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183610-70-0

Basic Information
CAS No.: 183610-70-0
Name: 2-Amino-3-(trifluoromethyl)pyridine
Article Data: 7
Molecular Structure:
Molecular Structure of 183610-70-0 (2-Amino-3-(trifluoromethyl)pyridine)
Formula: C6H5F3N2
Molecular Weight: 162.114
Synonyms: (3-Trifluoromethylpyridin-2-yl)amine;3-(Trifluoromethyl)-2-pyridinamine;
Density: 1.368 g/cm3
Melting Point: 70-72 °C
Boiling Point: 203.2 °C at 760 mmHg
Flash Point: 76.7 °C
Hazard Symbols: IrritantXi
Risk Codes:  Xi:Irritant;
">  Xi:Irritant;
Safety: 26-36/37/39
PSA: 38.91000
LogP: 2.26380
Synthetic route
65753-52-8

2-fluoro-3-trifluoromethylpyridine

183610-70-0

2-amino-3-trifluoromethylpyridine

Conditions
ConditionsYield
With ammonia In water at 130℃; under 22502.3 Torr; for 10h; Temperature;95%
911112-72-6

(4-methoxy-benzyl)-(3-trifluoromethyl-pyridin-2-yl)-amine

183610-70-0

2-amino-3-trifluoromethylpyridine

Conditions
ConditionsYield
Stage #1: (4-methoxy-benzyl)-(3-trifluoromethyl-pyridin-2-yl)-amine With sulfuric acid at 5 - 23℃; for 0.5h;
Stage #2: With sodium hydroxide In water at 0℃;
92%
65753-47-1

2-chloro-3-trifluoromethyl-pyridine

183610-70-0

2-amino-3-trifluoromethylpyridine

Conditions
ConditionsYield
With ammonia In water at 175℃; for 24h;71%
With ammonia In water at 175℃; for 72h;
Multi-step reaction with 2 steps
1: hydrogen fluoride / 48 h / 130 °C / 60006 Torr / Autoclave
2: ammonia / water / 10 h / 130 °C / 22502.3 Torr
View Scheme
67-56-1

methanol

143812-76-4

8-Trifluoromethyl-tetrazolo[1,5-a]pyridine

A

183610-70-0

2-amino-3-trifluoromethylpyridine

B

177211-80-2

2-methoxy-4-trifluoromethyl-1H-1,3-diazepine

Conditions
ConditionsYield
In 1,4-dioxane at 25℃; for 1.33333h; Irradiation;A 5%
B 47%
183610-70-0

2-amino-3-trifluoromethylpyridine

79456-34-1

5-bromo-3-(trifluoromethyl)pyridin-2-amine

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 0 - 20℃;99%
With N-Bromosuccinimide In acetonitrile at 5 - 23℃; for 1h;98%
With N-Bromosuccinimide In acetonitrile at 20℃;93%
183610-70-0

2-amino-3-trifluoromethylpyridine

5-iodo-3-(trifluoromethyl)pyridin-2-amine

Conditions
ConditionsYield
With N-iodo-succinimide; acetic acid at 0 - 20℃; for 90h;89%
Stage #1: 2-amino-3-trifluoromethylpyridine With N-iodo-succinimide; acetic acid at 0 - 20℃;
Stage #2: With sodium hydrogencarbonate In water Cooling with ice;
76%
With N-iodo-succinimide76%
With N-iodo-succinimide In acetic acid at 0 - 20℃;76%
With N-iodo-succinimide In N,N-dimethyl-formamide at 20℃;70%
183610-70-0

2-amino-3-trifluoromethylpyridine

79456-33-0

5-chloro-3-(trifluoromethyl)pyridin-2-amine

Conditions
ConditionsYield
With N-chloro-succinimide In N,N-dimethyl-formamide at 60℃; for 1h;88%
With N-chloro-succinimide In N,N-dimethyl-formamide at 60℃; for 1h;88%
With N-chloro-succinimide In N,N-dimethyl-formamide at 60℃; for 1h; Inert atmosphere;
108-94-1

cyclohexanone

183610-70-0

2-amino-3-trifluoromethylpyridine

4-(trifluoromethyl)benzo[4,5]imidazo[1,2-a]pyridine

Conditions
ConditionsYield
With iodine; oxygen In 1,1,2,2-tetrachloroethane at 160℃; for 24h; Green chemistry;88%
183610-70-0

2-amino-3-trifluoromethylpyridine

C6H5F3N2O

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In acetone at 0 - 20℃; for 12.5h;81%
183610-70-0

2-amino-3-trifluoromethylpyridine

1121056-94-7

5-nitro-3-(trifluoromethyl)pyridin-2-amine

Conditions
ConditionsYield
With sulfuric acid; nitric acid In water at 0 - 50℃; for 3.25h;75%
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    2-Amino-3-(trifluoromethyl)pyridine

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  • 3-(trifluoromethyl)pyridin-2-amine cas no. 183610-70-0 97%

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    183610-70-0

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  • 3-(Trifluoromethyl)-2-Pyridinamine

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    183610-70-0

    3-(Trifluoromethyl)-2-Pyridinamine

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  • 2-Amino-3-(trifluoromethyl)pyridine

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    183610-70-0

    2-Amino-3-(trifluoromethyl)pyridine

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Specification

The 2-Amino-3-(trifluoromethyl)pyridine is an organic compound with the formula C6H5F3N2. The systematic name of this chemical is 3-(trifluoromethyl)pyridin-2-amine. With the CAS registry number 183610-70-0, it is also named as 2-Pyridinamine, 3-(trifluoromethyl)-. The product's categories are Amines and Anilines; Heterocycles; Pyridines, Pyrimidines, Purines and Pteredines; Amines; Pyridines. Additionally, this chemical should be stored at room temperature.

The other characteristics of 2-Amino-3-(trifluoromethyl)pyridine can be summarized as: (1)ACD/LogP: 2.09; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.07; (4)ACD/LogD (pH 7.4): 2.09; (5)ACD/BCF (pH 5.5): 21.82; (6)ACD/BCF (pH 7.4): 22.84; (7)ACD/KOC (pH 5.5): 312.05; (8)ACD/KOC (pH 7.4): 326.63; (9)#H bond acceptors: 2; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 16.13 Å2; (13)Index of Refraction: 1.478; (14)Molar Refractivity: 33.56 cm3; (15)Molar Volume: 118.4 cm3; (16)Polarizability: 13.3×10-24 cm3; (17)Surface Tension: 33.2 dyne/cm; (18)Density: 1.368 g/cm3; (19)Flash Point: 76.7 °C; (20)Enthalpy of Vaporization: 43.95 kJ/mol; (21)Boiling Point: 203.2 °C at 760 mmHg; (22)Vapour Pressure: 0.28 mmHg at 25°C

People can use the following data to convert to the molecule structure.
1. SMILES:FC(F)(F)c1cccnc1N
2. InChI:InChI=1/C6H5F3N2/c7-6(8,9)4-2-1-3-11-5(4)10/h1-3H,(H2,10,11)
3. InChIKey:YWOWJQMFMXHLQD-UHFFFAOYAV
4. Std. InChI:InChI=1S/C6H5F3N2/c7-6(8,9)4-2-1-3-11-5(4)10/h1-3H,(H2,10,11) 
5. Std. InChIKey:YWOWJQMFMXHLQD-UHFFFAOYSA-N