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Basic Information
CAS No.: 2516-92-9
Name: Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate
Article Data: 14
Molecular Structure:
Molecular Structure of 2516-92-9 (Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate)
Formula: C28H50N2O6
Molecular Weight: 510.715
Synonyms: Piperidinooxy,4-hydroxy-2,2,6,6-tetramethyl-, sebacate (2:1) (ester) (8CI);Piperidinooxy,4-hydroxy-2,2,6,6-tetramethyl-, sebacate (7CI);Sebacic acid, diester with4-hydroxy-2,2,6,6-tetramethylpiperidinooxy (8CI);Bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) sebacate;Bis(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) decanedioate;Bis(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) sebacate;CXA 5415;Ciba 5415;MP1002;Prostab 5415;
EINECS: 1308068-626-2
Density: 1.12 at 22℃
Melting Point: 99.0 to 103.0 °C
Boiling Point: 523.5°C at 760 mmHg
Flash Point: 270.4°C
PSA: 59.08000
LogP: 5.80360
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Synthetic route
52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions
ConditionsYield
With sodium tungstate; dihydrogen peroxide; edetate disodium In methanol; acetonitrile10%
52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

A

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

B

80004-15-5

C28H51N2O5

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane 1) 273 K, 1 h, 2) 1 h, reflux;
45985-24-8, 2226-96-2

TEMPOL

818-88-2

sebacic acid mono methyl ester

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions
ConditionsYield
With sodium methylate In n-heptane Heating / reflux;
111-19-3

sebacoyl chloride

45985-24-8, 2226-96-2

TEMPOL

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 18h;
2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

111-65-9

octane

bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate

Conditions
ConditionsYield
With dihydrogen peroxide at 75 - 80℃; for 9h; Reagent/catalyst; Temperature;89.7%
With iron(III) chloride; dihydrogen peroxide; acetic acid In water; acetonitrile at 76℃; for 4h; Heating / reflux;31%
2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

371756-16-0

di(1-phenoxy-2,2,6,6-tetramethyl-piperidin-4-yl) sebacate

Conditions
ConditionsYield
With pyridine; tert.-butylnitrite; aniline In n-heptane; ethyl acetate47.9%
2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

110-82-7

cyclohexane

bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate

Conditions
ConditionsYield
With methanesulfonic acid; dihydrogen peroxide; iron(II) sulfate In water; acetonitrile at 55℃; for 5.5h; Heating / reflux;43%
2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

52829-07-9

bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions
ConditionsYield
With ethanethiol In benzene17%
292638-84-7

styrene

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

polymer, Mn (g/mol) = 20600, Mw/Mn = 1.68; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

polymer, Mn (g/mol) = 20600, Mw/Mn = 1.68; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

Conditions
ConditionsYield
With dibenzoyl peroxide at 130℃; for 2.5h;53 % Turnov.
292638-84-7

styrene

2516-92-9

bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

polymer, Mn (g/mol) = 25000, Mw/Mn = 1.72; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

polymer, Mn (g/mol) = 25000, Mw/Mn = 1.72; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

Conditions
ConditionsYield
With dibenzoyl peroxide at 130℃; for 14h;86 % Turnov.
Raw Materials
45985-24-8
818-88-2
52829-07-9
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52829-07-9
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    2516-92-9

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  • Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl)sebacate

  • Casno:

    2516-92-9

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  • Bis(2,2,6,6-Tetramethyl-1-Piperidinyloxy-4-Yl) Sebacate

  • Casno:

    2516-92-9

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Specification

The Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate is an organic compound with the formula C28H50N2O6. With the CAS registry number 2516-92-9, it is also named as 1-Piperidinyloxy, 4,4'-((1,10-dioxo-1,10-decanediyl)bis(oxy))bis(2,2,6,6-tetramethyl-. The product's category is Pharmaceutical Intermediates.

You can still convert the following datas into molecular structure:
(1)SMILES: CC1(CC(CC(N1[O])(C)C)OC(=O)CCCCCCCCC(=O)OC2CC(N(C(C2)(C)C)[O])(C)C)C
(2)InChI: InChI=1/C28H50N2O6/c1-25(2)17-21(18-26(3,4)29(25)33)35-23(31)15-13-11-9-10-12-14-16-24(32)36-22-19-27(5,6)30(34)28(7,8)20-22/h21-22H,9-20H2,1-8H3
(3)InChIKey: XVJWWMHPPKXKRU-UHFFFAOYAB
(4)Std. InChI: InChI=1S/C28H50N2O6/c1-25(2)17-21(18-26(3,4)29(25)33)35-23(31)15-13-11-9-10-12-14-16-24(32)36-22-19-27(5,6)30(34)28(7,8)20-22/h21-22H,9-20H2,1-8H3
(5)Std. InChIKey: XVJWWMHPPKXKRU-UHFFFAOYSA-N