CAS No.188-94-3,DIINDENO[1,2,3-C,D-1',2',3'-I,M]PERYLENE Suppliers

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Basic Information

Molecular Structure:
CAS No.:	188-94-3
Name:	DIINDENO[1,2,3-C,D-1',2',3'-I,M]PERYLENE
Article Data:	8

Formula:	C₃₂H₁₆
Molecular Weight:	400.479
Synonyms:	NSC 87529;Periflanthen;Periflanthene;
EINECS:	205-875-4
Density:	1.467 g/cm³
Melting Point:	>400 °C
Flash Point:	6 °C
Appearance:	orange solid
Hazard Symbols:	FXn
Risk Codes:	11-38-48/20-63-65-67
Safety:	36/37-62
PSA:	0.00000
LogP:	9.03200

Synthetic route

: 206-44-0
fluoranthene

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

Conditions

Conditions	Yield
With sodium amide In N,N-dimethyl acetamide at 162.5 - 165.5℃; for 10h; Temperature; Solvent; Inert atmosphere;	46.7%
With sodium amide; decalin at 200℃;
With sodium amide; decalin at 200℃;

: 198-55-0
PERYLENE

: 71-43-2
benzene

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

Conditions

Conditions	Yield
With aluminium trichloride zuletzt bei Siedetemperatur;

: 206-44-0
fluoranthene

: sodium amide

: 91-17-8
decalin

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

Conditions

Conditions	Yield
at 200℃;
at 200℃;

...Expand

bifluoranthenyl-(3.3'): bifluoranthenyl-(3.3')

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

Conditions

Conditions	Yield
With sodium amide; decalin at 200℃;
With sodium amide; decalin at 200℃;

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

: 1,2,3,4,4a,8b,9,10,11,12,12a,16b-dodecahydro-diindeno[1,2,3-cd;1',2',3'-lm]perylene

Conditions

Conditions	Yield
With nickel at 270℃; under 183877 Torr; Hydrogenation;
Multi-step reaction with 2 steps 1: nickel; decalin / 270 °C / Hydrogenation 2: selenium / 300 °C View Scheme

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

: 860549-06-0
1,2,3,4,4a,4b,5,6,6a,8b,9,10,11,12,12a,16b-hexadecahydro-diindeno[1,2,3-cd;1',2',3'-lm]perylene

Conditions

Conditions	Yield
With nickel; decalin at 270℃; Hydrogenation;

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

: 103283-39-2
diindeno[1,2,3-cd;1',2',3'-lm]perylene-6,7-dione

Conditions

Conditions	Yield
With sodium dichromate; acetic acid; nitrobenzene

: 188-94-3
Diindeno<1,2,3-c,d:1',2',3'-lm>perylene

: 91-17-8
decalin

nickel: nickel

A: 860549-06-0
1,2,3,4,4a,4b,5,6,6a,8b,9,10,11,12,12a,16b-hexadecahydro-diindeno[1,2,3-cd;1',2',3'-lm]perylene

B 1.2.3.4.4a.8b.9.10.11.12.12a.16b-dodecahydro-diindeno<1.2.3-cd:1'.2'.3'-lm>perylene (?): 1.2.3.4.4a.8b.9.10.11.12.12a.16b-dodecahydro-diindeno<1.2.3-cd:1'.2'.3'-lm>perylene (?)

Conditions

Conditions	Yield
at 270℃; under 183877 Torr; Hydrogenation;

...Expand

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Specification

The Diindeno[1,2,3-cd:1',2',3'-lm]perylene, with the CAS registry number 188-94-3, is also known as Periflanthene. Its EINECS registry number is 205-875-4. This chemical's molecular formula is C₃₂H₁₆ and molecular weight is 400.47. What's more, its systematic name is Diindeno[1,2,3-cd:1',2',3'-lm]perylene also. It is orange solid. This chemical is an organic semiconductor which receives attention because of its potential application in optoelectronics and electronics.

Physical properties about Diindeno[1,2,3-cd:1',2',3'-lm]perylene: (1)ACD/LogP: 9.85; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 9.85; (4)ACD/LogD (pH 7.4): 9.85; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 5407511; (8)ACD/KOC (pH 7.4): 5407511; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 0 Å²; (13)Index of Refraction: 2.122; (14)Molar Volume: 272.9 cm³; (15)Surface Tension: 85.7 dyne/cm; (16)Density: 1.467 g/cm³.

When you are dealing with this chemical, you should be very careful. This chemical is irritating to skin and may cause lung damage if swallowed. It may cause damage to health by prolonged exposure through inhalation and its vapours may cause drowsiness and dizziness. What's more, it risks the unborn child possibly. Therefore, you should wear suitable protective clothing and gloves. And if swallowed, do not induce vomiting and you should seek medical advice immediately. In addition, This chemical is highly flammable, it may catch fire in contact with air and only need briefly contact with an ignition source. And its flash point is very low. In case of contacting with water, it could evolve highly flammable gas also.

You can still convert the following datas into molecular structure:
(1) SMILES: c59c3ccc2c1ccccc1c4c2c3c(cc4)c6c5c8c(cc6)c7ccccc7c8cc9
(2) InChI: InChI=1/C32H16/c1-2-6-18-17(5-1)21-9-13-25-27-15-11-23-19-7-3-4-8-20(19)24-12-16-28(32(27)30(23)24)26-14-10-22(18)29(21)31(25)26/h1-16H
(3) InChIKey: BKMIWBZIQAAZBD-UHFFFAOYAB