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CAS No.: | 2083-91-2 |
---|---|
Name: | N,N-Dimethyltrimethylsilylamine |
Article Data: | 52 |
Molecular Structure: | |
Formula: | C5H15NSi |
Molecular Weight: | 117.266 |
Synonyms: | Silanamine,pentamethyl- (9CI);Silylamine, pentamethyl- (6CI,7CI,8CI);(Dimethylamino)trimethylsilane;(N,N-Dimethylamino)trimethylsilane;(Trimethylsilyl)dimethylamine;N,N,1,1,1-Pentamethylsilanamine;N,N-Dimethyl(trimethylsilyl)amine;N,N-Dimethyl-N-(trimethylsilyl)amine;N-(Trimethylsilyl)dimethylamine;N-Methyl-N-(trimethylsilyl)methylamine;Pentamethylsilanamine;Pentamethylsilylamine;TSL 8831;Trimethyl(dimethylamino)silane; |
EINECS: | 218-222-3 |
Density: | 0.761 g/cm3 |
Melting Point: | <0 °C |
Boiling Point: | 89.3 °C at 760 mmHg |
Flash Point: | -19 °C |
Solubility: | decomposes in water |
Appearance: | clear colorless to pale yellow liquid |
Hazard Symbols: | F, C |
Risk Codes: | 11-34 |
Safety: | 16-26-36/37/39-45 |
Transport Information: | UN 2733 3/PG 2 |
PSA: | 3.24000 |
LogP: | 1.38290 |
dimethyl amine
1,1,1,3,3,3-hexamethyl-disilazane
N,N-Dimethyltrimethylsilylamine
Conditions | Yield |
---|---|
With 1,3-dimethyl-2-imidazolidinone at 40℃; Reagent/catalyst; | 94% |
With ammonium sulfate at 80℃; for 8h; Reagent/catalyst; Time; Autoclave; | 84% |
trimethylsilyl <(dimethylamino)methyl>methylcarbamate
A
1,3,5-trimethyl-1,3,5-triazacyclohexane
B
N,N-Dimethyltrimethylsilylamine
Conditions | Yield |
---|---|
at 20℃; for 360h; nitrogen atmosphere; | A 90% B n/a |
bis-(dimethylamino)methane
bis(trimethylsilyl) 2-(2-furyl)ethylphosphonite
A
N,N-Dimethyltrimethylsilylamine
Conditions | Yield |
---|---|
With zinc(II) chloride at 130℃; for 1h; | A n/a B 83% |
benzylthiotrimethylsilane
N,N-dimethylphenylmethane sulfenamide
A
dibenzyl disulphide
B
N,N-Dimethyltrimethylsilylamine
Conditions | Yield |
---|---|
at 80 - 110℃; | A 72% B 79% |
trimethylsilyl iodide
N,N-dimethyl acetamide
A
N,N-Dimethyltrimethylsilylamine
B
heptamethyldisilazane
C
N-methyldiacetamide
D
methyl iodide
Conditions | Yield |
---|---|
In dichloromethane at 35℃; for 5h; | A 76% B 1% C 5% D 3% |
Conditions | Yield |
---|---|
In methylbutane Ambient temperature; | 75% |
In octane; acetonitrile at 20℃; for 5h; Solvent; Reflux; | 70% |
bis-(dimethylamino)methane
bis(trimethylsilyl) [2-(2-furyl)-1-(trimethylsilyloxycarbonyl)ethyl]phosphonite
A
N,N-Dimethyltrimethylsilylamine
B
trimethylsilyl (dimethylaminomethyl)[2-(2-furyl)-1-(trimethylsiloxycarbonyl)ethyl]phosphinate
Conditions | Yield |
---|---|
With zinc(II) chloride at 110 - 130℃; for 1.5h; | A n/a B 74% |
A
N,N-Dimethyltrimethylsilylamine
B
dipropylphosphinous iodide
Conditions | Yield |
---|---|
With trimethylsilyl iodide In chlorobenzene at 110 - 132℃; for 8h; | A n/a B 63% |
trimethylsilyl iodide
N,N-dimethyl-formamide
A
N,N-Dimethyltrimethylsilylamine
B
N-formyl-N-methylformamide
C
N-Methyl-N-(trimethylsilyl)-formamid
D
formyl iodide
E
methyl iodide
Conditions | Yield |
---|---|
In dichloromethane at 40℃; for 5h; | A 61% B 1% C 11% D 5% E 11% |
trimethylsilyl iodide
Hexamethylphosphorous triamide
A
N,N-Dimethyltrimethylsilylamine
B
N,N,N',N'-tetramethylphosphorodiamidous iodide
Conditions | Yield |
---|---|
In dichloromethane Ambient temperature; | A n/a B 60% |
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IUPAC Name: N-methyl-N-trimethylsilylmethanamine
Molecular Formula: C5H15NSi
Molecular Weight: 117.27g/mol
EINECS: 218-222-3
Chemical Properties: clear colorless to pale yellow liquid
Density: 0.732 g/mL at 25 °C(lit.)
Melting Point: <0°C
Boiling Point: 89.3 °C at 760 mmHg
Solubility: decomposes
liansport Information: UN 2733 3/PG 2
Properties: liquid
Freely Rotating Bonds: 1
Polar Surface Area: 3.24Å2
Index of Refraction: 1.403
Molar Refractivity: 37.65 cm3
Molar Volume: 154 cm3
Polarizability: 14.92 ×10-24 cm3
Surface Tension: 17.6 dyne/cm
Enthalpy of Vaporization: 31.57 kJ/mol
Vapour Pressure: 66.5 mmHg at 25°C
Sensitive moisture sensitive
The chemical synonyms of Dimethylaminotrimethylsilane (2083-91-2) are Dimethylaminotrimethylsilan ; (Dimethylamino)trimethylsilane ; N,N-dimethylaminotrimethylsilane ; N,N-dimethylaminotrimethylsilane tmsdma ; N,N-dimethyltrimethylsilylamine ; N-trimethylsilydimethylamine ; N-(trimethylsilyl)dimethylamine ; Tmsdma .Product categories of Dimethylaminotrimethylsilane (2083-91-2) are Aminosilanes ; Analytical Chemistry ; GC Derivatizing Reagents ; Si (Classes of Silicon Compounds) ; Silicon Compounds (for Synthesis) ; Silylation (GC Derivatizing Reagents) ; Si-N Compounds ; Synthetic Organic Chemistry ; Trimethylsilylation (GC Derivatizing Reagents) .The molecular structure of Dimethylaminotrimethylsilane (2083-91-2) is.
It can be used as raw material in organic synthesis.
Explosive reaction with xenon difluoride below 0°C. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes: F,C
F: Highly flammable
C: Corrosive
Risk Statements: 11-34
11: Highly flammable
34: Causes burns
Safety Statements: 16-26-36/37/39-45
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
F 1-10
HazardClass : 3