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16532-79-9

Basic Information
CAS No.: 16532-79-9
Name: 4-Bromophenylacetonitrile
Article Data: 40
Molecular Structure:
Molecular Structure of 16532-79-9 (4-Bromophenylacetonitrile)
Formula: C8H6BrN
Molecular Weight: 196.046
Synonyms: Acetonitrile,(p-bromophenyl)- (6CI,7CI,8CI);(4-Bromophenyl)acetonitrile;(p-Bromophenyl)acetonitrile;1-Bromo-4-cyanomethylbenzene;2-(4-Bromophenyl)acetonitrile;4-(Cyanomethyl)bromobenzene;4-Bromobenzyl cyanide;NSC 84174;p-Bromobenzyl cyanide;
EINECS: 240-602-2
Density: 1.487 g/cm3
Melting Point: 47-49 °C(lit.)
Boiling Point: 286.2 °C at 760 mmHg
Flash Point: 126.9 °C
Solubility: slightly soluble in water
Appearance: colorless to pale brown crystalline mass
Hazard Symbols: HarmfulXn,IrritantXi
Risk Codes: 20/21/22-36/37/38
Safety: 26-36/37/39
PSA: 23.79000
LogP: 2.51518
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Chemistry

Molecular Formula: C8H6BrN
Formula Weight: 196.04
mp of 4-BROMOPHENYLACETONITRILE (16532-79-9): 47-49 °C(lit.)
bp of 4-BROMOPHENYLACETONITRILE (16532-79-9): 116-118°C 3mm
Flash Point: 126.9 °
Water Solubility : slightly soluble
Index of Refraction: 1.572 
Density of 4-BROMOPHENYLACETONITRILE (16532-79-9): 1.487 g/cm
Vapour Pressure: 0.00268 mmHg at 25°
PHYSICAL STATE: clear to yellow crystals 

Uses

4-BROMOPHENYLACETONITRILE (16532-79-9) is used in organic synthesis for dyes, perfumes, pesticides, pharmaceuticals, especially penicillin precursors.

Toxicity Data With Reference

1.   

ivn-mus LD50:56 mg/kg

   CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#03252 .

Consensus Reports

Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community Right-To-Know List.

Safety Profile

Safety: DANGER: POISON, causes cyanosis; skin, eye, lung irritation
Hazard Codes : Xn,Xi (Harmful; Irritant)
Risk Statements : 20/21/22-36/37/38-20/21/22/36/37/39 (Harmful by inhalation, in contact with skin and if swallowed; Irritating to eyes, respiratory system and skin)
Safety Statements : 26-36/37/39-38-26/36/37/39 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing, gloves and eye/face protection; In case of insufficient ventilation, wear suitable respiratory equipment)
RIDADR : 3276
WGK Germany : 3
RTECS : AL8090000
Hazard Note : Irritant
HazardClass : 6.1
PackingGroup : III
Poison by intravenous route. See also BROMIDES and NITRILES. When heated to decomposition it emits very toxic fumes of Br, NOx, and CN.

Standards and Recommendations

PURITY: 98.0% min

Specification

Storage: Keep containers tightly closed. Store in a cool, dry, well-ventilated area away from incompatible substances.