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CAS No.: | 2622-14-2 |
---|---|
Name: | Tricyclohexyl phosphine |
Article Data: | 55 |
Molecular Structure: | |
Formula: | C18H33P |
Molecular Weight: | 280.434 |
Synonyms: | Phosphine,tricyclohexyl-;Tricyclohexylphosphine;tricyclohexylphosphine); |
EINECS: | 220-069-2 |
Density: | 0.909 g/mL at 25 °C |
Melting Point: | 81-83 °C(lit.) |
Boiling Point: | 383.434 °C at 760 mmHg |
Flash Point: | 195.609 °C |
Solubility: | Soluble in most organic solvents. Insoluble in water. |
Appearance: | white to yellow crystalline powder |
Hazard Symbols: | Xn,Xi,F |
Risk Codes: | 36/37/38-22-37/38-36-19-11-67-65-63 |
Safety: | 26-36/37-62-37/39-36-33-29-16 |
Transport Information: | UN 2056 3/PG 2 |
PSA: | 13.59000 |
LogP: | 6.46640 |
Conditions | Yield |
---|---|
In benzene-d6 at 20℃; for 0.166667h; Inert atmosphere; Glovebox; | A 95% B n/a |
tricyclohexylphosphine
Conditions | Yield |
---|---|
With methanol; 4 A molecular sieve In 1,4-dioxane at 115℃; for 42h; | 92% |
tricyclohexylphosphine
Conditions | Yield |
---|---|
With sodium hydroxide In water Product distribution / selectivity; | 90% |
Conditions | Yield |
---|---|
With pyridine In benzene-d6 at 25℃; Inert atmosphere; Glovebox; | A 87% B 13% |
tricyclohexylphosphine oxide
tricyclohexylphosphine
Conditions | Yield |
---|---|
With Bis(p-nitrophenyl) phosphate; 1,3-diphenyl-disiloxane In ethyl acetate at 23℃; for 70h; Sealed tube; chemoselective reaction; | 84% |
Stage #1: tricyclohexylphosphine oxide With triphenyl phosphite; diphenyl hydrogen phosphite; iodine; triethylamine In tetrahydrofuran at 25℃; for 63h; Inert atmosphere; Schlenk technique; Stage #2: With sodium hydroxide In water for 0.5h; Glovebox; | 82% |
With bis(2-chlorophenyl)borinic acid; phenylsilane In toluene at 80℃; for 36h; Inert atmosphere; | 78% |
ICo(CO)2(P(C6H11)3)2
diphenylphosphane sulfide
N-ethyl-N,N-diisopropylamine
B
dicarbonyl(η2-diphenylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
C
tricyclohexylphosphine
Conditions | Yield |
---|---|
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.; | A n/a B 71% C n/a |
bis(tricyclohexylphosphine)platinum(0)
A
[(OC)3Fe{μ-BN(SiMe3)2}(μ-BDur)Pt(PCy3)]
B
tricyclohexylphosphine
Conditions | Yield |
---|---|
In hexane Inert atmosphere; Schlenk technique; Glovebox; | A 71% B n/a |
diethylphosphine sulfide
ICo(CO)2(P(C6H11)3)2
N-ethyl-N,N-diisopropylamine
dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
C
tricyclohexylphosphine
Conditions | Yield |
---|---|
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C2H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.; | A n/a B 65% C n/a |
ICo(CO)2(P(C6H11)3)2
dimethylphosphine sulfide
N-ethyl-N,N-diisopropylamine
C
dicarbonyl(η2-dimethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
D
tricyclohexylphosphine
Conditions | Yield |
---|---|
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of Me2HPS to a soln. of Co compound in toluene and dropwise addn. of (Et)(i-Pr)2N in toluene at 25°C during 2 h, 8 h; decantation, concd. in vac., addn. of n-hexane, decantation, cooled to -30°C, filtration of pptn., suspension in toluene, filtration (polymeric product), addn. of hexane to the filtrate, crystn. at -30°C; elem. anal.; | A n/a B n/a C 46% D n/a |
ICo(CO)2(P(C6H11)3)2
di(yclohexyl)phosphine sulfide
N-ethyl-N,N-diisopropylamine
B
dicarbonyl(η2-dicyclohexylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
C
tricyclohexylphosphine
Conditions | Yield |
---|---|
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H11)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.; | A n/a B 37% C n/a |
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The Tricyclohexyl phosphine, with the CAS registry number 2622-14-2,is also known as Phosphine,tricyclohexyl-. It belongs to the product categories of organophosphorus ligand;organophosphine ligand.Its EINECS number is 220-069-2. This chemical's molecular formula is C18H33P and molecular weight is 280.43. What's more,Its systematic name is Tricyclohexyl phosphine.It is a clear colorless to pale yellow solution.
Physical properties about Tricyclohexyl phosphine are:
(1)ACD/LogP: 6.352; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.35; (4)ACD/LogD (pH 7.4): 6.35; (5)ACD/BCF (pH 5.5): 39568.81; (6)ACD/BCF (pH 7.4): 39568.81; (7)ACD/KOC (pH 5.5): 67978.00; (8)ACD/KOC (pH 7.4): 67978.00; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Flash Point: 195.609 °C; (13)Enthalpy of Vaporization: 60.723 kJ/mol; (14)Boiling Point: 383.434 °C at 760 mmHg; (15)Vapour Pressure: 0 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES:C1CCC(CC1)P(C2CCCCC2)C3CCCCC3;
(2)Std. InChI:InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2;
(3)Std. InChIKey:WLPUWLXVBWGYMZ-UHFFFAOYSA-N.
Safety Information of Tricyclohexyl phosphine:
The Tricyclohexyl phosphine is Irritating to eyes, respiratory system and skin. It May form explosive peroxides and its Vapours may cause drowsiness and dizziness.And it may cause lung damage if swallowed. There is possible risk of harm to the unborn child.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.When you use it ,wear suitable protective clothing, gloves and eye/face protection. If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. Take precautionary measures against static discharges. This chemical is highly flammable,keep away from sources of ignition.