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28292-43-5

Basic Information
CAS No.: 28292-43-5
Name: 2-AMINO-5-METHYLHEXANE
Article Data: 5
Molecular Structure:
Molecular Structure of 28292-43-5 (2-AMINO-5-METHYLHEXANE)
Formula: C7H17N
Molecular Weight: 115.219
Synonyms: Pentylamine,1,4-dimethyl- (8CI);1,4-Dimethylpentylamine;5-Methyl-2-hexylamine;NSC 73708;dl-2-Amino-5-methylhexane;
EINECS: 248-941-8
Density: 0.776 g/cm3
Melting Point: -19°C (estimate)
Boiling Point: 134.62 °C at 760 mmHg
Flash Point: 29.301 °C
Hazard Symbols: CorrosiveC
Risk Codes: 10-34
Safety: 26-36/37/39-45
Transport Information: UN 2734 8/PG 2
PSA: 26.02000
LogP: 2.47010
Synthetic route
60372-16-9

bis-(1,4-dimethyl-pentylidene)-hydrazine

A

28292-43-5

2-amino-5-methylhexane

B

145659-67-2

bis-(1,4-dimethyl-pentyl)-amine

Conditions
ConditionsYield
With nickel at 190 - 200℃; Hydrogenation;
110-12-3

5-Methyl-2-hexanone

28292-43-5

2-amino-5-methylhexane

N-(5-methyl-2-hexyl)phthalimide

28292-43-5

2-amino-5-methylhexane

Conditions
ConditionsYield
With hydrazine hydrate In ethanol hydrazinolysis; Heating;
627-59-8

5-methylhexan-2-ol

28292-43-5

2-amino-5-methylhexane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 65 percent / PPh3; diethyl azodicarboxylate / tetrahydrofuran / 0 - 20 °C
2: N2H4*H2O / ethanol / Heating
View Scheme
646-07-1

4-Methylpentanoic acid

28292-43-5

2-amino-5-methylhexane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: thorium oxide
2: aqueous alcoholic NaOH-solution; hydrazine hydrate
3: nickel / 190 - 200 °C / Hydrogenation
View Scheme
28292-43-5

2-amino-5-methylhexane

98-68-0

4-methoxy-phenyl-sulphonyl chloride

4-methoxy-N-(5-methylhexan-2-yl)benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 12h;90%
28292-43-5

2-amino-5-methylhexane

14418-84-9

allylsulfonyl chloride

N-(5-methylhexan-2-yl)prop-2-ene-1-sulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 3h;83%
28292-43-5

2-amino-5-methylhexane

94-36-0

dibenzoyl peroxide

O-benzoyl-N-(5-methylhexan-2-yl)hydroxylamine

Conditions
ConditionsYield
Stage #1: dibenzoyl peroxide With caesium carbonate In dichloromethane at 23℃; for 2h;
Stage #2: 2-amino-5-methylhexane In dichloromethane at 23℃; for 14h;
82%
28292-43-5

2-amino-5-methylhexane

145659-67-2

bis-(1,4-dimethyl-pentyl)-amine

Conditions
ConditionsYield
With chlorohydridocarbonylbis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Schlenk technique; Inert atmosphere;80%
28292-43-5

2-amino-5-methylhexane

359-06-8

monofluoroacetyl chloride

N-(1,4-Dimethyl-pentyl)-2-fluoro-acetamide

Conditions
ConditionsYield
With potassium hydroxide In diethyl ether at 5 - 15℃; for 5h;75%
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Chemistry

IUPAC Name: (2S)-5-Methylhexan-2-amine
Synonyms: 1,4-Dimethylpentylamine
Molecular Structure of 5-Methyl-2-hexylamine (CAS NO. 28292-43-5) :
Molecular Formula of 5-Methyl-2-hexylamine (CAS NO. 28292-43-5) : C7H17N
Molecular Weight of 5-Methyl-2-hexylamine (CAS NO. 28292-43-5) : 115.22
CAS NO : 28292-43-5
EINECS : 248-941-8
Mol File: 28292-43-5.mol
Index of Refraction: 1.424
Surface Tension: 25.7 dyne/cm
Density: 0.775 g/cm3
Flash Point: 29.3 °C
Enthalpy of Vaporization: 37.21 kJ/mol
Boiling Point: 134.6 °C at 760 mmHg
Vapour Pressure: 8.02 mmHg at 25°C
BRN : 1731716

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 90mg/kg (90mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Journal of Pharmacology and Experimental Therapeutics. Vol. 103, Pg. 325, 1951.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard CodesCorrosiveC
Risk Statements 10-34 
R10:Flammable.
R34: 5-Methyl-2-hexylamine (CAS NO. 28292-43-5) can causes burns.  
Safety Statements 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39: When using 5-Methyl-2-hexylamine (CAS NO. 28292-43-5),wear suitable protective clothing, gloves and eye/face protection.   
RIDADR UN 2734 8/PG 2
WGK Germany 3
RTECS SC0875000
HazardClass 3
PackingGroup III