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| CAS No.: | 2179-92-2 | |
|---|---|---|
| Name: | TRI-N-BUTYLCYANOTIN | |
| Article Data: | 2 | |
| Molecular Structure: | ||
|
|
||
| Formula: | C13H27 N Sn | |
| Molecular Weight: | 316.074 | |
| Synonyms: | Tin,tributylcyano- (7CI,8CI); Cyanotributyltin; Tributylcyanostannane;Tributylcyanotin; Tributylstannanecarbonitrile; Tributylstannyl cyanide;Tributyltin cyanide | |
| Density: | g/cm3 | |
| Melting Point: |
105-107 °C(lit.) |
|
| Boiling Point: | 300.1°Cat760mmHg | |
| Flash Point: | 135.3°C | |
| Hazard Symbols: | A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin). | |
| Risk Codes: | 23/24/25-36/37/38-52/53 | |
| Safety: | Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx and CN−. See also TIN COMPOUNDS and NITRILES. | |
Analytical Methods: | For occupational chemical analysis use NIOSH: Organotin Compounds 5504. |
|
| PSA: | 23.79000 | |
| LogP: | 4.89828 | |
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Chemistry
Empirical Formula: C13H27NSn
Molecular Weight: 316.0702 g/mol
EINECS: 247-295-4
Flash Point: 135.3 °C
Melting point: 105-107 °C(lit.)
Appearance: White crystalline powder
Enthalpy of Vaporization: 54.02 kJ/mol
Boiling Point: 300.1 °C at 760 mmHg
Vapour Pressure: 0.00114 mmHg at 25 °C
Product Category of Tributylcyanotin (CAS NO.2179-92-2): Organometallic Reagents;Organotin
Structure of Tributylcyanotin (CAS NO.2179-92-2):
IUPAC Name: Tributylstannylformonitrile
Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C#N
InChI: InChI=1S/3C4H9.CN.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;;
InChIKey: GMYAQHAKWKXYHG-UHFFFAOYSA-N
Toxicity Data With Reference
| 1. | ivn-mus LD50:18 mg/kg | CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#05643 . |
Tributylcyanotin (CAS NO.2179-92-2) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. You can see actual entry in RTECS for complete information.
Consensus Reports
Cyanide and its compounds are on the Community Right-To-Know List.
Safety Profile
Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx and CN−. See also TIN COMPOUNDS and NITRILES.
Hazard Codes: 
T
Risk Statements: 23/24/25-36/37/38-52/53
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 22-26-36/37/39-45-61
S22:Do not breathe dust.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
Standards and Recommendations
OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3
Analytical Methods
For occupational chemical analysis use NIOSH: Organotin Compounds 5504.
Specification
Tributylcyanotin , its cas register number is 2179-92-2. It also can be called Tributylstannanecarbonitrile ; Tri-n-butyltin cyanide ; and Tin, tributylcyano- (8CI) . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water, and get medical aid immediately.
In addition, Tributylcyanotin (CAS NO.2179-92-2) is not compatible with strong oxidizing agents, strong acids, and you must not take it with incompatible materials. It should be exposured to moist air or water. And also prevent it to broken down into hazardous decomposition products: hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, tin/tin oxides.