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| CAS No.: | 23719-80-4 |
|---|---|
| Name: | Cyclopropylmagnesium bromide |
| Article Data: | 3 |
| Molecular Structure: | |
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| Formula: | C3H5BrMg |
| Molecular Weight: | 145.282 |
| Synonyms: | CYCLOPROPYLMAGNESIUM BROMIDE;CYCLOPROPYLMAGNESIUM BROMIDE, 0.5 M IN THF;Cyclopropylmagnesium Bromide 0.75 M In Tetrahydrofuran;Cyclopropylmagnesium Bromide, 0.5 M in Tetrahydrofuran;cyclopropylmagnesium bromide solution;Cyclopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L);Bromocyclopropylmagnesium;Cyclopropylbromomagnesium |
| EINECS: | 472-500-0 |
| Density: | 0.968 g/mL at 25 °C |
| Boiling Point: | 65 °C |
| Flash Point: | 65°C |
| Solubility: | Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents. |
| Appearance: | clear colorless solution |
| Hazard Symbols: |
 F,  Xi
|
| Risk Codes: | 11-14-19-36/37/38 |
| Safety: | 16-26 |
| Transport Information: | UN 3399 4.3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 1.96360 |
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Specification
The Cyclopropylmagnesium bromide, with the CAS registry number 23719-80-4, is also known as Magnesium, bromocyclopropyl-. It belongs to the product categories of Cyclopropanes; Grignard Reagents; Grignard Reagents & Alkyl Metals; Simple 3-Membered Ring Compounds; Synthetic Organic Chemistry; Alkyl; Grignard Reagents; Organometallic Reagents. This chemical's molecular formula is C3H5BrMg and molecular weight is 145.28. Its systematic name is called bromo(cyclopropyl)magnesium. This chemical is clear colorless solution.
Physical properties of Cyclopropylmagnesium bromide: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0 Å2; (5)Flash Point: 65 °C; (6)Density: 0.968 g/mL at 25 °C; (7)Boiling Point: 65 °C.
Uses of Cyclopropylmagnesium bromide: it can be used to produce 5-Cyclopropylpentane-1,5-diol. This reaction will need solvent tetrahydrofuran. The yield is about 81%.
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When you are using this chemical, please be cautious about it as the following:
This chemical may catch fire in contact with air which only need brief contact with an ignition source and has a very low flash point or evolve highly flammable gases in contact with water. In addition, this chemical may cause inflammation to the skin or other mucous membranes. It is highly flammable. It will react violently with water. Besides, it may form explosive peroxides. It is irritating to eyes, respiratory system and skin. You should keep away from sources of ignition - No smoking. In case of contact with eyes, you must rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: Br[Mg]C1CC1
(2)InChI: InChI=1/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1/rC3H5BrMg/c4-5-3-1-2-3/h3H,1-2H2
(3)InChIKey: QUPLLJGAJVXXBW-XMUNDLKSAU