha 4;Alphakil;Anhydroglucochloral;Aphosal;Chloralosane;Dorcalm;Dulcidor;Glucochloral;Glucochloralose;Kalmettumsomniferum;Murex;Murex (carbohydrate);Somio;a-Chloralose;a-D-Chloralose;a-Monotrichloroethylidene-D-glucose;
EINECS:	240-016-7
Density:	1.773 g/cm³
Melting Point:	178-182 °C
Boiling Point:	504.4 °C at 760 mmHg
Flash Point:	258.9 °C
Solubility:	0.44 g/100 mL (15 °C) in water
Appearance:	needle-like crystals or powder
Hazard Symbols:	Xn
Risk Codes:	20/22
Safety:	16-24/25-28-28A
Transport Information:	UN 3249
PSA:	88.38000
LogP:	-0.46290

Synthetic route

: 7664-93-9
sulfuric acid

: 75-87-6
chloral

: 498-07-7
levoglucosan

: 15879-93-3
α-chloralose

...Expand

: 302-17-0
chloral hydrate

: 50-99-7
D-glucose

A: 15879-93-3
α-chloralose

B O1,O2-<(S)-2,2,2-trichloro-ethylidene>-α-D-glucofuranose; 4 O1,O2;O5,O6-bis-<2,2,2-trichloro-ethylidene>-α-D-glucofuranoses: O1,O2-<(S)-2,2,2-trichloro-ethylidene>-α-D-glucofuranose; 4 O1,O2;O5,O6-bis-<2,2,2-trichloro-ethylidene>-α-D-glucofuranoses

Conditions

Conditions	Yield
With sulfuric acid

...Expand

: Acetic acid (2R,3aR,5R,6S,6aR)-5-((R)-1,2-diacetoxy-ethyl)-2-trichloromethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 15879-93-3
α-chloralose

Conditions

Conditions	Yield
With methanol; sodium methylate

: 39598-39-5
α-D-chloralose

: 15879-93-3
α-chloralose

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: pyridine 2: MeONa; MeOH View Scheme

: 50-99-7
D-glucose

: 104-15-4
toluene-4-sulfonic acid

: 75-87-6
chloral

: 15879-93-3
α-chloralose

Conditions

Conditions	Yield
In chloroform

...Expand

: 15879-93-3
α-chloralose

: C8H9Cl3O5

Conditions

Conditions	Yield
With 4,4-dimethyl-5-methylene-1,3-dioxolan-2-one; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 25℃; for 24h;	90%

: 77-76-9
2,2-dimethoxy-propane

: 15879-93-3
α-chloralose

: 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-α-D-glucofuranose

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 20℃; for 24h;	84%

: 4437-80-3
4,4-dimethyl-5-methylene-1,3-dioxolan-2-one

: 15879-93-3
α-chloralose

: C15H17Cl3O10

Conditions

Conditions	Yield
With dmap In N,N-dimethyl-formamide at 25℃; for 24h;	80%

: 15879-93-3
α-chloralose

: 124595-32-0
(R)-1,2-O-(2,2,2-trichloroethylidene)-α-D-xylo-1,4-furanodialdose

Conditions

Conditions	Yield
With sodium periodate In methanol; water at 20℃; for 2h;	78%
With sodium periodate In methanol; water at 20℃; for 4h;	76%
With periodic acid
With sodium periodate In methanol; water

: 15879-93-3
α-chloralose

: 187029-11-4
1,2-O-R-(2,2,2-trichloroethylidene)-α-D-glucofuranose 3,5,6-phosphite

Conditions

Conditions	Yield
With hexaethylphosphorous triamide at 100 - 110℃; for 2h;	74%

Raw Materials

498-07-7

104-15-4

39598-39-5

75-87-6

7664-93-9

302-17-0

50-99-7

Total:45 Page 1 of 2 1 2 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 15879-93-3

Chemistry

Chemical Name: alpha-Chloralose
IUPAC NAME: (1R)-1-[(2R,3aR,5R,6S,6aR)-6-Hydroxy-2-(trichloromethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol
CAS No.: 15879-93-3
EINECS: 240-016-7
RTECS: FM9450000
RTECS Class: Agricultural Chemical and Pesticide ; Tumorigen ; Human Data
EC Class: Harmful
Molecular Formula: C₈H₁₁Cl₃O₆
Molecular Weight: 309.53 g/mol
Melting Point: 178-182 °C
Density: 1.773 g/cm³
Flash Point: 258.9 °C
Boiling Point: 504.4 °C at 760 mmHg
Following is the structure of α-d-Glucochloralose (15879-93-3):

Product Categories about α-d-Glucochloralose (15879-93-3) are Biochemistry ; Glucose ; O-Substituted Sugars ; Sugars ; Dextrins、Sugar & Carbohydrates
The chemical synonymous of are (R)-1,2-O-(2,2,2-Trichloroethylidene)-alpha-D-glucofuranose ; 2-O-(2,2,2-Trichloroethylidene)-(R)-alpha-D-glucofuranos ; 2-O-(2,2,2-Trichloroethylidene)-(theta)-alpha-D-glucofuranos ; Alfamat ; Alpha-Chloralos ; Alphakil ; Aphosal ; Chloralosane

Toxicity Data With Reference

1.	orl-rat LDLo:400 mg/kg	85ESA3 Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals. 9 (1976),260.
2.	scu-rat LDLo:200 mg/kg	27ZIAQ Drug Dosages in Laboratory Animals-A Handbook C.D. Barnes andL.G. Eltherington,Berkeley, CA.: Univ. of California Press,1973,70.
3.	orl-mus LD50:200 mg/kg	FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C68.
4.	ipr-mus LD50:175 mg/kg	ARZNAD Arzneimittel-Forschung. Drug Research. 21 (1971),1727.
5.	orl-dog LD50:250 mg/kg	RMVEAG Recueil de Medecine Veterinaire. 154 (1978),137.
6.	ipr-dog LDLo:400 mg/kg	AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 3 (1897),191.
7.	orl-cat LD50:250 mg/kg	RMVEAG Recueil de Medecine Veterinaire. 154 (1978),137.
8.	ipr-cat LDLo:150 mg/kg	AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 3 (1897),191.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, subcutaneous, and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of Cl⁻.
Hazard Codes:
Xn: Harmful
Risk Statements about α-d-Glucochloralose (15879-93-3):
R20/22 Harmful by inhalation and if swallowed.
Safety Statements about α-d-Glucochloralose (15879-93-3):
S16 Keep away from sources of ignition - No smoking.
S24/25 Avoid contact with skin and eyes.
S28A After contact with skin, wash immediately with plenty of water.
Attention:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale.