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| CAS No.: | 22722-98-1 |
|---|---|
| Name: | Sodium bis(2-methoxyethoxy)aluminiumhydride |
| Molecular Structure: | |
|
|
|
| Formula: | C6H16AlNaO4 |
| Molecular Weight: | 202.162 |
| Synonyms: | Aluminate(1-),dihydrobis(2-methoxyethanolato)-, sodium (8CI);Aluminate(1-), dihydrobis(2-methoxyethanolato-O,O')-,sodium;Aluminate(1-), dihydrobis[2-(methoxy-kO)ethanolato-kO]-, sodium (9CI);Ethanol, 2-methoxy-, aluminumcomplex;Red-Al;SDMA (reducing agent);SMEAH;Sodium aluminumbis(2-methoxyethoxy)hydride;Sodium bis(2-methoxyethoxy)dihydroaluminate;Sodiumdihydridobis(2-methoxyethoxy)aluminate;Sodiumdihydrobis(2-methoxyethoxy)aluminate;Sodiumdihydrobis(2-methoxyethoxy)aluminate(1-);Sodiumdihydrobis(2-methoxyethyl)aluminate;Sodium dihydrobis(methoxyethoxy)aluminate;Sodium dihydrobis(b-methoxyethoxy)aluminate;Synhydride;Vitride; |
| EINECS: | 245-178-2 |
| Density: | 1.036 g/mL at 25 °C |
| Melting Point: | 112oC |
| Boiling Point: | 396-402°C |
| Flash Point: | 40 °F |
| Solubility: | Reacts with water |
| Appearance: | clear to slightly hazy, colorless to light amber |
| Hazard Symbols: |
 F,  C
|
| Risk Codes: | 11-14/15-34-48/20-63-65-67 |
| Safety: | 26-36/37/39-43-45-62-46-16 |
| Transport Information: | UN 3399 4.3/PG 1 |
| PSA: | 36.92000 |
| LogP: | 0.45240 |
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Chemistry
IUPAC Name: Sodium ; Alumanylium ; 2-Methoxyethanolate (22722-98-1)
Synonyms: Sodium dihydro-bis-(2-methoxyethoxy)aluminate ; RED-AL ; SBAH
Molecular Structure: 
Molecular Formula : C6H16AlNaO4
Molecular Weight: 202.16
CAS : 22722-98-1
EINECS: 245-178-2
Density: 1.036
Water solubility : reacts
Flash Point: 46.1 °C
Enthalpy of Vaporization: 37.54 kJ/mol
Boiling Point: 124.4 °C at 760 mmHg
Vapour Pressure: 5.98 mmHg at 25°C
Mol File: 22722-98-1.mol
Vapor pressure 21 mm Hg ( 20 °C)
Storage temp: Flammables area
Water Solubility: reacts
Sensitive: Air & Moisture Sensitive
Merck : 14,8564
Appearance: clear to slightly hazy, colorless to light amber
Product Categories: Organometallics;Al (Alminum) Compounds;Classes of Metal Compounds;Reduction;Synthetic Organic Chemistry;Typical Metal Compounds
Safety Profile
Hazard Codes F.gif){kind=small}
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Risk Statements 11-14/15-34-48/20-63-65-67
11: Highly Flammable
14/15: Reacts violently with water, liberating extremely flammable gases
34: sodium Dihydrobis(2-methoxyethoxy)-aluminate (22722-98-1) can causes burns
48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
63: Possible risk of harm to the unborn child
65: Harmful: sodium Dihydrobis(2-methoxyethoxy)-aluminate (22722-98-1) may cause lung damage if swallowed
67: Vapors may cause drowsiness and dizziness
Safety Statements 26-36/37/39-43-45-62-46-16
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
46: If swallowed, seek medical advice immediately and show this container or label
62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
RIDADR UN 3399 4.3/PG 1
WGK Germany 2
F 1-10
TSCA Yes
HazardClass 4.3
PackingGroup I
Specification
1.General Information:As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor.
2.Extinguishing Media: Use dry sand or earth to smother fire. Do NOT use water, carbon dioxide, or foam
3.Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Take precautionary measures against static discharges. Use only in a chemical fume hood.
4.Storage: Keep sodium Dihydrobis(2-methoxyethoxy)-aluminate (22722-98-1) away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Store under argon.
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