CAS No.16024-58-1,2-[2-(2-METHOXYETHOXY)ETHOXY]ACETIC ACID Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	16024-58-1
Name:	2-[2-(2-METHOXYETHOXY)ETHOXY]ACETIC ACID
Article Data:	16

Formula:	C₇H₁₄O₅
Molecular Weight:	178.185
Synonyms:	Aceticacid, [2-(2-methoxyethoxy)ethoxy]- (8CI,9CI);(Methoxyethoxy)ethoxyacetic acid;3,6,9-Trioxadecanoic acid;8-Methoxy-3,6-dioxaoctanoic acid;[2-(2-Methoxyethoxy)ethoxy]acetic acid;
EINECS:	240-162-1
Density:	1.129 g/cm³
Boiling Point:	295.214 °C at 760 mmHg
Flash Point:	116.711 °C
Appearance:	COA
Hazard Symbols:	C
Risk Codes:	34
Safety:	26-36/37/39-45
PSA:	64.99000
LogP:	-0.24940

Synthetic route

: 112-35-6
triethylene glucol monomethyl ether

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hydrogencarbonate; sodium carbonate at 20℃; Electrochemical reaction;	99%
Stage #1: triethylene glucol monomethyl ether With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; sodium carbonate at 20℃; for 2h; aq. buffer; Electroliysis; Stage #2: With Amberlite IR 120 for 0.5h; Mechanism; Solvent; Temperature; aq. buffer;	99%
Stage #1: triethylene glucol monomethyl ether With C29H44Cl2N2Ru; sodium hydroxide In water for 24h; Reflux; Stage #2: With hydrogenchloride In water	88%

: 79-11-8
chloroacetic acid

sodium compound of diethylene glycol-monoethyl ether: sodium compound of diethylene glycol-monoethyl ether

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
With diethyl ether

: 862072-76-2
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]acetoxy}ethoxy)ethoxy]ethyl ester

A: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

B: 27063-48-5, 34733-86-3, 37750-50-8, 117835-14-0, 143916-13-6
bicyclo[2.2.1]hept-2-ene-5-carbonyl chloride

C: 112-27-6
2,2'-[1,2-ethanediylbis(oxy)]bisethanol

Conditions

Conditions	Yield
With phosphate-buffered saline at 80℃; pH=7.4; Kinetics; Further Variations:; pH-values; Temperatures;

...Expand

CC-4 silica gel: CC-4 silica gel

: 112-35-6
triethylene glucol monomethyl ether

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydrogencarbonate In water

: 1252661-82-7
p-nitrophenyl 2-[2-(2-methoxyethoxy)ethoxy]acetate

A: 100-02-7
4-nitro-phenol

B: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
With 6-{N-[6-(6-deoxy-α-cyclodextrinylthio)acetyl]-L-histidylamino}-6-deoxy-β-cyclodextrin at 25℃; pH=7.4; Kinetics; aq. phosphate buffer;

: 1252661-81-6
m-nitrophenyl 2-[2-(2-methoxyethoxy)ethoxy]acetate

A: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

B: 554-84-7
meta-nitrophenol

Conditions

Conditions	Yield
With 6-{N-[6-(6-deoxy-α-cyclodextrinylthio)acetyl]-L-histidylamino}-6-deoxy-β-cyclodextrin at 25℃; pH=7.4; Kinetics; aq. phosphate buffer;

C11H22O5: C11H22O5

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
With methoxybenzene; trifluoroacetic acid In dichloromethane at 20℃; for 5h;
With methoxybenzene; trifluoroacetic acid In dichloromethane at 20℃; for 5h;
With trifluoroacetic acid In dichloromethane at 20℃;	400 mg

: 111-77-3
2-(2-methoxyethoxy)ethyl alcohol

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: potassium tert-butylate / tert-butyl alcohol / 2 h / 20 °C 1.2: 12 h / 20 °C 2.1: trifluoroacetic acid; methoxybenzene / dichloromethane / 5 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: sodium hydride / tetrahydrofuran / 3 h / 20 - 25 °C / Cooling with ice 2: trifluoroacetic acid / dichloromethane / 20 °C View Scheme

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

: 29022-11-5
N-(fluoren-9-ylmethoxycarbonyl)glycine

: 881027-71-0
[2-(2-{2-[2-(2-methoxy-ethoxy)-ethoxy]-acetylamino}-acetylamino)-acetylamino]-acetic acid

Conditions

Conditions	Yield
Stage #1: N-(fluoren-9-ylmethoxycarbonyl)glycine With N-ethyl-N,N-diisopropylamine In dichloromethane solid phase reaction; Stage #2: With piperidine In N,N-dimethyl-formamide solid phase reaction; Stage #3: 2-[2-(2-methoxyethoxy)etoxy]acetic acid Further stages;	100%

: tetrakis(acetato)diaquadicopper(II)

: 16024-58-1
2-[2-(2-methoxyethoxy)etoxy]acetic acid

: copper(II) 2-[2-(2-methoxyethoxy)ethoxy]acetate

Conditions

Conditions	Yield
In toluene	100%

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Specification

The Acetic acid,2-[2-(2-methoxyethoxy)ethoxy]- is an organic compound with the formula C₇H₁₄O₅. The IUPAC name of this chemical is 2-[2-(2-Methoxyethoxy)ethoxy]acetic acid. With the CAS registry number 16024-58-1, it is also named as (2-(2-Methoxyethoxy)ethoxy)essigsure. The product's category is Heterocyclic Compounds. Besides, it should be stored in a cool, sealed, dry place.

Physical properties about Acetic acid,2-[2-(2-methoxyethoxy)ethoxy]- are: (1)ACD/LogP: -1.38; (2)ACD/LogD (pH 5.5): -3.48; (3)ACD/LogD (pH 7.4): -4.93; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1; (7)ACD/KOC (pH 7.4): 1; (8)#H bond acceptors: 5; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 8; (11)Polar Surface Area: 53.99 Å²; (12)Index of Refraction: 1.436; (13)Molar Refractivity: 41.27 cm³; (14)Molar Volume: 157.7 cm³; (15)Polarizability: 16.36×10^-24 cm³; (16)Surface Tension: 37.8 dyne/cm; (17)Density: 1.129 g/cm³; (18)Flash Point: 116.7 °C; (19)Enthalpy of Vaporization: 58.84 kJ/mol; (20)Boiling Point: 295.2 °C at 760 mmHg; (21)Vapour Pressure: 0.000376 mmHg at 25 °C.

Preparation: this chemical can be prepared by 2-[2-(2-Methoxy-ethoxy)-ethoxy]-ethanol. This reaction will need reagents Potassium hydroxide; Potassium permanganate, and solvent H₂O. The reaction time is 12 hours. The yield is about 75%.

Uses of Acetic acid,2-[2-(2-methoxyethoxy)ethoxy]-: it can be used to produce 2-{2-[2-(2-Methoxy-ethoxy)-ethoxy]-acetylamino}-pentanedioic acid bis-octylamide. It will need reagents Et₃N; Benzotriazole-1-yl-oxy-tris(dimethylamino)-phosphoniumhexafluorophosphate and solvent Acetone with reaction time of 12 hours. The yield is about 65%.

When you are using this chemical, please be cautious about it as the following:
It causes burns. When you are using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C7H14O5/c1-10-2-3-11-4-5-12-6-7(8)9/h2-6H2,1H3,(H,8,9)
(2)InChIKey: YHBWXWLDOKIVCJ-UHFFFAOYAS
(3)Std. InChI: InChI=1S/C7H14O5/c1-10-2-3-11-4-5-12-6-7(8)9/h2-6H2,1H3,(H,8,9)
(4)Std. InChIKey: YHBWXWLDOKIVCJ-UHFFFAOYSA-N