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| CAS No.: | 2325-27-1 |
|---|---|
| Name: | TETRAPHENYLPHOSPHINE IMIDE |
| Article Data: | 37 |
| Molecular Structure: | |
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|
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| Formula: | C24H20NP |
| Molecular Weight: | 353.403 |
| Synonyms: | Phosphineimide, tetraphenyl- (6CI,7CI,8CI);(Phenylimino)triphenylphosphorane;N-(Triphenylphosphoranylidene)aniline;N-Phenylimino(triphenyl)phosphorane;N-Phenyltriphenylphosphinimine;NSC 110604;Triphenylphosphine phenylimide;Triphenyl(phenylimino)phosphorane;Tetraphenylphosphinimine; |
| EINECS: | 219-039-1 |
| Density: | 1.07g/cm3 |
| Melting Point: | 130 °C |
| Boiling Point: | 505.3 °C at 760 mmHg |
| Flash Point: | 259.4 °C |
| Solubility: | Insoluble in water. Soluble in chloroform 25 mg/mL. |
| Appearance: | yellow solid |
| Hazard Symbols: |
 Xi
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| Risk Codes: | 36/37/38 |
| Safety: | 26-37/39 |
| PSA: | 22.17000 |
| LogP: | 5.49580 |
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Specification
The Benzenamine,N-(triphenylphosphoranylidene)-, with the CAS registry number 2325-27-1, is also known as N-Phenylimino(triphenyl)phosphorane. Its EINECS number is 219-039-1. This chemical's molecular formula is C24H20NP and molecular weight is 353.4. What's more, its IUPAC name is triphenyl(phenylimino)-λ5-phosphane. It should be sealed and stored in a cool, ventilated and dry place. Moreover, it should be protected from oxides, air and water.
Physical properties of Benzenamine,N-(triphenylphosphoranylidene)- are: (1)ACD/LogP: 5.84; (2)# of Rule of 5 Violations: 1; (3)#H bond acceptors: 1; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 4; (6)Polar Surface Area: 22.17 Å2; (7)Index of Refraction: 1.6; (8)Molar Refractivity: 112.87 cm3; (9)Molar Volume: 329.9 cm3; (10)Polarizability: 44.74×10-24cm3; (11)Surface Tension: 44.8 dyne/cm; (12)Density: 1.07 g/cm3; (13)Flash Point: 259.4 °C; (14)Enthalpy of Vaporization: 74.56 kJ/mol; (15)Boiling Point: 505.3 °C at 760 mmHg; (16)Vapour Pressure: 7.78E-10 mmHg at 25°C.
Preparation of Benzenamine,N-(triphenylphosphoranylidene)-: this chemical can be prepared by triphenylphosphane and azidobenzene by heating. This reaction will need solvent toluene with the reaction time of 2 hours. The yield is about 100%.
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Uses of Benzenamine,N-(triphenylphosphoranylidene)-: it can be used to produce (N-methylphenylamino)triphenylphosphonium iodide by heating. It will need solvent benzene with the reaction time of 8 hours. The yield is about 80%.
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When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing and gloves.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1=CC=C(C=C1)N=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4
(2)InChI: InChI=1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H
(3)InChIKey: PTLOPIHJOPWUNN-UHFFFAOYSA-N