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| CAS No.: | 19354-27-9 |
|---|---|
| Name: | METHYL TETRAHYDROFURFURYL ETHER |
| Article Data: | 14 |
| Molecular Structure: | |
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| Formula: | C6H12O2 |
| Molecular Weight: | 116.16 |
| Synonyms: | 2-(Methoxymethyl)tetrahydrofuran;Methyl tetrahydrofurfuryl ether;NSC 93893;Tetrahydrofurfuryl methyl ether; |
| EINECS: | 242-986-7 |
| Density: | 0.939 g/cm3 |
| Boiling Point: | 140 °C at 760 mmHg |
| Flash Point: | 33.3 °C |
| Hazard Symbols: | R10:Flammable.; |
| Risk Codes: | 10 |
| Safety: | 16-33-29 |
| PSA: | 18.46000 |
| LogP: | 0.81180 |
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Specification
The CAS registry number of Furan,tetrahydro-2-(methoxymethyl)- is 19354-27-9. Its EINECS registry number is 242-986-7. The IUPAC name is 2-(methoxymethyl)oxolane. In addition, the molecular formula is C6H12O2 and the molecular weight is 116.16. What's more, it is a kind of clear yellow liquid and should be stored in a cool and dry place.
Physical properties about this chemical are: (1)ACD/LogP: -0.08; (2)ACD/LogD (pH 5.5): -0.08; (3)ACD/LogD (pH 7.4): -0.08; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 21.69; (7)ACD/KOC (pH 7.4): 21.69; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 2; (10)Polar Surface Area: 18.46 Å2; (11)Index of Refraction: 1.417; (12)Molar Refractivity: 31.12 cm3; (13)Molar Volume: 123.6 cm3; (14)Polarizability: 12.33 ×10-24cm3; (15)Surface Tension: 29.6 dyne/cm; (16)Density: 0.939 g/cm3; (17)Flash Point: 33.3 °C; (18)Enthalpy of Vaporization: 36.17 kJ/mol; (19)Boiling Point: 140 °C at 760 mmHg; (20)Vapour Pressure: 7.79 mmHg at 25°C.
Preparation of Furan,tetrahydro-2-(methoxymethyl)-: it can be prepared by methanol and pent-4-en-1-ol. This reaction will need reagents 1,4-dicyaninaphthalene and PhSeSePh. The reaction time is 30 hours with ambient temperature. The reaction also needs irradiation. The yield is about 67%.
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Uses of Furan,tetrahydro-2-(methoxymethyl)-: it can be used to get 5-bromo-1-methoxy-pentan-2-ol and 4-bromo-5-methoxy-pentan-1-ol. This reaction will need reagents triethylamine and dimethylboron bromide, and solvent CH2Cl2. The reaction time is 2 hours at reaction temperature of 0 °C. The yield is about 65%.
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When you are using this chemical, please be cautious about it as the following:
It is flammable. You should not empty into drains. And you should keep it away from sources of ignition-no smoking. In addition, you should take precautionary measures against static discharges.
You can still convert the following datas into molecular structure:
(1)SMILES: O(C)CC1OCCC1
(2)InChI: InChI=1/C6H12O2/c1-7-5-6-3-2-4-8-6/h6H,2-5H2,1H3
(3)InChIKey: IEOPZUMPHCZMCS-UHFFFAOYAM