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26544-38-7

Basic Information
CAS No.: 26544-38-7
Name: 2-DODECEN-1-YLSUCCINIC ANHYDRIDE
Molecular Structure:
Molecular Structure of 26544-38-7 (2-DODECEN-1-YLSUCCINIC ANHYDRIDE)
Formula: C16H26 O3
Molecular Weight: 266.42
Synonyms: Succinicanhydride, (tetrapropenyl)- (7CI,8CI); (Tetrapropenyl)succinic anhydride;ASAN-PT; DSA; DSA (crosslinking agent); NSC 41536; RD 174
EINECS: 247-781-6
Density: 1.005
Melting Point: 41-43 °C(lit.)
Boiling Point: 180-182 °C5 mm Hg(lit.)
Flash Point: 113 ºC
Solubility: 20mg/L at 22℃
Appearance: clear yellow viscous liquid
Hazard Symbols:
Risk Codes: R36/38   
Safety: Moderately toxic by ingestion. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
PSA: 43.37000
LogP: 4.16310
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Chemistry

IUPAC Name: 3-Dodec-2-enyloxolane-2,5-dione
Synonyms : 2-Dodecen-1-ylsuccinic anhydride
Molecular Structure:  
Molecular Formula : C16H26O3
Molecular Weight : 266.38
CAS Registry Number:  26544-38-7
EINECS : 247-781-6
Surface Tension: 35.7 dyne/cm
Density: 0.99 g/cm
Flash Point: 177.8 °C 
Melting point:  41-43 °C(lit.)
Boiling Point: 348.4 °C at 760 mmHg 
Vapour Pressure: 5.04E-05 mmHg at 25°C 
vapor density  9.2 (vs air)
Enthalpy of Vaporization: 59.28 kJ/mol 
Refractive index : 1.479
Appearance:Tetrapropenylsuccinic anhydride (26544-38-7) is clear yellow viscous liquid 。

Uses

1.Tetrapropenylsuccinic anhydride (26544-38-7) is mainly used for epoxy curing agent ; casting and laminating products.
2.Tetrapropenylsuccinic anhydride (26544-38-7) is also used for glue of paper; anti-rust agent; alkyd resin soft conditioner; plastic plasticizer; ink agent; leather water-repellent treatment agent; desiccant, PVC stabilizer production.

Production

Using maleic anhydride and gas in the heating conditions for the reactions ,obtaining Dodecencylsuccinic anhydride ,washing after crude vacuum distillation, collecting at 165-240 ℃ (0.53-1.33kPa) , then get Tetrapropenylsuccinic anhydride (26544-38-7) .

Toxicity Data With Reference

1.    

orl-rat LD50:2550 mg/kg

    34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,581.
2.    

skn-rbt LD50:6200 mg/kg

    34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,581.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes  Xi
Risk Statements  36/37/38
36/37/38:  Irritating to eyes, respiratory system and skin 
Safety Statements  26-37/39-36
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing 
37/39:  Wear suitable gloves and eye/face protection  
WGK Germany  3
RTECS  WN1225000

Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
2.Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. 
3.Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
4.Storage: Store Tetrapropenylsuccinic anhydride (26544-38-7) in a cool, dry place. Keep container closed when not in use.