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2113-58-8

Basic Information
CAS No.: 2113-58-8
Name: 3-NITROBIPHENYL
Article Data: 274
Molecular Structure:
Molecular Structure of 2113-58-8 (3-NITROBIPHENYL)
Formula: C12H9NO2
Molecular Weight: 199.209
Synonyms: Biphenyl,3-nitro- (7CI,8CI);3-Nitro-1,1'-biphenyl;3-Nitrobiphenyl;3-Nitrodiphenyl;3-Phenylnitrobenzene;3'-Nitrobiphenyl;NSC 408697;m-Nitrobiphenyl;
EINECS: 218-305-4
Density: 1.196g/cm3
Melting Point: 58-60 °C(lit.)
Boiling Point: 339 °C at 760 mmHg
Flash Point: 161.4 °C
Appearance: yellow crystalline powder
Hazard Symbols: HarmfulXn
Risk Codes: 20/21/22
Safety: 36
PSA: 45.82000
LogP: 3.78500
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Specification

The 1,1'-Biphenyl, 3-nitro-, with CAS registry number 2113-58-8, belongs to the following product categories: (1)Nitro Compounds; (2)Nitrogen Compounds; (3)Organic Building Blocks. It has the systematic name of 3-nitrobiphenyl. Its classification code is Mutation data. This chemical is a kind of yellow crystalline powder. The main use of this chemical is for intermediate of organic synthesis. What's more, its EINECS is 218-305-4.

Physical properties of 1,1'-Biphenyl, 3-nitro-: (1)ACD/LogP: 3.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.51; (4)ACD/LogD (pH 7.4): 3.51; (5)ACD/BCF (pH 5.5): 271.86; (6)ACD/BCF (pH 7.4): 271.86; (7)ACD/KOC (pH 5.5): 1923.58; (8)ACD/KOC (pH 7.4): 1923.58; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 45.82 Å2; (13)Index of Refraction: 1.605; (14)Molar Refractivity: 57.39 cm3; (15)Molar Volume: 166.5 cm3; (16)Polarizability: 22.75×10-24cm3; (17)Surface Tension: 47 dyne/cm; (18)Density: 1.196 g/cm3; (19)Flash Point: 161.4 °C; (20)Enthalpy of Vaporization: 55.93 kJ/mol; (21)Boiling Point: 339 °C at 760 mmHg; (22)Vapour Pressure: 0.000186 mmHg at 25°C.

Preparation: this chemical can be prepared by biphenyl-3-ylamine. This reaction will need reagents eosin, 0.2 M NaOH, O2 and solvents methanol, H2O. The yield is about 32%.

Uses of 1,1'-Biphenyl, 3-nitro-: it can be used to produce 3,3'-diphenylazobenzene. This reaction will need reagent ethylenediamine. The reaction time is 22 hour(s) with reaction temperature of 150 ℃. The yield is about 68%.

When you are using this chemical, please be cautious about it as the following:
The 1,1'-Biphenyl, 3-nitro- is harmful by inhalation, in contact with skin and if swallowed. When use it, wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)SMILES: [O-][N+](=O)c2cccc(c1ccccc1)c2
(2)InChI: InChI=1/C12H9NO2/c14-13(15)12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-9H
(3)InChIKey: FYRPEHRWMVMHQM-UHFFFAOYAM
(4)Std. InChI: InChI=1S/C12H9NO2/c14-13(15)12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-9H
(5)Std. InChIKey: FYRPEHRWMVMHQM-UHFFFAOYSA-N