Products Categories
CAS No.: | 2311-91-3 |
---|---|
Name: | perphthalic acid |
Article Data: | 21 |
Molecular Structure: | |
Formula: | C8H6 O5 |
Molecular Weight: | 182.133 |
Synonyms: | Benzenecarboperoxoicacid, 2-carboxy- (9CI); Phthalic monoperoxyacid (6CI,7CI,8CI);Monoperoxyphthalic acid; Monoperphthalic acid; NSC 240744; Perphthalic acid |
Density: | 1.507g/cm3 |
Boiling Point: | 407.3°Cat760mmHg |
Flash Point: | 173.4°C |
PSA: | 83.83000 |
LogP: | 1.01460 |
Conditions | Yield |
---|---|
Stage #1: phthalic anhydride With dihydrogen peroxide; sodium carbonate In water at -5 - 0℃; for 0.5h; Stage #2: With sulfuric acid In water; ethyl acetate | 76.9% |
With dihydrogen peroxide; sodium carbonate at 0℃; | |
With alkali hydroxide; dihydrogen peroxide |
phthalic anhydride
A
monoperoxyphthalic acid
B
bis-(2-carboxy-benzoyl)-peroxide
Conditions | Yield |
---|---|
With alkaline H2O2 |
phthalic anhydride
dihydrogen peroxide
A
monoperoxyphthalic acid
B
bis-(2-carboxy-benzoyl)-peroxide
Conditions | Yield |
---|---|
unter Eiskuehlung; |
monoperoxyphthalic acid
Conditions | Yield |
---|---|
With sodium hydroxide |
bis-(2-carboxy-benzoyl)-peroxide
A
monoperoxyphthalic acid
B
benzene-1,2-dicarboxylic acid
monoperoxyphthalic acid
N-[4-cyano-3-(trifluoromethyl)phenyl]-2-methylacrylamide
A
N-[4-cyano-3-(trifluoromethyl)-phenyl]-2,3-dihydroxy-2-methyl-propionamide
B
N-[4-cyano-3-(trifluoromethyl)phenyl]-2-methyloxirane-2-carboxamide
Conditions | Yield |
---|---|
In ethyl acetate at 20 - 55℃; Product distribution / selectivity; | A 5.51% B 100% |
monoperoxyphthalic acid
tricyclo<7.3.1.02,7>tridec-2(7)-ene
2,7-epoxytricyclo<7.3.1.02,7>tridecane
Conditions | Yield |
---|---|
In diethyl ether for 2h; | 88% |
monoperoxyphthalic acid
Conditions | Yield |
---|---|
In chloroform at 0℃; | 88% |
monoperoxyphthalic acid
Conditions | Yield |
---|---|
In chloroform at 0℃; for 168000h; | 85% |
monoperoxyphthalic acid
trans-9-propenyl-3,6-dichlorocarbazole
9-(1-phtaloyloxy-2-hydroxypropyl)-3,6-dichlorocarbazole
Conditions | Yield |
---|---|
In chloroform at 60℃; for 8h; | 40% |
With monoperoxyphthalic acid In 1,4-dioxane at 25℃; for 1h; Rate constant; |