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2495-37-6

Basic Information
CAS No.: 2495-37-6
Name: Benzyl methacrylate
Article Data: 41
Molecular Structure:
Molecular Structure of 2495-37-6 (Benzyl methacrylate)
Formula: C11H12O2
Molecular Weight: 176.215
Synonyms: Methacrylicacid, benzyl ester (6CI,7CI,8CI);Acryester BZ;Benzyl 2-methyl-2-propenoate;Benzyl 2-methylacrylate;Benzyl methacrylate;BzMA;Fancryl FA-BZM;Light EsterBZ;NSC 20970;Phenylmethyl 2-methyl-2-propenoate;
EINECS: 219-674-4
Density: 1.036 g/cm3
Melting Point: <25 °C
Boiling Point: 247.033 °C at 760 mmHg
Flash Point: 124.13 °C
Solubility: Insoluble in water.
Appearance: colourless liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26
PSA: 26.30000
LogP: 2.30590
Synthetic route
79-41-4

poly(methacrylic acid)

100-51-6

benzyl alcohol

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
tetrachlorobis(tetrahydrofuran)hafnium(IV) In benzene for 40h; Heating;99%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h;90%
toluene-4-sulfonic acid In benzene for 15h; Heating;85%
80-62-6

methacrylic acid methyl ester

100-51-6

benzyl alcohol

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With C2H3O3(1-)*C37H78N(1+) In hexane at 90℃; for 2h; Reagent/catalyst; Molecular sieve;97%
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate In hexane for 10h; Molecular sieve; Reflux;80%
920-46-7

Methacryloyl chloride

100-51-6

benzyl alcohol

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With triethylamine at 0℃; Inert atmosphere; Microwave irradiation;96%
With triethylamine In dichloromethane at 0℃;62%
With triethylamine In dichloromethane at 0℃; Inert atmosphere;50%
81171-49-5

(1-Benzyloxy-2-chloro-2-methyl-cyclopropoxy)-trimethyl-silane

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With triethylamine In methanol for 6h; Heating;91%
With triethylamine In methanol for 12h; Heating; Yield given;
1426060-15-2

benzyl 3-(dimethylamino)-2-methylpropanoate

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; triethylamine In isopropyl alcohol at 20℃; for 0.25h; Eschenmoser Methylenation;90%
65-85-0

benzoic acid

75107-16-3

2-bromoisobutyric acid,benzyl ester

A

C18H18O4

B

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With silver(l) oxide In water; acetonitrile at 100℃; for 24h;A 89%
B n/a
100-44-7

benzyl chloride

920-46-7

Methacryloyl chloride

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With dmap; caesium carbonate at 50℃; for 24h; Concentration;89%
4245-37-8

vinyl methacrylate

100-51-6

benzyl alcohol

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With TBA7[γ-HGeW10O36] In acetonitrile at 39.84℃; for 0.0166667h;83%
63613-50-3

benzyl 2-(tripheny l-λ5phosphanylidene)propanoate

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
With carbon dioxide; potassium tert-butylate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 12h;83%
463-49-0

1,2-propanediene

201230-82-2

carbon monoxide

100-51-6

benzyl alcohol

2495-37-6

benzyl methacrylate

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h;73%
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Chemistry

Molecular Formula: C11H12O2
Formula Weight: 176.21
bp: 95-98 °C 4 mm Hg(lit.)
density: 1.04 g/mL at 25 °C(lit.)
refractive index: n20/D 1.512(lit.)
Fp: 225 °F
Sensitive: Light Sensitive
PHYSICAL STATE: clear liquid
SOLUBILITY IN WATER: Insoluble
STABILITY Of Benzyl Methacrylate: Polymerization will occur under light and HEAT

Uses

Benzyl Methacrylate can be used as funtional monomer for polymers, coatings, Adhesives. Textile treatment agent, LUBRICATING OIL .

Toxicity Data With Reference

Oral rat LD50: 3600 mg/kg

Safety Profile

Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26
WGK Germany : 1

Standards and Recommendations

PURITY (G.C): 98.0% min
COLOR, APHA: 30 max
SPECIFIC GRAVITY: 1.035 - 1.045
WATER: 0.1% max
FREE ACID:0.05% max (Methacrlic acid)
INHIBITOR: 200ppm max (Monomethyl Ether Hydroquinone)

Specification

PACKING OF Benzyl Methacrylate: 200kgs in drum