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| CAS No.: | 18171-11-4 |
|---|---|
| Name: | Chloromethyldimethylisopropoxysilane |
| Article Data: | 4 |
| Molecular Structure: | |
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| Formula: | C6H15ClOSi |
| Molecular Weight: | 166.723 |
| Synonyms: | Silane,(chloromethyl)isopropoxydimethyl- (6CI,8CI);(Chloromethyl)(isopropoxy)dimethylsilane;(Chloromethyl)dimethylisopropoxysilane;Dimethylisopropoxysilylmethyl chloride;Isopropoxydimethyl(chloromethyl)silane;NSC 103263; |
| EINECS: | 242-225-9 |
| Density: | 0.918 g/cm3 |
| Boiling Point: | 142 °C at 760 mmHg |
| Flash Point: | 28.3 °C |
| Appearance: | Colorless liquid |
| Hazard Symbols: |
 Xi
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| Risk Codes: | 10-36/37/38 |
| Safety: | 26-36 |
| Transport Information: | UN 1993 3/PG 3 |
| PSA: | 9.23000 |
| LogP: | 2.81280 |
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Specification
The CAS register number of Silane,(chloromethyl)dimethyl(1-methylethoxy)- is 18171-11-4. It also can be called as (Chloromethyl)(isopropoxy)dimethylsilane and the systematic name about this chemical is (chloromethyl)(dimethyl)(propan-2-yloxy)silane. The molecular formula about this chemical is C6H15ClOSi and the molecular weight is 166.72. It belongs to the following product categories which include Monoalkoxysilanes; Si (Classes of Silicon Compounds); Silicon Compounds (for Synthesis); Si-O Compounds; Synthetic Organic Chemistry and so on.
Physical properties about Silane,(chloromethyl)dimethyl(1-methylethoxy)- are: (1)ACD/LogP: 2.73; (2)#H bond acceptors: 1; (3)#Freely Rotating Bonds: 3; (4)Polar Surface Area: 9.23 Å2; (5)Index of Refraction: 1.411; (6)Molar Refractivity: 45.11 cm3; (7)Molar Volume: 181.4 cm3; (8)Polarizability: 17.88x10-24 cm3; (9)Surface Tension: 20.3 dyne/cm; (10)Density: 0.918 g/cm3; (11)Flash Point: 28.3 °C; (12)Enthalpy of Vaporization: 36.35 kJ/mol; (13)Boiling Point: 142 °C at 760 mmHg; (14)Vapour Pressure: 7.15 mmHg at 25°C.
Uses of Silane,(chloromethyl)dimethyl(1-methylethoxy)-: it can be used to produce (2S,6R)-6-(3-Chloropropyl)-2-[(isopropyloxydimethylsilyl)methyl]-5,5-dimethyltetrahydro-2H-pyran-4-one with (R)-6-(3-Chloropropyl)-5,6-dihydro-5,5-dimethyl-4H-pyran-4-one. This reaction is a kind of Grignard reaction//Addition. This reaction needs two steps. It will need reagent Mg, 1,2-dibromoethane, CuBr*SMe2, SMe2 and solvent tetrahydrofuran. The yield is about 100%.
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When you are using this chemical, please be cautious about it as the following:
This chemical is flammable. It is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: ClC[Si](OC(C)C)(C)C
(2)InChI: InChI=1/C6H15ClOSi/c1-6(2)8-9(3,4)5-7/h6H,5H2,1-4H3
(3)InChIKey: KOTFCAKXPLOYLN-UHFFFAOYAI
(4)Std. InChI: InChI=1S/C6H15ClOSi/c1-6(2)8-9(3,4)5-7/h6H,5H2,1-4H3
(5)Std. InChIKey: KOTFCAKXPLOYLN-UHFFFAOYSA-N