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| CAS No.: | 2177-18-6 |
|---|---|
| Name: | VINYL ACRYLATE |
| Article Data: | 10 |
| Molecular Structure: | |
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|
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| Formula: | C5H6 O2 |
| Molecular Weight: | 98.1014 |
| Synonyms: | Acrylicacid, vinyl ester (6CI,7CI,8CI); NSC 4768; Vinyl acrylate |
| Density: | 0.936g/cm3 |
| Melting Point: | -81.9°C |
| Boiling Point: | 91.5°Cat760mmHg |
| Flash Point: | 13.5°C |
| Hazard Symbols: | A poison by ingestion. Low toxicity by inhalation. A severe skin and eye irritant. |
| Risk Codes: | 11-25-34 |
| Safety: | A poison by ingestion. Low toxicity by ingestion. inhalation. A severe skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating vapors. |
| PSA: | 26.30000 |
| LogP: | 0.85910 |
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| Conditions | Yield |
|---|---|
| With sodium methylate In methanol at 50 - 55℃; | 98% |
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate; hydroquinone | |
| With rhodium(III) chloride trihydrate; sodium formate at 80℃; for 24h; | 67 %Chromat. |
| Conditions | Yield |
|---|---|
| In n-heptane for 0.5h; Heating; |
| Conditions | Yield |
|---|---|
| With oxygen; sodium 2-propenoate; p-benzoquinone; palladium diacetate In 1-methyl-pyrrolidin-2-one at 50 - 60℃; under 1838.93 - 2942.29 Torr; for 4 - 36h; Product distribution / selectivity; | A 5.7 - 65 %Chromat. B 4.8 - 18 %Chromat. |
| palladium diacetate In 2-n-butyl-4-(hydroxymethyl)imidazole at 50℃; under 367.786 Torr; for 16h; Product distribution / selectivity; | A 0.5 %Chromat. B 1.3 %Chromat. |
| With 4-methoxy-phenol; p-benzoquinone; palladium 10% on activated carbon at 80℃; under 2574.5 Torr; for 16h; Product distribution / selectivity; | A 6.0 %Chromat. B 11.8 %Chromat. |
| Conditions | Yield |
|---|---|
| decacarbonyldirhenium(0) In toluene at 140℃; under 15001.5 Torr; for 17h; Product distribution / selectivity; |
| Conditions | Yield |
|---|---|
| With Cp*2Sm(THF)2 In toluene Ambient temperature; further reagent: SmI2; | 99% |
| With 1,3-dichlorotetrabutyldistannoxane at 50℃; for 15h; | 98% |
| With 1,3-dichlorotetrabutyldistannoxane at 50℃; for 15h; | 98% |
| In 2,2,4-trimethylpentane at 37℃; immobilized lipase from Candida cylindracea; |
| Conditions | Yield |
|---|---|
| In 1,4-dioxane | 99% |
| Conditions | Yield |
|---|---|
| With 1,3-dichlorotetrabutyldistannoxane at 30℃; for 45h; | 96% |
| With 1,3-dichlorotetrabutyldistannoxane at 30℃; for 45h; | 96% |
| Conditions | Yield |
|---|---|
| With 1,3-dichlorotetrabutyldistannoxane In acetonitrile at 50℃; for 36h; | 96% |
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Chemistry
Molecular Structure of Ethyl 2-propenoate (CAS NO.2177-18-6):
IUPAC: Ethyl prop-2-enoate
Molecular Formula:C5H6O2
Molecular Weight:98.1
EINECS:218-538-1
Product Categories:monomer
Density:0.942 g/mL at 25oC(lit.)
Boiling Point:90-92oC(lit.)
Flash Point:36oF
Refractive index:n20/D 1.432(lit.)
Vapor pressure:53.7 mmHg at 25oC
SMILES:O=C(O\C=C)\C=C
InChIKey:BLCTWBJQROOONQ-UHFFFAOYAA
Molar Volume:104.7 cm3
Surface Tension:24.8 dyne/cm
Molar Refractivity:26.43 cm3
Enthalpy of Vaporization:33.14 kJ/mol
Toxicity Data With Reference
| 1. | skn-rbt 500 µL SEV | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0529778-1 . | ||
| 2. | eye-rbt 5 µL SEV | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0529778-1 . | ||
| 3. | orl-rat LD50:90 µL/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0529778-1 . | ||
| 4. | ihl-rat LC50:1450 ppm/4H | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0529778-1 . |
Safety Profile
A poison by ingestion. Low toxicity by ingestion. inhalation. A severe skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Safty informations about Ethyl 2-propenoate (CAS NO.2177-18-6):
Hazard Codes:F
,T
Risk Statements:11-25-34
R11:Highly flammable.
R25:Toxic if swallowed.
R34:Causes burns.
Safety Statements:9-16-26-28-36/37/39-45
S9:Keep container in a well-ventilated place
S16:Keep away from sources of ignition.
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28:After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR:UN 3286 3/PG 2
WGK Germany:3
RTECS:UD3341000
Specification
Ethyl 2-propenoate with CAS registry number of 2177-18-6 is also known as Vinyl acrylate ; 2-Propenoicacid,ethenylester ; Acrylic acid,vinyl ester ; Acrylicacid,vinylester ; Ethenyl2-propenoate ; Vinyl acrylate98% ; Vinyl acrylate,stabilized,98+% ; 3-Oxahexa-1,5-diene-4-one . It is a colorless clear liquid. Ethyl 2-propenoate is prone to polymerization because it contains a vinyl double bond, so this compound is suitable for manufacture of homopolymer and copolymer which can be used as coatings and protective colloid.