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22499-12-3

Basic Information
CAS No.: 22499-12-3
Name: BENZOIN ISOBUTYL ETHER
Article Data: 2
Molecular Structure:
Molecular Structure of 22499-12-3 (BENZOIN ISOBUTYL ETHER)
Formula: C18H20O2
Molecular Weight: 268.356
Synonyms: Acetophenone,2-isobutoxy-2-phenyl- (8CI);2-Isobutoxy-2-phenylacetophenone;Benzoin isobutylether;Isobutyl benzoin ether;Quantacure B 2;Vicure 10;
EINECS: 245-039-6
Density: 1.051 g/cm3
Melting Point: 33~34℃
Boiling Point: 344.8 °C at 760 mmHg
Flash Point: 155.6 °C
Appearance: clear yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 22
Safety: 23-24/25
PSA: 26.30000
LogP: 4.28320
Synthetic route
926-62-5

isobutylmagnesium bromide

134-81-6

benzil

A

22499-12-3

2-isobutoxy-2-phenylacetophenone

B

119-53-9

2-hydroxy-2-phenylacetophenone

C

α-isobutylbenzoin

α-isobutylbenzoin

Conditions
ConditionsYield
With ammonium chloride 1.) ether, room temperature, 2.) 150 deg C, 1 min; Multistep reaction;
22499-12-3

2-isobutoxy-2-phenylacetophenone

623-48-3

ethyl iodoacetae

(3SR,4RS)-ethyl 3-hydroxy-3,4-diphenyl-4-isobutyloxybutanoate

Conditions
ConditionsYield
With indium(III) chloride; indium In toluene at 20℃; for 2h; ultrasonication;99%
667-27-6

Ethyl bromodifluoroacetate

22499-12-3

2-isobutoxy-2-phenylacetophenone

C22H24F2O4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium acetate; silver fluoride; triphenylphosphine In hexane at 140℃; for 20h; Sealed tube; Inert atmosphere;63%
With tetrakis(triphenylphosphine) palladium(0); potassium acetate; silver fluoride; triphenylphosphine In hexane at 140℃; for 20h; Inert atmosphere; Sealed tube;63%
22499-12-3

2-isobutoxy-2-phenylacetophenone

A

451-40-1

phenyl benzyl ketone

B

(4-Isobutoxymethyl-phenyl)-phenyl-methanone

C

2-Isopropyl-3,4-diphenyl-oxetan-3-ol

D

C22H30O2

Conditions
ConditionsYield
With alkalimetal-zeolite In 2,2,4-trimethylpentane; benzene Irradiation; 2.) degassed at 1E-4 Torr and irradiated;
22499-12-3

2-isobutoxy-2-phenylacetophenone

A

134-81-6

benzil

B

(4-Isobutoxymethyl-phenyl)-phenyl-methanone

C

2-Isopropyl-3,4-diphenyl-oxetan-3-ol

D

C22H30O2

Conditions
ConditionsYield
With alkalimetal-zeolite In 2,2,4-trimethylpentane; benzene Irradiation; 2.) degassed at 1E-4 Torr and irradiated;
22499-12-3

2-isobutoxy-2-phenylacetophenone

74-88-4

methyl iodide

27962-50-1

α-Methyl-benzoin-isobutylether

Conditions
ConditionsYield
With sodium hydroxide In dimethyl sulfoxide
37746-78-4

4-bromo-trans-crotonic acid ethyl ester

22499-12-3

2-isobutoxy-2-phenylacetophenone

ethyl (E,5RS,6SR)-5-hydroxy-6-isobutyloxy-5,6-diphenylhex-2-enoate

ethyl (E,5SR,6SR)-5-hydroxy-6-isobutyloxy-5,6-diphenylhex-2-enoate

Conditions
ConditionsYield
With indium In tetrahydrofuran at 20℃; for 5h; Title compound not separated from byproducts.;
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    benzoin isobutyl ether Purity 99% CAS NO.22499-12-3

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  • Bnzoin isobutyl ether

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    22499-12-3

    Bnzoin isobutyl ether

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  • benzoin isobutyl ether Purity 99% CAS NO.22499-12-3

  • Casno:

    22499-12-3

    benzoin isobutyl ether Purity 99% CAS NO.22499-12-3

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  • Ethanone,2-(2-methylpropoxy)-1,2-diphenyl-

  • Casno:

    22499-12-3

    Ethanone,2-(2-methylpropoxy)-1,2-diphenyl-

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  • 22499-12-3

  • Casno:

    22499-12-3

    22499-12-3

    Min.Order: 0

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  • CSR160805-22060

  • Casno:

    22499-12-3

    CSR160805-22060

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    Purity, Prompt shipment, Price Application:surface active agent

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  • BenzoinIsobutylEther

  • Casno:

    22499-12-3

    BenzoinIsobutylEther

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  • FT-0700084

  • Casno:

    22499-12-3

    FT-0700084

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Specification

The Ethanone,2-(2-methylpropoxy)-1,2-diphenyl-, with CAS registry number 22499-12-3, belongs to the following product categories: (1)Functional Materials; (2)Photopolymerization Initiators. It has the systematic name of 2-(2-methylpropoxy)-1,2-diphenylethanone. This chemical is a kind of clear yellow liquid. And this chemical is harmful if swallowed. When use this chemical, do not breathe vapour and avoid contact with skin and eyes. What's more, its EINECS is 245-039-6.

Physical properties of Ethanone,2-(2-methylpropoxy)-1,2-diphenyl-: (1)ACD/LogP: 4.78; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4.78; (4)ACD/LogD (pH 7.4): 4.78; (5)ACD/BCF (pH 5.5): 2546.09; (6)ACD/BCF (pH 7.4): 2546.09; (7)ACD/KOC (pH 5.5): 9539.39; (8)ACD/KOC (pH 7.4): 9539.39; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 26.3 Å2; (13)Index of Refraction: 1.547; (14)Molar Refractivity: 81 cm3; (15)Molar Volume: 255.1 cm3; (16)Polarizability: 32.11×10-24cm3; (17)Surface Tension: 39.4 dyne/cm; (18)Density: 1.051 g/cm3; (19)Flash Point: 155.6 °C; (20)Enthalpy of Vaporization: 58.88 kJ/mol; (21)Boiling Point: 344.8 °C at 760 mmHg; (22)Vapour Pressure: 6.44E-05 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(c1ccccc1)C(OCC(C)C)c2ccccc2
(2)InChI: InChI=1/C18H20O2/c1-14(2)13-20-18(16-11-7-4-8-12-16)17(19)15-9-5-3-6-10-15/h3-12,14,18H,13H2,1-2H3
(3)InChIKey: JMVZGKVGQDHWOI-UHFFFAOYAJ
(4)Std. InChI: InChI=1S/C18H20O2/c1-14(2)13-20-18(16-11-7-4-8-12-16)17(19)15-9-5-3-6-10-15/h3-12,14,18H,13H2,1-2H3
(5)Std. InChIKey: JMVZGKVGQDHWOI-UHFFFAOYSA-N