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2867-47-2

Basic Information
CAS No.: 2867-47-2
Name: 2-(Dimethylamino)ethyl methacrylate
Article Data: 20
Molecular Structure:
Molecular Structure of 2867-47-2 (2-(Dimethylamino)ethyl methacrylate)
Formula: C8H15NO2
Molecular Weight: 157.213
Synonyms: Methacrylicacid, 2-(dimethylamino)ethyl ester (6CI,8CI);(2-Methacryloyloxyethyl)dimethylamine;(Dimethylamino)ethyl methacrylate;2-(N,N-Dimethylamino)ethyl methacrylate;Acryester DM;Ageflex FA 1;Ageflex FM 1;Ageflex FM 2;DM (methacrylate);Dimethyl[2-(methacryloyloxy)ethyl]amine;GE 720;Light Ester DM;MADAM;Methacryl Ester DM;Methacryloyloxyethyldimethylamine;Mhoromer BM 601;N,N-Dimethylaminoethyl methacrylate;N,N-Dimethylethanolamine methacrylate;NSC20959;b-(N,N-Dimethylamino)ethylmethacrylate;b-Dimethylaminoethylmethacrylate;
EINECS: 220-688-8
Density: 0.945 g/cm3
Melting Point: -50 °C
Boiling Point: 187 °C at 760 mmHg
Flash Point: 70.6 °C
Solubility: decomposes in water
Appearance: colourless liquid
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 21/22-36/38-43
Safety: 26-28-2
Transport Information: UN 2522 6.1/PG 2
PSA: 29.54000
LogP: 0.66730
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    2-(Dimethylamino)ethyl methacrylate

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Chemistry

The Molecular Structure of 2-Dimethylaminoethyl methacrylate (CAS NO.2867-47-2):

Empirical Formula: C8H15NO2
Molecular Weight: 157.2102 
IUPAC Name: 2-dimethylaminoethyl 2-methylprop-2-enoate 
Appearance: colourless liquid
Classification Code: Drug / Therapeutic Agent;Indicators and Reagents;Reducing agents
Nominal Mass: 157 Da
Average Mass: 157.2102 Da
Monoisotopic Mass: 157.110279 Da 
Index of Refraction: 1.444
Molar Refractivity: 44.17 cm3
Molar Volume: 166.2 cm3
Surface Tension: 29 dyne/cm
Density: 0.945 g/cm3
Flash Point: 70.6 °C
Enthalpy of Vaporization: 42.32 kJ/mol
Boiling Point: 187 °C at 760 mmHg
Vapour Pressure: 0.644 mmHg at 25°C 
log P (octanol-water): 0.970
Water Solubility: 1.06E+05 mg/L at 25°C 
Henry's Law Constant: 9.54E-08 atm-m3/mole at 25°C 
Atmospheric OH Rate Constant: 9.92E-11 cm3/molecule-sec at 25°C 
InChI
InChI=1/C8H15NO2/c1-7(2)8(10)11-6-5-9(3)4/h1,5-6H2,2-4H3
Smiles
O(C(C(C)=C)=O)CCN(C)C 
Stability: Stable. Incompatible with strong acids, strong bases, strong oxidizing or reducing agents. May decompose on exposure to air and moisture. May undergo autopolymerization. Light sensitive.

Uses

 2-Dimethylaminoethyl methacrylate (CAS NO.2867-47-2) can be used for the preparation of polymer.

Toxicity Data With Reference

1.    

orl-rat LD50:1751 mg/kg

       Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT.: 1982,55.
2.    

ihl-rat LC50:620 mg/m3/4H

       Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT.: 1982,55.
3.    

ihl-mus LC50:1800 mg/m3/2H

       Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT.: 1982,55.
4.    

ipr-mus LD50:25 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and inhalation. A skin, eye, and mucous membrane irritant. A powerful lachrymator. Flammable when exposed to sparks, heat, open flame, or oxidizers. To fight fire, use alcohol foam, dry chemical, spray. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.
Hazard Codes: IrritantXiIrritantXn
Risk Statements: 21/22-36/38-43 
R21/22: Harmful in contact with skin and if swallowed
R36/38: Irritating to eyes and skin
R43: May cause sensitization by skin contact
Safety Statements: 26-28-2 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28: After contact with skin, wash immediately with plenty of soap-suds
S2: Keep out of the reach of children
RIDADR: UN 2522 6.1/PG 2
WGK Germany: 1
RTECS: OZ4200000
F 19: Lachrymator
HazardClass: 6.1
PackingGroup: II
HS Code: 29221980

Standards and Recommendations

DOT Classification:  6.1; Label: Poison

Specification

 2-Dimethylaminoethyl methacrylate (CAS NO.2867-47-2) is also called as 2-(Dimethylamino)ethyl 2-methyl-2-propenoate ; 2-(Dimethylamino)ethyl methacrylate ; 2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester ; Dimethylaminoethyl methacrylate ; N,N-Dimethylaminoethyl methacrylate ; 2-(Dimethylamino)ethyl methacrylate ; 2-(N,N-Dimethylamino)ethyl methacrylate ; 2-Dimethylaminoethylester kyseliny methakrylove ; 2-Dimethylaminoethylester kyseliny methakrylove [Czech] ; 2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester ; Ethanol, 2-(dimethylamino)-, methacrylate ; Methacrylic acid, 2-(dimethylamino)ethyl ester ; N,N-Dimethylaminoethyl methacrylate ; N,N-Dimethylethanolamine methacrylate ; beta-Dimethylaminoethyl methacrylate ; 2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester ; Methacrylic acid, 2-(dimethylamino)ethyl ester ; 2-Dimethylaminoethyl methacrylate [UN2522] [Poison] .