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1760-24-3

Basic Information
CAS No.: 1760-24-3
Name: N-[3-(Trimethoxysilyl)propyl]ethylenediamine
Article Data: 17
Cas Database
Molecular Structure:
Molecular Structure of 1760-24-3 (N-[3-(Trimethoxysilyl)propyl]ethylenediamine)
Formula: C8H22N2O3Si
Molecular Weight: 222.36
Synonyms: 1,2-Ethanediamine,N-[3-(trimethoxysilyl)propyl]- (9CI);(2-Aminoethyl)(3-(trimethoxysilyl)propyl)amine;DynasylanDAMO-T;Geniosil GF 9;N-(Aminoethyl)aminopropyltrimethoxysilane;N-b-Aminoethyl-g-aminopropyyltrimethoxysilane;Prosil 3128;SilaneA 0700;en-APTAS;g-(Ethylenediamino)propyltrimethoxysilane;N-(β-aminoethyl)-γ-aminopropyl]trimethoxysilane;[3-(2-Aminoethyl)Aminopropyl]Trimethoxysilane;
EINECS: 217-164-6
Density: 0.975 g/cm3
Melting Point: 0ºC
Boiling Point: 272.2 ºC at 760 mmHg
Flash Point: 108.1 ºC
Solubility: reacts with water
Appearance: colorless transparent liquid
Hazard Symbols: HarmfulXn,IrritantXi
Risk Codes: 38-41-43-52/53-42/43-37/38
Safety: 26-39-61-37/39-24-36/37/39-23
Transport Information: UN 3267 8/PG 2
PSA: 65.74000
LogP: 0.89410
Synthetic route
107-15-3

ethylenediamine

2530-87-2

3-Chloropropyltrimethoxysilan

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions
ConditionsYield
Heating;90%
2530-87-2

3-Chloropropyltrimethoxysilan

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions
ConditionsYield
In ethylenediamine70.1%
67-56-1

methanol

C11H28N2O4Si

A

110-80-5

2-ethoxy-ethanol

B

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions
ConditionsYield
at 20℃; Kinetics; Equilibrium constant; Further Variations:; Temperatures;
103-72-0

phenyl isothiocyanate

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

C22H32N4O3S2Si

Conditions
ConditionsYield
In ethanol for 0.25h; Heating;100%
19494-73-6

1-[(2-oxazepan-1-yl)carbonyl]azepan-2-one

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

A

105-60-2

caprolactam

B

C15H31N3O5Si

Conditions
ConditionsYield
In toluene at 75℃; for 3h;A n/a
B 100%
30674-80-7

2-Isocyanatoethyl methacrylate

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

4,9-dioxo-5-(3-(trimethoxysilyl)propyl)-3,5,8,10-tetraazadodecane-1,12-diyl bis(2-methylacrylate)

Conditions
ConditionsYield
at 55℃;100%
75-15-0

carbon disulfide

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

C10H20N2O3S4Si(2-)*2Li(1+)

Conditions
ConditionsYield
With lithium hydride In tetrahydrofuran for 2h; Heating;99%
2680-03-7

N,N-Dimethylacrylamide

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

C13H31N3O4Si

Conditions
ConditionsYield
at 70 - 100℃; for 8.5h;98%
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

1-[3-(trimethoxysilyl)propyl]-4,5-dihydro-1H-imidazole

Conditions
ConditionsYield
In toluene at 80℃; for 24h;98%
108-31-6

maleic anhydride

5333-84-6

3-methyl-Δ4-tetrahydrophthalic anhydride

1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

C17H32N2O6Si

Conditions
ConditionsYield
In ethyl acetate at 50 - 60℃;97%
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Chemistry


IUPAC Name: N-(3-Trimethoxysilylpropyl)ethane-1,2-diamine
Molecular Formula: C8H22N2O3Si
Molecular Weight: 222.36 g/mol
SMILES: [Si](CCCNCCN)(OC)(OC)OC
InChI: InChI=1/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
EINECS: 217-164-6
Classification Code: Skin / Eye Irritant
Product Categories: Amino; Amino Silanes (Silane Coupling agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Adhesion Promoters; Amino Silanes; Coupling Agents; Dispersing Agents; Surface Modifiers; Silane series
Water Solubility: REACTS
Sensitive: Air & Moisture Sensitive
Index of Refraction: 1.441 
Molar Refractivity: 60.19 cm3 
Molar Volume: 227.9 cm
Polarizability: 23.86×10-24 cm3 
Surface Tension: 28.2 dyne/cm 
Density: 0.975 g/cm3 
Flash Point: 108.1 °C 
Enthalpy of Vaporization: 51.05 kJ/mol 
Boiling Point: 272.2 °C at 760 mmHg 
Vapour Pressure of Z 6020 (CAS NO.1760-24-3): 0.00616 mmHg at 25 °C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 180mg/kg (180mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03517,
rabbit LDLo skin 16mL/kg (16mL/kg)   Union Carbide Data Sheet. Vol. 4/2/1971,
rat LD50 oral 7460uL/kg (7.46mL/kg)   Union Carbide Data Sheet. Vol. 4/2/1971,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. Mildly toxic by ingestion and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes: HarmfulXn,IrritantXi
Risk Statements: 38-41-43-52/53-42/43-37/38 
R38:Irritating to skin. 
R41:Risk of serious damage to the eyes. 
R43:May cause sensitization by skin contact. 
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R42/43:May cause sensitization by inhalation and skin contact. 
R37/38:Irritating to respiratory system and skin.
Safety Statements: 26-39-61-37/39-24-36/37/39-23 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S39:Wear eye / face protection. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S37/39:Wear suitable gloves and eye/face protection. 
S24:Avoid contact with skin. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S23:Do not breathe vapour.
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
RTECS: KV7400000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup of Z 6020 (CAS NO.1760-24-3): III

Specification

 Z 6020 (CAS NO.1760-24-3), its Synonyms are AAS-M ; AP 132 ; Dow corning Z-6020 silane ; N-(3-Trimethoxysilylpropyl)-ethylenediamine ; 1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)- ; 1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)- ; Ethylenediamine, N-(3-(trimethoxysilyl)propyl)- ; N-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamine ; Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- . It is colorless transparent liquid.