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| CAS No.: | 1760-24-3 |
|---|---|
| Name: | N-[3-(Trimethoxysilyl)propyl]ethylenediamine |
| Molecular Structure: | |
|
|
|
| Formula: | C8H22N2O3Si |
| Molecular Weight: | 222.36 |
| Synonyms: | 1,2-Ethanediamine,N-[3-(trimethoxysilyl)propyl]- (9CI);(2-Aminoethyl)(3-(trimethoxysilyl)propyl)amine;DynasylanDAMO-T;Geniosil GF 9;N-(Aminoethyl)aminopropyltrimethoxysilane;N-b-Aminoethyl-g-aminopropyyltrimethoxysilane;Prosil 3128;SilaneA 0700;en-APTAS;g-(Ethylenediamino)propyltrimethoxysilane;N-(β-aminoethyl)-γ-aminopropyl]trimethoxysilane;[3-(2-Aminoethyl)Aminopropyl]Trimethoxysilane; |
| EINECS: | 217-164-6 |
| Density: | 0.975 g/cm3 |
| Melting Point: | 0ºC |
| Boiling Point: | 272.2 ºC at 760 mmHg |
| Flash Point: | 108.1 ºC |
| Solubility: | reacts with water |
| Appearance: | colorless transparent liquid |
| Hazard Symbols: |
 Xn, Xi
|
| Risk Codes: | 38-41-43-52/53-42/43-37/38 |
| Safety: | 26-39-61-37/39-24-36/37/39-23 |
| Transport Information: | UN 3267 8/PG 2 |
| PSA: | 65.74000 |
| LogP: | 0.89410 |
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| Conditions | Yield |
|---|---|
| Heating; | 90% |
| Conditions | Yield |
|---|---|
| In ethylenediamine | 70.1% |
| Conditions | Yield |
|---|---|
| at 20℃; Kinetics; Equilibrium constant; Further Variations:; Temperatures; |
| Conditions | Yield |
|---|---|
| In ethanol for 0.25h; Heating; | 100% |
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|---|---|
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| Conditions | Yield |
|---|---|
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| Conditions | Yield |
|---|---|
| With lithium hydride In tetrahydrofuran for 2h; Heating; | 99% |
| Conditions | Yield |
|---|---|
| at 70 - 100℃; for 8.5h; | 98% |
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[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane
| Conditions | Yield |
|---|---|
| In toluene at 80℃; for 24h; | 98% |
- 108-31-6
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- 5333-84-6
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[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane
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|---|---|
| In ethyl acetate at 50 - 60℃; | 97% |
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Chemistry
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IUPAC Name: N-(3-Trimethoxysilylpropyl)ethane-1,2-diamine
Molecular Formula: C8H22N2O3Si
Molecular Weight: 222.36 g/mol
SMILES: [Si](CCCNCCN)(OC)(OC)OC
InChI: InChI=1/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
EINECS: 217-164-6
Classification Code: Skin / Eye Irritant
Product Categories: Amino; Amino Silanes (Silane Coupling agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Adhesion Promoters; Amino Silanes; Coupling Agents; Dispersing Agents; Surface Modifiers; Silane series
Water Solubility: REACTS
Sensitive: Air & Moisture Sensitive
Index of Refraction: 1.441
Molar Refractivity: 60.19 cm3
Molar Volume: 227.9 cm3
Polarizability: 23.86×10-24 cm3
Surface Tension: 28.2 dyne/cm
Density: 0.975 g/cm3
Flash Point: 108.1 °C
Enthalpy of Vaporization: 51.05 kJ/mol
Boiling Point: 272.2 °C at 760 mmHg
Vapour Pressure of Z 6020 (CAS NO.1760-24-3): 0.00616 mmHg at 25 °C
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intravenous | 180mg/kg (180mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03517, | |
| rabbit | LDLo | skin | 16mL/kg (16mL/kg) | Union Carbide Data Sheet. Vol. 4/2/1971, | |
| rat | LD50 | oral | 7460uL/kg (7.46mL/kg) | Union Carbide Data Sheet. Vol. 4/2/1971, |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by intravenous route. Mildly toxic by ingestion and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes: 
Xn,
Xi
Risk Statements: 38-41-43-52/53-42/43-37/38
R38:Irritating to skin.
R41:Risk of serious damage to the eyes.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R42/43:May cause sensitization by inhalation and skin contact.
R37/38:Irritating to respiratory system and skin.
Safety Statements: 26-39-61-37/39-24-36/37/39-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S37/39:Wear suitable gloves and eye/face protection.
S24:Avoid contact with skin.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S23:Do not breathe vapour.
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
RTECS: KV7400000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup of Z 6020 (CAS NO.1760-24-3): III
Specification
Z 6020 (CAS NO.1760-24-3), its Synonyms are AAS-M ; AP 132 ; Dow corning Z-6020 silane ; N-(3-Trimethoxysilylpropyl)-ethylenediamine ; 1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)- ; 1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)- ; Ethylenediamine, N-(3-(trimethoxysilyl)propyl)- ; N-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamine ; Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- . It is colorless transparent liquid.