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16096-31-4

Basic Information
CAS No.: 16096-31-4
Name: 1,6-Hexanediol diglycidyl ether
Article Data: 7
Cas Database
Molecular Structure:
Molecular Structure of 16096-31-4 (1,6-Hexanediol diglycidyl ether)
Formula: C12H22O4
Molecular Weight: 230.304
Synonyms: Hexane,1,6-bis(2,3-epoxypropoxy)- (6CI,8CI);1,6-Bis(glycidyloxy)hexane;1,6-Hexamethylenediol diglycidyl ether;Hexamethylene diglycidyl ether;Hexamethylene glycol diglycidyl ether;Hexanediol diglycidyl ether;NPEK 051;ZH 16;
EINECS: 240-260-4
Density: 1.076 g/cm3
Melting Point: N/A
Boiling Point: 328.7 °C at 760 mmHg
Flash Point: 120 °C
Solubility: N/A
Appearance: Clear liquid
Hazard Symbols: N/A
Risk Codes: N/A
Safety:
Transport Information: N/A
PSA: 43.52000
LogP: 1.37760
Synthetic route
629-11-8

1,6-hexanediol

106-89-8

epichlorohydrin

16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride; sodium hydroxide In water at 40℃; for 2h;68.2%
With tetrabutylammomium bromide; sodium hydroxide In water at 40℃; for 2h;
Etherification;
tin(IV) chloride Etherification;
81866-56-0

1,6-bis(allyloxy)hexane

A

16096-31-4

1,6 hexanediol diglycidyl ether

B

1246463-46-6

C12H22O3

Conditions
ConditionsYield
With dihydrogen peroxide; benzonitrile; triethylamine In water at 60℃; for 25h; Conversion of starting material;A 29%
B 44%
629-11-8

1,6-hexanediol

106-89-8

epichlorohydrin

A

16096-31-4

1,6 hexanediol diglycidyl ether

B

6-hydroxy hexyl glycidyl ether

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran for 5h; Heating;A 14 g
B 50 g
629-11-8

1,6-hexanediol

3132-64-7

1,2-Epoxy-3-bromopropane

A

16096-31-4

1,6 hexanediol diglycidyl ether

B

6-hydroxy hexyl glycidyl ether

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran for 7h; Heating;A 35 g
B 35 g
20387-39-7

1-chloro-3-[6-(3-chloro-2-hydroxy-propoxy)-hexyloxy]-propan-2-ol

16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
With sodium hydride In hexane; toluene at 20℃; for 0.0833333h; Cyclization;228 mg
629-11-8

1,6-hexanediol

16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: SnCl4 / toluene; heptane / 3 h / 90 °C
2: 228 mg / NaH / toluene; hexane / 0.08 h / 20 °C
View Scheme
16096-31-4

1,6 hexanediol diglycidyl ether

871835-30-2

2-oxo-1,3-dioxolane-4-carboxylic acid

C20H30O14

Conditions
ConditionsYield
With chromium(III) acetylacetonate; triethylamine In tetrahydrofuran at 80℃; for 16h;100%
16096-31-4

1,6 hexanediol diglycidyl ether

(2-dimethylamino-1-(4-morpholinophenyl)-2-(4-carboxyphenylmethyl)butan-1-one)

C60H82N4O12

Conditions
ConditionsYield
With tetrabutylammomium bromide In acetonitrile for 10h; Reflux;88%
16096-31-4

1,6 hexanediol diglycidyl ether

3-{[6-(2,3-dihydroxypropoxy)hexyl]oxy}-1,2-propanediol

Conditions
ConditionsYield
With water; trifluoroacetic acid Hydrolysis; ring cleavage;63%
16096-31-4

1,6 hexanediol diglycidyl ether

111-86-4

n-Octylamine

189192-11-8

di[(2-hydroxy-3-octylamino)propyloxy]hexamethylene

Conditions
ConditionsYield
In ethanol for 4h;105 g
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Chemistry

Molecular Structure of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4):

Molecular Formula: C12H22O4
Molecular Weight: 230.3007
IUPAC Name: 2-[6-(Oxiran-2-ylmethoxy)hexoxymethyl]oxirane
Synonyms of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4): 1,6-Hexanediol diglycidyl ether ; EINECS 240-260-4 ; 1,6-Bis(2,3-epoxypropoxy)hexane
CAS NO: 16096-31-4
Classification Code: TSCA Flag E [Subject to the Section 5(e) Consent Order of TSCA] ; TSCA Flag P [A commenced PMN (Premanufacture Notice) substance] ; TSCA Flag S [Substance is identified in a proposed or final SNUR (Significant New Use Rule) under TSCA] 
Index of Refraction: 1.475
Molar Refractivity: 60.28 cm3
Molar Volume: 213.9 cm3
Surface Tension: 41.8 dyne/cm
Density: 1.076 g/cm3
Flash Point: 120 °C
Enthalpy of Vaporization: 54.85 kJ/mol
Boiling Point: 328.7 °C at 760 mmHg
Vapour Pressure of Oxirane, 2,2'-(1,6-hexanediylbis(oxymethylene))bis- (CAS NO.16096-31-4): 0.000355 mmHg at 25°C