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2164-09-2

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Basic Information
CAS No.: 2164-09-2
Name: CHLORANOCRYL
Article Data: 3
Molecular Structure:
Molecular Structure of 2164-09-2 (CHLORANOCRYL)
Formula: C10H9Cl2NO
Molecular Weight: 230.094
Synonyms: N-(3,4-dichlorophenyl)-2-methyl-2-propenamide;Acrylanilide,3',4'-dichloro-2-methyl;N-(3,4-dichlorophenyl)-2-methylprop-2-enamide;2-Propenamide, N-(3,4-dichlorophenyl)-2-methyl-;dicryl;methacrylic acid 3,4-dichloroanilide;Chloranocryl;Caswell No. 329;2-Methyl-acrylsaeure-<3,4-dichlor-anilid>;3,4-dichloro-N-methacryloylaniline;DCMA;Licryl;Niagara 4556;3’,4’-dichloro-2-methylacrylanilide;
Density: 1.319
Melting Point: 124-126oC
Boiling Point: 375.5°C at 760 mmHg
Flash Point: 180.9°C
Solubility: 8mg/L(temperature not stated)
Hazard Symbols: Xn
Risk Codes: R22
Safety: Moderately toxic by ingestion, skin contact, and intraperitoneal routes. An herbicide. When heated to decomposition it emits very toxic fumes of Cl− and NOx.
PSA: 29.10000
LogP: 3.58100
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Chemistry

IUPAC Name: N-(3,4-Dichlorophenyl)-2-methylprop-2-enamide
Synonyms of 3',4'-Dichloro-2-methylacrylanilide (CAS NO.2164-09-2) : 3',4'-Dichloro-2-methylacrylanilide ; 2-Propenamide, N-(3,4-dichlorophenyl)-2-methyl- ; Dicryl ; N-(3,4-dichlorophenyl)-2-methylacrylamide ; N-(3,4-Dichlorophényl)-2-méthylacrylamide
CAS NO: 2164-09-2
Molecular Formula:C10H9Cl2NO
Molecular Weight :230.0906
Molecular Structure :
Index of Refraction:1.593
Surface Tension: 43.4 dyne/cm
Density: 1.319 g/cm3
Flash Point: 180.9 °C
Enthalpy of Vaporization: 62.3 kJ/mol
Boiling Point: 375.5 °C at 760 mmHg
Vapour Pressure: 7.75E-06 mmHg at 25°C
Melting point: 128°C
Appearance:White powder
Solubility: 3',4'-Dichloro-2-methylacrylanilide (CAS NO.2164-09-2) does not dissolve in water, soluble in acetone (30%), pyridine (33%), dimethyl formamide (51%) and xylene (25%).

Uses

 3',4'-Dichloro-2-methylacrylanilide (CAS NO.2164-09-2) is used as contact herbicide, mainly used for cotton, maize shoots after the weeding.

Production

Raw materials :3,4-Dichloroaniline-->Methacryloyl chloride 
can be derived from from 3,4 - Dichloro-aniline react with Isobutylene chloride.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 410mg/kg (410mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(12), Pg. 30, 1977.
rabbit LD50 skin 10gm/kg (10000mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 375, 1966.
rat LD50 oral 1800mg/kg (1800mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.
rat LD50 skin 1780mg/kg (1780mg/kg)   Pesticide Manual. Vol. 1, Pg. 155, 1968.

Safety Profile

Moderately toxic by ingestion, skin contact, and intraperitoneal routes. An herbicide. When heated to decomposition it emits very toxic fumes of Cl− and NOx.
Hazard Codes HarmfulXn
Risk Statements 22
R22:Harmful if swallowed.
RTECS AS4025000