Products Categories
CAS No.: | 26452-98-2 |
---|---|
Name: | 1-ACETOXYINDAN |
Article Data: | 37 |
Molecular Structure: | |
Formula: | C11H12 O2 |
Molecular Weight: | 176.215 |
Synonyms: | 1-Indanol,acetate (7CI,8CI); 1H-Inden-1-ol, 2,3-dihydro-, acetate (9CI); 1-Acetoxyindan;1-Indanyl acetate; NSC 31257; NSC 62558 |
Density: | 1.09 |
Melting Point: | 42-43 °C |
Boiling Point: | 241 °C |
Flash Point: | 100.1°C |
PSA: | 26.30000 |
LogP: | 2.23700 |
Conditions | Yield |
---|---|
With 4-(N,N-dimethylamino)pyridine based 1,3,5,7-tetraphenyladamantane polymer In neat (no solvent) at 25℃; for 4.5h; Schlenk technique; | 98% |
With silica-bonded N-propyl sulfamic acid at 20℃; for 0.5h; chemoselective reaction; | 93% |
With C7H10N2*C8HF15O2 at 25℃; for 17h; neat (no solvent); | 93% |
Conditions | Yield |
---|---|
With 1,3-dicyclohexylimidazol-2-ylidene at 25℃; for 0.25h; | 91% |
Conditions | Yield |
---|---|
With Novozym 435; (isopropylamino)(tetraphenyl)cyclopentadienyl Ru(CO)2Cl; potassium tert-butylate In toluene at 25℃; for 48h; | 89% |
With Y(salen)(N(SiMe2H)2)(THF) In toluene at -22℃; for 4h; |
Conditions | Yield |
---|---|
With 1,3-dicyclohexylimidazol-2-ylidene at 25℃; for 0.25h; | 89% |
Conditions | Yield |
---|---|
With ZnAl2O4 nanoparticles at 20℃; for 0.5h; Neat (no solvent); | 86% |
With pyridine In diethyl ether at 20℃; | 27% |
With pyridine In benzene Ambient temperature; |
1H-inden-3-yl acetate
2,3-dihydro-1H-inden-1-yl-acetate
Conditions | Yield |
---|---|
With hydrogen In toluene for 48h; | 75% |
1-Indanol
1-acetyl-2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrimidinium tetraphenylborate
2,3-dihydro-1H-inden-1-yl-acetate
Conditions | Yield |
---|---|
With DBN In acetonitrile at 80℃; for 16h; Inert atmosphere; | 70% |
INDANE
acetic acid
A
1-Indanol
B
2,3-dihydro-1H-inden-1-yl-acetate
C
inden-1-one
Conditions | Yield |
---|---|
With C26H28F6MnN6O7S2; dihydrogen peroxide In water; acetonitrile at 20℃; for 0.5h; Inert atmosphere; | A 6% B 10% C 32% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide In water; acetonitrile at 82℃; for 24h; | 26% |
1-chloroindane
2,3-dihydro-1H-inden-1-yl-acetate
Conditions | Yield |
---|---|
With sodium acetate; acetic acid | |
With potassium acetate; acetic acid | |
Multi-step reaction with 2 steps 1: diluted K2CO3 / 60 °C 2: sodium acetate View Scheme |