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| CAS No.: | 2516-33-8 |
|---|---|
| Name: | Cyclopropyl carbinol |
| Molecular Structure: | |
|
|
|
| Formula: | C4H8O |
| Molecular Weight: | 72.1069 |
| Synonyms: | Cyclopropylcarbinyl alcohol;Cyclopropanemethyl alcohol;Cyclopropanemethanol;Cyclopropylmethyl alcohol;Cyclopropylmethanol;1-Cyclopropylmethanol;Cyclopropyl Methanol; |
| EINECS: | 219-735-5 |
| Density: | 1.004 g/cm3 |
| Melting Point: | -60 °C |
| Boiling Point: | 124.3 °C at 760 mmHg |
| Flash Point: | 35 °C |
| Solubility: | miscible with water |
| Appearance: | Clear colorless liquid |
| Hazard Symbols: |
 Xn,  Xi,  C,  F
|
| Risk Codes: | 10-22-36-34 |
| Safety: | 16-26-36-45-36/37/39 |
| Transport Information: | UN 1987 3/PG 3 |
| PSA: | 20.23000 |
| LogP: | 0.38870 |
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| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate In tert-butyl methyl ether at 0 - 50℃; for 24h; | 95% |
| With lithium aluminium tetrahydride | 83% |
| With lithium aluminium tetrahydride | 67% |
- 2516-33-8
Cyclopropylmethanol
| Conditions | Yield |
|---|---|
| With cerium(III) chloride In acetonitrile for 1h; Heating; | 95% |
| Conditions | Yield |
|---|---|
| With C24H20ClN2OPRu; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 10640.7 Torr; for 36h; Inert atmosphere; Schlenk technique; | 91% |
- 1344115-77-0
2-(cyclopropylmethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- 2516-33-8
Cyclopropylmethanol
| Conditions | Yield |
|---|---|
| With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation; | 90% |
| Conditions | Yield |
|---|---|
| With sodium In methanol at 45 - 65℃; for 2h; Inert atmosphere; Large scale; | 88% |
| With lithium aluminium tetrahydride In diethyl ether at 0℃; for 1h; | 85% |
| Stage #1: methyl cyclopropylcarboxylate With methanol; aluminum (III) chloride; sodium tetrahydroborate at 2℃; Stage #2: With ammonium chloride In water Temperature; Reagent/catalyst; | 74.3% |
- 2516-33-8
Cyclopropylmethanol
| Conditions | Yield |
|---|---|
| With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation; | 85% |
| Conditions | Yield |
|---|---|
| With formaldehyd; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In water; toluene at 90℃; | 77% |
| Conditions | Yield |
|---|---|
| bis(benzonitrile)palladium(II) dichloride In dichloromethane at 0 - 10℃; catalytic cyclopropanation of other unsaturated compounds; | 72% |
| bis(benzonitrile)palladium(II) dichloride In diethyl ether; dichloromethane at 0 - 10℃; for 0.5h; | 72% |
| bis(benzonitrile)palladium(II) dichloride In dichloromethane at 0 - 10℃; | 72% |
| palladium(II) acetylacetonate In diethyl ether at -10℃; | 45% |
| With bis(benzonitrile)palladium(II) dichloride In dichloromethane at 0 - 10℃; Yield given; |
| Conditions | Yield |
|---|---|
| With 1,2-dimethoxyethane; zinc In diethyl ether Heating; | 67% |
| With lanthanum; iodine In tetrahydrofuran for 5h; | 67% |
- 70458-21-8
cyclobutanecarbonyl m-chlorobenzoyl peroxide
A
- 627-27-0
homoalylic alcohol
B
- 2516-33-8
Cyclopropylmethanol
C
- 70458-29-6
3-butenyl m-chlorobenzoate
D
- 70458-27-4
cyclobutyl m-chlorobenzoate
E
- 70458-28-5
cyclopropylmethyl m-chlorobenzoate
F
- 2919-23-5
cyclobutanol
| Conditions | Yield |
|---|---|
| With acetic acid; potassium iodide In tetrachloromethane at 26℃; Rate constant; on silica; | A 4.3% B 9.6% C 19.5% D 11.8% E 45.5% F 6.5% |
| With acetic acid; potassium iodide In neat (no solvent) at 26℃; Rate constant; on silica; | |
| With acetic acid; potassium iodide In chloroform at 55℃; Rate constant; | |
| With acetic acid; potassium iodide In tetrachloromethane at 55℃; Rate constant; |
- 2516-34-9Cyclobutylamine
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- Total:29 Page 1 of 1 1
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Chemistry
IUPAC Name:cyclopropylmethanol
Molecular Formula:C4H8O
Molecular Weight:72.105720 g/mol
Appearance:clear liquid
Melting Point:-60 °C
Boiling Point:123-124 °C738 mm Hg(lit.)
Flash Point:95 °F
Solubility:water, alcohol
density:0.89 g/mL at 25 °C(lit.)
refractive index:n20/D 1.431(lit.)
storage temp.:Flammables area
Water Solubility:miscible
BRN:1846846
Synonyms of CYCLOPROPYL CARBINOL(2516-33-8):
CPC-OL;CP-CARBINOL;CPMO;CYCLOPROPYL CARBINOL;CYCLOPROPYLMETHANOL;CYCLPOPROPANEMETHANOL;CYCLOPROPANEMETHANOL;(HYDROXYMETHYL)CYCLOPROPANE
Categories of CYCLOPROPYL CARBINOL(2516-33-8):
Cyclopropanes;Simple 3-Membered Ring Compounds;Cycloalkanes
Uses
Safety Profile
Hazard Codes:Xn,Xi
,C 
,F 
Risk Statements:10-22-36-34
10:Flammable
22:Harmful if swallowed
36:Irritating to the eyes
34:Causes burns
Safety Statements:16-26-36-45-36/37/39
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:Wear suitable protective clothing
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
RIDADR:UN 1987 3/PG 3
WGK Germany:1
RTECS:GZ2212250
Hazard Note:Irritant
HazardClass:3
PackingGroup:III
Specification
First Aid Measures of CYCLOPROPYL CARBINOL(2516-33-8):
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Storage of CYCLOPROPYL CARBINOL(2516-33-8):
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.