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16721-80-5

Basic Information
CAS No.: 16721-80-5
Name: Sodium hydrosulfide
Molecular Structure:
Molecular Structure of 16721-80-5 (Sodium hydrosulfide)
Formula: NaHS
Molecular Weight: 56.0637
Synonyms: Sodiumsulfide (Na(HS)) (8CI);Hydrogen sodium sulfide;Hydrogen sodium sulfide(HNaS);NSC 158264;Sodium bisulfide;Sodium hydrogen sulfide;Sodium hydrogensulfide (NaHS);Sodium hydrosulfide (Na(HS));Sodiummercaptan;Sodium mercaptide;Sodium sulfhydrate;sodium hydrosulphide;
EINECS: 240-778-0
Density: 1.79 g/cm3
Melting Point: 55 °C
Flash Point: 90 °C
Solubility: water: 620 g/L (20 °C)
Appearance: white crystals or powder with a very unpleasant smell
Hazard Symbols: CorrosiveC,FlammableF
Risk Codes: 31-34
Safety: 25-36/37/39-45-50A
Transport Information: UN 2318/1385/2949
PSA: 38.80000
LogP: 0.38050
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Chemistry

IUPAC Name: Sodium sulfanide
Synonyms of Sodium hydrosulfide (CAS NO.16721-80-5): Sodium sulfide (Na(HS)) (8CI) ; Sodium sulfide (Na(SH)) ; NA2922 ; Sodium hydrosulfide ; Sodium hydrosulfide solution ; Sodium hydrosulfide solution (45% or less) ; Sodium hydrosulfide, solution ; Sodium hydrosulfide, solution [NA2922] [Corrosive] ; Sodium hydrosulfide, with <25% water of crystallization ; Sodium hydrosulfide, with <25% water of crystallization [UN2318] [Spontaneously combustible] ;  Sodium hydrosulfide, with not <25% water of crystallization ; Sodium hydrosulfide, with not <25% water of crystallization [UN2949] [Corrosive] ; Sodium sulfide ; UN2318 ; UN2949
CAS NO: 16721-80-5
Classification Code: Mutation data
Molecular Formula of Sodium hydrosulfide (CAS NO.16721-80-5): HNaS
Molecular Weight: 56.0627
Molecular Structure:

Melting Point of Sodium hydrosulfide (CAS NO.16721-80-5): 55°C 
Freely Rotating Bonds: 1
Polar Surface Area: 38.8 Å2 
SMILES: [Na]S 
InChI: InChI=1/Na.H2S/h;1H2/q+1;/p-1/rHNaS/c1-2/h2H 
InChIKey: HYHCSLBZRBJJCH-AWLWQTOKAZ
Std. InChI: InChI=1S/Na.H2S/h;1H2/q+1;/p-1 
Std. InChIKey: HYHCSLBZRBJJCH-UHFFFAOYSA-M

Uses

 Sodium hydrosulfide (CAS NO.16721-80-5) is a useful reagent for the synthesis of organic and inorganic sulfur compounds.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 18mg/kg (18mg/kg) BEHAVIORAL: COMA Drug and Chemical Toxicology. Vol. 1, Pg. 327, 1978.
mouse LD50 subcutaneous 200mg/kg (200mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Japanese Journal of Pharmacology. Vol. 3, Pg. 99, 1954.
rat LD50 intraperitoneal 14600ug/kg (14.6mg/kg)   Biochemical Pharmacology. Vol. 38, Pg. 973, 1989.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: CorrosiveC,FlammableF
Risk Statements: 31-34 
R31: Contact with acids liberates toxic gas. 
R34: Causes burns.
Safety Statements: 25-36/37/39-45-50 
S25: Avoid contact with eyes. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S50: Do not mix with ...
RIDADR: 2318
HazardClass: 4.2
PackingGroup: II
Hazardous Substances Data: 16721-80-5(Hazardous Substances Data)
Poison by intraperitoneal and subcutaneous routes. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. Flammable when exposed to heat or flame. Spontaneous combustion. Reacts violently with diazonium salts. Readily yields H2S. When heated to decomposition it emits toxic fumes of SOx and Na2O. See also SULFIDES and MERCAPTANS.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive, Poison (NA 2922); DOT Class: 4.2; Label: Spontaneously Combustible (UN 2318); DOT Class: 8; Label: Corrosive (UN 2949)